Waste heat generation has a widespread presence into daily applications, however, due to the low-temperature grade which presents, its exploitation with the most common technologies is complicated. Thermoelectricity presents the possibility of harvesting any temperature grade heat; besides it also includes many other advantages which make thermoelectric generators perfect for generating electric power from waste heat. A prototype divided into two levels along the chimney which uses the waste heat of a combustion has been built. The experimentation has been used to determine the parameters that influence the generation and to validate a generic computational model able to predict the thermoelectric generation of any application, but specially applications where waste heat is harvested. The temperature and mass flow of the flue gases and the load resistance determine the generation, and consequently, these parameters have been included into the model, among many others. This computational model incorporates all the elements included into the generators (heat exchangers, ceramics, unions) and all the thermoelectric phenomena and moreover, it takes into account the temperature loss of the flue gases while circulating along the thermoelectric generator. The built prototype presents a 65 % reduction in the generation of the two levels of the thermoelectric generator due to the temperature loss of the flue gases. The general computational model predicts the thermoelectric generation with an accuracy of the ±12 %.The authors are indebted to the Spanish Ministry of Economy and Competitiveness for the economic support to this work, included in the DPI2014-53158-R research project

An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection.The authors are indebted to the Ministry of Economy, Industry and Competitiveness-Government of Spain and FEDER Funds for economic support of this work, included in the DPI2014-53158-R Research Project