Peroxide has been considered a chemical agent that can be used to tune the properties of polymeric materials. This research evaluated the influence of different concentrations of dialkyl peroxides on the mechanical, thermal, and morphological properties of linear low-density polyethylene (LLDPE) and ultra-high molecular weight polyethylene (UHMWPE). The neat polymer, as well as those with the addition of 1% and 2% by mass of dialkyl peroxides, were subjected to compression molding and immersion in water for 1 h, under controlled temperatures of 90 °C. The values of the gel content found in the samples indicated that the addition of peroxide to the LLDPE and to the UHMWPE promoted the formation of a reticulated network. The structure obtained by the crosslinking led to less reorganization of the chains during the crystallization process, resulting in the formation of imperfect crystals and, consequently, in the reduction in melting temperatures, crystallization and enthalpy. The mechanical properties were altered with the presence of the crosslinker. The polymers presented had predominant characteristics of a ductile material, with the occurrence of crazing with an increased peroxide content.

The construction industry contributes enormously to the high levels of carbon dioxide on the planet. For this reason, the sector has been investing in the development of new products that reduce the environmental impact. This study developed a fibrous polymeric composite using industrial residues of polyethylene terephthalate (PET) fibers for application in civil construction as a cladding element. The thermal and morphological characterization of the fiber was performed using Thermogravimetry (TG) and Scanning Electron Microscopy (SEM). Composites with 1, 3, and 5% PET fibers were obtained. Mechanical, morphological properties, chemical resistance, the effect of ultraviolet radiation and water absorption of the composites were evaluated. The results were compared to parameters established by the Brazilian standard NBR 15.575-3. Fibers had a smooth surface but with small surface defects, diameter between 20 and 30 µm and thermal stability up to 325.44 °C. The addition of 5% PET fibers resulted in an increase of more than 300% in the impact resistance of the composites, but with a reduction in the flexural strength. The mechanical and chemical resistance results met the parameters established by the standard used in the study. The degradation chamber test indicated that PET fibers suffered more from exposure to ultraviolet radiation than the polymeric matrix.

To modify its characteristics, expand its applicability, and, in some cases, its processability, new blends using ultra-high-molecular-weight polyethylene (UHMWPE) have been developed. In this study, three different formulations of linear low-density polyethylene (LLDPE) and UHMWPE blends were prepared with 15, 30, and 45% (% w/w) UHMWPE in the LLDPE matrix. All mixtures were prepared by hot pressing and were immersed in water for one hour afterwards at a controlled temperature of 90 °C to relieve the internal stresses that developed during the forming process. The thermal characterization showed that the blends showed endothermic peaks with different melting temperatures, which may be the result of co-crystallization without mixing between the polymers during the forming process. The mechanical characteristics presented are typical of a ductile material, but with the increase in the percentage of UHMWPE, there was a decrease in the ductility of the blends, as the elongation at rupture of the blends was higher than that of the pure components. The morphologies observed by SEM indicate that there were two phases in the blends. This is the result of the system’s immiscibility due to the mode of preparation of the blends, wherein the two polymers may not have mixed intimately, confirming the results found with the thermal analyses.

This study compares the logistics of decommissioning wind turbine blades for energy recovery in a cement kiln (proposed scenario) to industrial landfill site disposal and coke fuel in a cement kiln combined (base scenario) to check the financial cost of the operation in each scenario. The wind farm coordinates, wind turbine blade mass, and logistics costs of the 760 wind farms in Northeast Brazil were used to determine the location of a material processing center (MPC) for wind turbine blade waste. The findings showed that the cost of the proposed scenario was higher than that of the base scenario when a single MPC was considered to serve the Northeast region. However, the proposed scenario was preferable when installing decentralized MPCs to serve the Northeast region. The installation of four additional decentralized MPCs shows that energy recovery is a more favorable technological route in the economic performance for disposing of 96% of the wind turbine blades in operation in the Northeast region, which represents 210,188 tonnes. Therefore, the gradual implementation of MPCs should consider a wind turbine blade decommissioning plan to support the energy recovery potential.

Anais do Congresso Brasileiro Interdisciplinar em Ciência e Tecnologia (2764-0582) - Método Para Desenvolvimento De Ferramenta De Acompanhamento De Egressos Universitários