The possibility of contemporary mural paintings to be “tagged” by vandals, with spray and/or markers, represents a serious problem for the conservation of urban art. The present study aims to define the applicability of a protective coating on murals’ surface to preserve them against vandalism. The research has been focused on anti-graffiti products currently used in the field of cultural heritage conservation. These products represent an optimum start point to preserve mural artwork from vandal actions. The commercially available anti-graffiti products have been compared with an innovative product, PRO-ART, specifically formulated by YOCOCU in collaboration with Pelicoat, for the conservation of murals. At the same time, it has tested the cleaning of contemporary murals by using different mixtures of solvents and surfactants. The experimentations have been carried out on external walls, followed by the conducting of in situ tests (application tests, empirical evaluations and colorimetric analysis), as well as laboratory investigations (contact angle and optical/electronic microscopy).
This article discloses a rare and outstanding type of Mn-rich black-blue patina found on mural painting and granite ashlars located in the church of Sta. Marinha, north of Portugal, and conjectures the phenomenon associated to the appearance of such patinas in different surface materials. This Mn-patina reported on mural painting and their origin is probably assigned to manganese leaching from building materials (i.e., granite and phyllites). Stained mural painting and granite examined by XPS and SEM have showed patinas enriched with manganese (IV) oxide, potentially catalysed by a microbiota, like fungi, observed in SEM micrographs. The pigments used to depict mural painting and groundwater were also analysed by micro-Raman and ICP-MS, respectively, indicating that they are unlikely manganese sources. Unstained building materials, such as granite ashlars, historic joints, mortars and phyllite rocks, were also analysed by ICP-MS showing that historic joints and mortars present significant concentrations of manganese, possibly associated to their absorbing feature. The main materials with potential to impart manganese to Mn-rich patinas are granite ashlars and phyllites. The aim of this investigation is to reveal and ascertain the hypothetical sources and the phenomenon responsible for the Mn-rich black-blue patina appearance, both on mural painting and granite ashlars.
This review aims to explore the literature to assess the potential of artificial intelligence (AI) in environmental monitoring for predicting microbiome dynamics. Recognizing the significance of comprehending microorganism diversity, composition, and ecologically sustainable impact, the review emphasizes the importance of studying how microbiomes respond to environmental changes to better grasp ecosystem dynamics. This bibliographic search examines how AI (Machine Learning and Deep Learning) approaches are employed to predict changes in microbial diversity and community composition in response to environmental and climate variables, as well as how shifts in the microbiome can, in turn, influence the environment. Our research identified a final sample of 50 papers that highlighted a prevailing concern for aquatic and terrestrial environments, particularly regarding soil health, productivity, and water contamination, and the use of specific microbial markers for detection rather than shotgun metagenomics. The integration of AI in environmental microbiome monitoring directly supports key sustainability goals through optimized resource management, enhanced bioremediation approaches, and early detection of ecosystem disturbances. This study investigates the challenges associated with interpreting the outputs of these algorithms and emphasizes the need for a deeper understanding of microbial physiology and ecological contexts. The study highlights the advantages and disadvantages of different AI methods for predicting environmental microbiomes through a critical review of relevant research publications. Furthermore, it outlines future directions, including exploring uncharted territories and enhancing model interpretability.
The purpose of this study was to assess the extraction of cellulose from stalks of vines using auto-hydrolysis and characterize it. As the results obtained, the colorimeter readings displayed a final yellow color of the fiber, demonstrating that the bleaching process was insufficient and that multiple bleaching processes might be required. According to the FTIR (Fourier-transform infrared spectroscopy) data, there were stretching and deformation vibrationsof characteristic peak that represent cellulose (2900, 1500, and 1200 cm−1). Although lignin and hemicellulose were partially removed according to the FTIR, distinct cellulose yields were achieved for each fraction, including fractions 500, 300, 250, 150 µm, and retain, with values of 21.98, 12.70, 7.20, 5.74, and 3.11%, respectively. In sum, we were able to extract cellulose from the stalk vine, although the last step still needs to be optimized for better whitening.