The current research encompasses utilization of peanut shells (PS) as feedstock for pyrolysis carried out at various temperatures (250, 400, and 550 °C) for deriving biochar, namely PS-BC250, PS-BC400, and PS-BC550. After analyzing the biochar types physicochemically, it was applied as a soil ameliorant for the growth of cucumber. The results showed that in prepared biochar type, bulk density, volatile contents, hydrogen, oxygen, and nitrogen content decreased, whereas pH, electrical conductivity, ash content, fixed carbon content, and surface area increased with the increasing temperature. Scanning electron microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR) presented high porosity, re-orientation of vessels, and a greater number of aromatic compounds, respectively, for PS-BC prepared at 550 °C. On applying PS-BC250, PS-BC400, and PS-BC550 as amendments in potted soil at 2, 4, and 6% (w/w), it improved soil quality (viz pH, EC_e, BD, and soil water holding capacity) and increased the yield of cucumber. Because of improved soil properties and crop yield, PS-BC550 at the rate of 4% (w/w) demonstrated a great potential for agricultural application while provisioning dual circular economic indicators in the form of diverting PS waste to an effective alternative of chemical fertilizer having intensive carbon footprints in cucumber production.

The current study is aimed at deriving biochar (BC) from rice straw (RS-BC) and waste bones (WB-BC), being wasted without adequate return at the expense of environmental degradation. The RS and WB feedstocks were pyrolyzed at 550 °C, and the potential of derived biochar as a slow nutrient releasing soil amendment was examined during the growth of ridge gourd. Proximate analysis of the prepared biochars showed significant improvement in ash content and fixed carbon as compared to their raw biomasses. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) analysis of RS-BC and WB-BC displayed a diverse range of functional groups viz. derivatives of cellulose and hydroxylapatite (HA); macro and microporosity; multiple nutrients. Application of RS-BC and WB-BC in potted soil alone and as biochar composite (RS-BC+WB-BC) at 5, 10 and 15% (w/w) and chemical fertilizer (CF) resulted in a significant increase in soil pH, electrical conductivity (ECe), cation exchange capacity (CEC) and water holding capacity (WHC) in exchange for growth and yield of ridge gourd. However, there were insignificant differences in the growth of plants in response to RS-BC, WB-BC alone and CF with biochar composite at 15% amendment. For giving insignificantly different growth results than CF, the prepared biochar composite showed outstanding potential as an organic fertilizer applicable in agrarian soils to elevate soil properties and yield of agricultural commodities.

Two of the multiple limitations of phytoextraction efficiency (PE %) of TSW polluted soils are: (i) low growth of plant performance, (ii) poor bioavailability of excessive essential and heavy metals (ascribed as Category-I and II metals respectively) The current study reports biostimulant role of allochthonous Trichoderma harzianum (F1) and autochthonous Trichoderma pseudokoningii (F2) in growth of Tagetes patula L. and uptake of Category-I & II metals from TSW-soil (0, 5 & 10%). Significantly higher growth (27.5–47.8% dry wt. than Control) and highly significantly higher uptake of Category-I & II metals (72–80% Ca, 32–69% K, 72–76% Na & 73–86% Cd, 63–100% Cr, 72–77% Cu, 73–78% Fe, 43–77% Mg, 22–33% Ni, 70–73% Zn) was observed in T. patula applied with F1 + F2 treatment. The PE (%) parameters viz.specific extraction yield, tolerance and translocation index of Category-I & II metals were higher in plants cultivated on fungal inoculated TSW:soil. The Trichoderma spp. acted as strong biostimulants for enhancing plant growth and conc. of catalase (CAT, 44-52% than control), superoxide dismutase (SOD, 37–43%), soluble proteins (37-68%) and total chlorophyll (10–26%) in T. patula during metal phytoextraction of TSW:soil. Novelty statement Due to multiple socio-economic constraints for effective management of tannery solid waste (TSW), the heavy metal phytoextraction seems to be one of the promising approaches. However, due to complex composition of TSW, that is, with more than 37 components, high pH, multiple types and high conc. of metals; there lies huge challenge of enhancing phytoextraction efficiency (PE %). This can be done by enhancing growth of hyperaccumulator plants and increasing bioavailable fraction of metals. The current study suggests application of selected fungal biostimulants for increasing growth of T. patula while improving bioavailable fraction of the total metal contents of the TSW: soil.

