The objective of this study is to analyze the economic viability of municipal household solid waste (organic matter + paper) for the production of gas, coke and biofuel through the pyrolysis and distillation process. The waste was collected in the city of Belém do Pará-Brazil and pretreated at the Federal University of Pará. The analyzed fraction (organic matter + paper) was subjected to the pretreatment of drying, crushing, and sieving and was subsequently subjected to proximate characterization and, finally, pyrolysis of the organic fraction (organic matter + paper) in a fixed bed reactor. Initially, it was necessary to review the literature, and with the yields obtained by pyrolysis of the fraction, economic feasibility analyses were carried out. The economic indicators for evaluating the most viable pyrolysis process were basic payback, discounted payback, net present value, internal rate of return, and profitability index, which are all financial metrics commonly used in investment analysis and decision making. These metrics provide valuable insights into the financial viability and attractiveness of investment projects. They are essential tools for assessing the feasibility and profitability of various ventures, helping decision-makers make informed choices in allocating resources. The analysis of the indicators showed the economic viability considering an analysis horizon of 10 years of materials based on organic material and paper. The breakeven point obtained was USD 0.96/dm³ and the minimum biofuel sales price found in this project was USD 1.30/dm³. The sensitivity research found that material costs (organic matter + paper), bio-oil yield, total project investment and electricity, respectively, are the variables that most affect the minimum biofuel sales price.

In this work, a techno-economic assessment of the production of bio-oil, coke and gas, via thermo-catalytic pyrolysis followed by distillation, is accomplished. The raw materials were two solid wastes: lipid-based material (residual fat/scum from a fat retention box from the University Restaurant at the Federal University of Pará—UFPA) and a lignin-cellulosic material of açaí seed (Euterpe oleracea Mart.). From the literature, a review is made of the physicochemical analysis of the raw materials, of the bio-oil, and of the chemical composition of the biofuels produced (kerosene, light diesel, and heavy diesel). The bio-oil yields for each experiment of pyrolysis and distillation are also presented and compared with the literature. The economic indicators for the evaluation of the most viable cracking (pyrolysis) and distillation process of bio-oils were: (a) the simple payback criterion, (b) discounted payback, (c) net present value (NPV), (d) internal rate of return (IRR), and (e) index of profitability (IP). The analysis of the indicators showed the economic viability of the lipid-based material and unfeasibility for the açai seed (Euterpe oleracea Mart.). The breakeven point obtained was 1.28 USD/L and the minimum fuel selling price (MFSP) obtained in this work for the biofuels was 1.34 USD/L). The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables to affect the minimum fuel selling price (MFSP).

Palm oil is, from an economic, environmental, and social point of view, a vegetable oil with great potential and the state of Pará-Brazil is Brazil’s great producer. In addition, soap phase residue or palm oil neutralization sludge (PONS), a byproduct of the neutralization step of the chemical refinement of palm oil, is produced, posing a huge problem for waste disposal and management in the production process of refined palm oil (RPO). In this context, this work aims to systematically investigate the economic analysis of the thermal–catalytic process of crude palm oil (CPO) and palm oil neutralization sludge (PONS). The thermocatalytic processes of CPO and PONS carried out at pilot scale and their economic feasibility were analyzed. The yields of biofuels produced by fractional distillation were also presented. The physicochemical properties of CPO and PONS, as well as those of organic liquid products obtained by the thermal–catalytic process of CPO and PONS were taken into account in the economic analysis. In addition, the chemical composition organic liquid products obtained by thermal–catalytic process of CPO and PONS, as well as its distillation fractions (green gasoline, green kerosene, green light diesel and heavy diesel), used as key factors/indicators on the economic analysis. The analysis of the key factors/indicators from the thermocatalytic processes of CPO and PONS showed economic viability for both crude palm oil (Elaeis guineensis, Jacq) and palm oil neutralization sludge. The minimum fuel selling price (MFSP) obtained in this work for the biofuels was 1.59 USD/L using crude palm oil (CPO) and 1.34 USD/L using palm oil neutralization sludge (PONS). The best breakeven point obtained was of 1.24 USD/L considering the PONS. The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables that affect the minimum fuel-selling price (MFSP) in both economic analyses.

