The paper presents unique research results on the effect of coking of diesel engine injector nozzles powered by mixtures of 10%, 20% and 30% biomethanol and diesel fuel compared to the engine being supplied with pure diesel fuel. The test results, obtained from an experiment conducted in accordance with the ISO 15550-1 standard, show the legitimacy of using biomethanol as an additive to diesel fuel due to the lower coking effect of the injector nozzles, which has a positive impact on the reduction of pollutant emissions during engine operation. Regarding the CEC PF-023 test, the tendency to reduce the coking tendency increases the percentage of biomethanol additive to diesel fuel. With a 10% share of biomethnol, the average coking effect of the injectors is over 1% lower, but with a share of 30% of bio-methanol, the coking effect is nearly 2% lower.
Compressed natural gas (CNG) in dual-fuel diesel engines offers environmental benefits but significantly increases unburned methane (CH4) emissions, especially at low engine loads. This study investigates the effectiveness of different catalytic converters in methane oxidation under transient test conditions (WHTC). Three types of catalysts (Pt-, Rh-, and Pd-based) were evaluated using a combined approach of empirical engine bench tests and mathematical modelling. The results showed that, under actual exhaust gas temperature conditions, the average methane conversion efficiencies were 3.7% for Pt, 17.7% for Rh, and 31.3% for Pd catalysts. Increasing the exhaust gas temperature by 50% improved the conversion efficiencies to 7.3%, 51.8%, and 69.2%, respectively. Despite this enhancement, none of the catalysts reached the 90% efficiency threshold required to increase the CNG content of the fuel beyond 6% without exceeding emission limits. The results highlight the need for high-activity Pd-based catalysts and optimised thermal management strategies to enable the broader adoption of dual-fuel engines, while complying with Euro VI standards.