Composites of polyurea (PU) reinforced with milled glass fiber (MGf) were fabricated. The volume fraction and length of the milled glass fiber were varied to study their effects on the morphological and mechanical properties of the MGf/PU composites. The morphological attributes were characterized with scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The SEM investigations revealed a uniform distribution and arbitrary orientation of milled glass fiber in the polyurea matrix. Moreover, it seems that the composites with longer fiber exhibit better interfacial bonding. It was found from the FTIR studies that the incorporation of milled glass fiber into polyurea leads to more phase mixing and decreases the hydrogen bonding of the polyurea matrix, while having a negligible effect on the H-bond strength. The compression tests at different strain rates (0.001, 0.01, 0.1, 1, 2000 and 3000 s−1) and dynamic mechanical properties over the temperature range from −30 to 100 °C at 1 Hz were performed. Experimental results show that the compressive behavior of MGf/PU composites is nonlinear and strain-rate-dependent. Both elastic modulus and flow stress at any given strain increased with strain rate. The composites with higher fiber volume fraction and longer fiber length are more sensitive to strain rate. Furthermore, the elastic modulus, stress at 65% strain and energy absorption capability were studied, taking into account both the effect of fiber volume fraction and mean fiber length. It is noted that an increase in fiber volume fraction and fiber length leads to an increase in elastic modulus, stress at 65% strain and absorbed energy up to ~103%, 83.0% and 137.5%, respectively. The storage and loss moduli of the composites also increase with fiber volume fraction and fiber length. It can be concluded that the addition of milled glass fiber into polyurea not only improves the stiffness of the composites but also increases their energy dissipative capability.
3 November 2021 in International Journal of Minerals, Metallurgy and Materials
High-performance extruded aluminum alloys with complex textures suffer significant dimension variation under environmental temperature fluctuations, dramatically decreasing the precision of navigation systems. This research mainly focuses on the effect of the texture of extruded pure aluminum on its dimensional stability after various annealing processes. The result reveals that a significant increment in the area fraction of recrystallized grains with orientation and a decrement in the area fraction of grains with orientation were found with increasing annealing temperature. Moreover, with the annealing temperature increasing from 150 °C to 400 °C, the residual plastic strain after twelve thermal cycles with a temperature range of 120 °C was changed from −1.6 × 10−5 to −4.5 × 10−5. The large amount of equiaxed grains with orientation was formed in the microstructure of the extruded pure aluminum and the average grain size was decreased during thermal cycling. The area fraction of grain with crystallographic orientation of the sample annealed at 400 °C after thermal cycling was 30.9% higher than annealed at 350 °C (23.7%) or at 150 °C (18.7%). It is attributed to the increase in the proportion of recrystallization grains with direction as the annealing temperature increases, provided more nucleation sites for the formation of fine equiaxed grains with orientation. The main orientation of the texture was rotated from parallel to to parallel to after thermal cycling. The change in the orientation of grains contributed to a change in interplanar spacing, which explains the change in the dimension along the extrusion direction during thermal cycling.