Light absorption rates depends on the color of a substance. In this study, a new type of FPC was suggested, which utilizes the light absorption rate of the working fluid passing through a transparent collecting tube.
Multiwalled carbon nanotubes (MWCNTs) have excellent electrical conductivity and good chemical stability, and are used as counter electrodes in dye-sensitized solar cells (DSSCs). The counter electrodes collect electrons from the external circuit and catalyze the redox reaction in the electrolyte. Electrocatalysis is an important step for generating energy from triiodide reduction in DSSCs. In this study, chemically treated MWCNTs were investigated for improving the photovoltaic performance of DSSCs. The MWCNTs were modified through chemical oxidation with sulfuric acid/nitric acid (H2SO4/HNO3) or potassium persulfate/sodium hydroxide (K2S2O8/NaOH). Nanocellulose (CNC) was used as a dispersant to improve the photovoltaic performance and dispersibility as an alternative material for counter electrodes in DSSCs. The counter electrodes were prepared on fluorine-doped tin oxide (FTO) glass substrates by spin coating nanofluids. Morphological and structural investigations were performed using scanning transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectroscopy, and Raman spectroscopy. The electrical conductivity and UV light absorption of the DSSCs were analyzed to evaluate their photovoltaic performance. The results of these analyses showed that chemical functionalization and addition of CNC were effective for increasing the electrical conductivity and UV light absorption. Finally, all result trends were the same. Increasing the dispersibility of the counter electrode was found to improve the reduction of I3− at the interface between the MWCNTs and the electrolyte, thereby, improving the energy conversion efficiency.
Transparent conductive films are fundamental materials, currently used in several fields. Recently, due to their unique multifunctional properties, composite materials have started to be used in place of fluorine tin oxide and indium tin oxide in transparent conductive electrodes. However, the production of composite materials is still complicated and involves toxic chemicals. Through a simple and environmentally-friendly method, we synthesized new composite materials—conductive, transparent, and flexible films—that can be applied to the production of modern optoelectronic devices. An even dispersion of the nanoparticles was achieved by ultrasound excitation. Moreover, a series of morphological and structural investigations were conducted on the films by scanning and transmission electron microscopy, electrical conductivity, Raman spectroscopy, X-ray diffraction and testing their sheet resistance. The results indicated that the tested composite materials were ideal for film coating. The nanofluids containing multi-walled carbon nanotubes presented the highest electrical conductivity; nevertheless, all the composite nanofluids tended to have relatively high electrical conductivities. The flexible films with composite structures presented lower sheet resistances than those with single structures. Finally, the hybrid materials showed a higher transmittance.