Plasters have covered wide surface areas of buildings since antiquity, with a main purpose of indoor protection of the substrate on which they are applied. When no longer functional, they might require substitution with solutions that can combine compatibility with the substrate with the current need to mitigate building emissions. Indeed, plasters can contribute to lowering buildings’ energy demands while improving indoor air quality and the comfort of buildings’ users, as plasters can be used as passive regulators of relative humidity (RH). Hence, this study presents the relative-humidity-dependent properties of different plastering mortars based on clay, air lime, and natural hydraulic lime, and plastering finishing pastes based on gypsum and gypsum–air lime, in all cases tested using small size specimens. A cement-based plaster is also analysed for comparison. The clay-based plaster was the most promising material for RH passive regulation, and could be applied to repair and replace plasters in different types of buildings. Pastes based on air lime–gypsum could be applied as finishing layers, specifically on traditional porous walls. The sorption behaviour of cement plaster appeared interesting; however, its water vapour permeability was as expected, found to be the lowest, discouraging its application on historic walls.

In Southern European countries, due to the specific climate, economy and culture, a permanent heating practice during winter is not widely adopted. This may have a significant effect on the performance of indoor coating materials, typically tested considering hygrothermal conditions in the range of 33–75% relative humidity (RH) and 20–25 °C, which are common in continuously heated buildings. In this study, the indoor climate of four bedrooms located in Lisbon, Portugal, was monitored under operational conditions. Based on the data monitored in the case studies, characteristic ranges of indoor hygrothermal conditions were defined and compared to those considered in standard test procedures. In addition, numerical simulations were adopted to compare the hygroscopic performance of four plasters under operational conditions observed on-site. Results show that the four rooms, intermittently heated or unheated, do not provide comfort conditions over 50% of the wintertime, with temperatures lower and RH higher than the ones recommended by the standards. The MBVs resulting from simulations (under operational conditions) are qualitatively in agreement with the MBVs obtained under standard testing conditions. Nonetheless, future studies are recommended to evaluate if standard tests are quantitatively representative of the hygroscopic performance of coating materials in the Southern European scenario.

In recent decades, interest in the eco-efficiency of building materials has led to numerous research projects focused on the replacement of raw materials with mineral and biomass wastes, and on the production of mortars with low-energy-consuming binders, such as gypsum. In this context, five different fractions (bark, wood, branchlets, leaves, and flowers) of Acacia dealbata—an invasive species—were evaluated as fillers for premixed gypsum mortars, at 5% and 10% (vol.) addition levels and fixed water content. Although these biomass fractions had different bulk densities (>50% of variation), all the mortars were workable, although presenting different consistencies. As expected, dry density decreased with biomass addition, but, while mortars with addition at 5% presented a slight shrinkage, a slight expansion occurred with those with 10% addition. Generally, the mechanical properties decreased with the biomass additions even if this was not always proportional to the added content. The wood fraction showed the most positive mechanical results but flexural and compressive strengths of all the tested mortars were found to be higher than the lower standard limit, justifying further studies.