This work aims to investigate systematically the tecno-economic feasibility of ther-mos-catalytic cracking process for two solid waste materials, a lipid-base material (re-sidual fat/scum from retention box of the University Restaurant of UFPA) and a lig-nin-cellulosic material Açaí seed (Euterpe oleracea. Mart). The thermo-catalytic process-es were carried out in pilot scale (THERMTEK/LEQ/UFPA/IME/RJ), and their economic feasibility analyzed. The yields of biofuels produced by fractional distillation were al-so studied. The physicochemical characteristics of the raw materials, the organic liquid product (bio-oil) and the chemical composition of kerosene, light-diesel and heavy-diesel from the lipid-base material, as well as those of kerosene and light-diesel from the Açaí seed were also determined. The economic indicators for the evaluation of the most viable cracking (pyrolysis) and distillation process of bio-oils were: a) the sim-ple payback criterion, b) discounted payback, c) net present value (NPV), d) internal rate of return (IRR), and e) index of profitability (IP). The analysis of the indicators showed the economic viability of crude palm oil (Elaeis guineensis, Jacq) and unfeasibil-ity for the palm oil neutralization. The minimum fuel selling price (MFSP) obtained is this work for the biofuels was of 1.34 US$/L) and the breakeven point obtained was of 1.28 US$/L. The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables to affect the minimum fuel selling price (MFSP).

This work aims to investigate systematically the tecno-economic feasibility of ther-mos-catalytic cracking process for two solid waste materials, a lipid-base material (re-sidual fat/scum from retention box of the University Restaurant of UFPA) and a lig-nin-cellulosic material Açaí seed (Euterpe oleracea. Mart). The thermo-catalytic process-es were carried out in pilot scale (THERMTEK/LEQ/UFPA/IME/RJ), and their economic feasibility analyzed. The yields of biofuels produced by fractional distillation were al-so studied. The physicochemical characteristics of the raw materials, the organic liquid product (bio-oil) and the chemical composition of kerosene, light-diesel and heavy-diesel from the lipid-base material, as well as those of kerosene and light-diesel from the Açaí seed were also determined. The economic indicators for the evaluation of the most viable cracking (pyrolysis) and distillation process of bio-oils were: a) the sim-ple payback criterion, b) discounted payback, c) net present value (NPV), d) internal rate of return (IRR), and e) index of profitability (IP). The analysis of the indicators showed the economic viability of crude palm oil (Elaeis guineensis, Jacq) and unfeasibil-ity for the palm oil neutralization. The minimum fuel selling price (MFSP) obtained is this work for the biofuels was of 1.34 US$/L) and the breakeven point obtained was of 1.28 US$/L. The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables to affect the minimum fuel selling price (MFSP).

This work aims to investigate systematically the tecno-economic feasibility of ther-mos-catalytic cracking process for two solid waste materials, a lipid-base material (re-sidual fat/scum from retention box of the University Restaurant of UFPA) and a lig-nin-cellulosic material Açaí seed (Euterpe oleracea. Mart). The thermo-catalytic process-es were carried out in pilot scale (THERMTEK/LEQ/UFPA/IME/RJ), and their economic feasibility analyzed. The yields of biofuels produced by fractional distillation were al-so studied. The physicochemical characteristics of the raw materials, the organic liquid product (bio-oil) and the chemical composition of kerosene, light-diesel and heavy-diesel from the lipid-base material, as well as those of kerosene and light-diesel from the Açaí seed were also determined. The economic indicators for the evaluation of the most viable cracking (pyrolysis) and distillation process of bio-oils were: a) the sim-ple payback criterion, b) discounted payback, c) net present value (NPV), d) internal rate of return (IRR), and e) index of profitability (IP). The analysis of the indicators showed the economic viability of crude palm oil (Elaeis guineensis, Jacq) and unfeasibil-ity for the palm oil neutralization. The minimum fuel selling price (MFSP) obtained is this work for the biofuels was of 1.34 US$/L) and the breakeven point obtained was of 1.28 US$/L. The sensibility analysis demonstrated that the pyrolysis and distillation yields are the most important variables to affect the minimum fuel selling price (MFSP).