This study describes the development of a renewable and biodegradable biopolymer-based hydrogel for application in agriculture and horticulture as a soil conditioning agent and for release of a nutrient or fertilizer. The novel product is based on a combination of cellulose derivatives (carboxymethylcellulose and hydroxyethylcellulose) cross-linked with citric acid, as tested at various concentrations, with acid whey as a medium for hydrogel synthesis in order to utilize the almost unusable by-product of the dairy industry. The water uptake of the hydrogel was evaluated by swelling tests under variations in pH, temperature and ion concentration. Its swelling capacity, water retention and biodegradability were investigated in soil to simulate real-world conditions, the latter being monitored by the production of carbon dioxide during the biodegradation process by gas chromatography. Changes in the chemical structure and morphology of the hydrogels during biodegradation were assessed using Fourier transform infrared spectroscopy and scanning electron microscopy. The ability of the hydrogel to hold and release fertilizers was studied with urea and KNO₃ as model substances. The results not only demonstrate the potential of the hydrogel to enhance the quality of soil, but also how acid whey can be employed in the development of a soil conditioning agent and nutrient release products.

This study details the design and characterization of a new, biodegradable, and renewable whey/cellulose-based hydrogel (i.e., agricultural hydrogel). This was formulated from cellulose derivatives (carboxymethylcellulose (CMC) and hydroxyethylcellulose (HEC)) and acid whey cross-linked with citric acid, with the aim to obtain an agricultural product with a high swelling capacity to uphold the quality of soil and conserve water resources. With regard to the swelling behaviour of the prepared hydrogels, the authors initially assessed the swelling ratio and capacity for water uptake. Evaluating the chemical structure of the hydrogel and its thermal and viscoelastic properties involved performing Fourier transform infrared spectroscopy, differential scanning colorimetry, thermal gravimetric analysis, and rheological measurement of the hydrogel films. According to preliminary results, sufficient swelling capacity and stiffness were observed in a hydrogel prepared with 3% CMC and HEC, cross-linked with 5% citric acid. Moreover, the kinetics of water uptake revealed a promising capacity that was sustainable after 5 drying and swelling cycles. The results confirmed that the stability of the hydrogel was enhanced by the presence of the citric acid. As a consequence, it is necessary to utilize an appropriate cross-linking concentration and abide by certain conditions to ensure the swelling properties of the prepared hydrogel are sufficient. Further investigation of the topic, especially in relation to applications in soil, could confirm if the whey-cellulose-based hydrogel is actually suitable for agricultural use, thereby contributing to the advancement of sustainable arable farming.

Agricultural production is influenced by the water content in the soil and the availability of nutrients. Recently, changes in the quantity and seasonal water availability are expected to impact agriculture due to climate change. This study aimed to test an agricultural product with promising properties to improve soil quality and water-holding capacity during agricultural application. Most of the traditional hydrogels are low-biodegradable synthetic materials with under-researched long-term fate in field soil conditions. The novel, biodegradable hydrogel made from acid whey and cellulose derivatives cross-linked with citric acid was used. The soil-improving effects were tested under controlled experimental conditions with the sandy artificial soil consisting of 10% finely ground sphagnum peat, 20% kaolinite clay, and 70% quartz sand. Soil pH, the content of organic carbon (Cox), total nitrogen (N), available forms of the essential macronutrients (P, K, Ca, and Mg), the cation exchange capacity (CEC), the maximum water capacity (MWC) and water holding capacity (WHC) were determined. The results showed a positive effect on water retention and basic soil properties after the different levels of hydrogel had been introduced into the soil. Generally, the addition of whey-based hydrogel increases the available nutrients concentration and water retention in soil.