The excessive concentration of multiple heavy metals in the tannery solid waste (TSW) needs integrated process solutions for its decontamination. This study is aimed at deriving TSW compost and autochthonous microbe synergies for improving phytoextraction potential of sunflower. In-vessel composting of TSW was carried out by using fruit waste as an inoculum to achieve the optimized conditions. Autochthonous strains of Trichoderma viride and Bacilllus sp. isolated from TSW were utilized individually as well as in combination with TSWC amendments of 2.5, 5 and 10% (w/w) prepared in our pilot scale experiment. Analyses of TSW compost based on FTIR and SEM illustrated the wide range of functionality and porosity along the mesh of fungal hyphae and inorganic moieties present on the compost surface. Plant biomass and TMs uptake (Cr 540 mg kg⁻¹ > Cd 330 mg kg⁻¹ > Pb 285 mg kg⁻¹) were significantly pronounced in shoots of sunflower under combined treatments at 10% TSWC amended soils. However, in seeds, TMs were found below detection limit (BDL) through atomic absorption spectrophotometry. Biochemical assays of sunflower including total chlorophyll content (18%), total soluble protein (45%), superoxide dismutase (80%) and catalase (75%) activities were also increased significantly at higher level of amendment in combination with microbes than in the control. Despite being high in TMs, high biomass in sunflower and associated elevation in biochemical products demonstrate the potential of TSW for valorization. Novelty statement: This study identifies the cost-effective management of multi metal contaminated tannery solid waste through deriving its compost along with autochthonous microbes as phytoextraction assistants by yielding higher plant biomass. This study suggests the use of composted TSW inoculated with selected autochthonous fungi and bacteria for enhancing sunflower’s biomass and enhancing the bioavailable fractions of toxic metals for phytoextraction.

Tannery solid waste is problematic and toxic biomass that has no other use than being dumped into the landfill or any dumping site. The present study provides an environmentally friendly method for sustainable management of toxic and unpleasant tannery solid waste by converting it into biochar, which is a carbon enriched byproduct of organic biomass produced through pyrolysis. The biochar derived from tannery solid waste contained a high percentage of carbon and nitrogen. The pH of biochar was alkaline (8.6) making it suitable for enhancing nutrient availability as compared to the initial pH of feedstock which was acidic (4.98). SEM analysis of biochar showed the presence of pores with some deposition of salts while no pores were observed in TSW feedstock. The surface area of biochar was 134.9 m2g-1, indicating that it can be used as a soil additive for enhancement of the absorption and adsorption processes as well as providing space for microbial activities. Amount of metals like Cr, Fe and Mg was high in biochar but it is presumed that bioavailability of these essential and non-essential metals to plants is limited. This study suggests the management of tannery solid waste by conversion to biochar and to use it as a soil additive because of properties like alkaline pH, increased surface area due to the presence of pores and essential elements such as Na, K, N and S.

Constructed wetland systems (CWSs) can offer cost-effective wastewater treatment in developing countries like Pakistan. This study focused on optimizing design and operational parameters of CWSs in horizontal surface flow (HSF), vertical surface flow (VSF), and hybrid mesocosms for treating sewage and textile effluents using local hydrophytes: Lemna minor, Typha latifolia, and Eichhornia crassipes. Pollutants and heavy metals (Cd, Cr, Cu, Pb, Ni, and Zn) were removed under different flow configurations, bedding materials, hydrophyte species, and hydraulic retention times (HRT) to optimize the overall contaminant removal efficiency (RE). Key findings indicated that the hybrid CWS achieved a maximum RE of 63.62% for total suspended solids (TSS) and 57.9% for biochemical oxygen demand (BOD) at an HRT of 3 days, with efficiencies declining at longer retention times. Additionally, the hybrid system showed maximum metal removal, with Cd and Cr RE reaching 75.2% and 70.5%, respectively. The study also highlighted the critical role of hydrophyte species and HRT in optimizing RE. Furthermore, the choice of hydrophyte species significantly influenced pollutant removal, with treatment cells containing mixed hydrophytes achieving the highest removal efficiencies (63.62%), followed by Eichhornia crassipes with high Cd (643.33 mgkg⁻¹) and Cr (1103.72 mgkg⁻¹) uptake. A lower HRT of 3 days resulted in the highest overall removal efficiency of 57.5%, which decreased with longer HRTs (from 6 to 9 days). Optimizing design and operational parameters is crucial for maximizing CWS treatment potential.