In this work, the effects of a functionalization method involving different conditions and milling processes on the dispersion and thermal and electrical conductivity of multiwalled carbon nanotubes were studied. The surfaces of MWCNTs were modified using a mixture of sulfuric and nitric acid as an acid treatment and potassium persulfate and sodium hydroxide as an alkaline treatment to achieve more hydrophilic MWCNTs. The morphological and structural investigations were carried out using transmission electron microscopy and Fourier transform infrared spectroscopy. Furthermore, the dispersion characteristics and thermal and electrical conductivity of the as-prepared water-based nanofluids were measured. As a result, the dispersion characteristics revealed that the best dispersion and stability results were obtained for alkaline-treated MWCNTs using potassium persulfate and sodium hydroxide. The thermophysical study using a thermal conductivity analyzer exhibited that the thermal conductivity of the pristine MWCNT nanofluid (0.1 wt%) was enhanced from 603.5 to 610.4 mW/m·K and the electrical conductivity of the raw MWCNT nanofluid was increased from 16.2 to 125.8 μS/cm at 25 °C after alkaline treatment and milling processes, which were performed using planetary ball milling. Regarding the overall results, the milling process and mild alkaline oxidation process are more environmentally friendly, effective, and convenient for the functionalization of CNTs, without requiring any organic solvents or strong acids.

Light absorption rates depends on the color of a substance. In this study, a new type of FPC was suggested, which utilizes the light absorption rate of the working fluid passing through a transparent collecting tube.

Multiwalled carbon nanotubes (MWCNTs) have excellent electrical conductivity and good chemical stability, and are used as counter electrodes in dye-sensitized solar cells (DSSCs). The counter electrodes collect electrons from the external circuit and catalyze the redox reaction in the electrolyte. Electrocatalysis is an important step for generating energy from triiodide reduction in DSSCs. In this study, chemically treated MWCNTs were investigated for improving the photovoltaic performance of DSSCs. The MWCNTs were modified through chemical oxidation with sulfuric acid/nitric acid (H₂SO₄/HNO₃) or potassium persulfate/sodium hydroxide (K₂S₂O₈/NaOH). Nanocellulose (CNC) was used as a dispersant to improve the photovoltaic performance and dispersibility as an alternative material for counter electrodes in DSSCs. The counter electrodes were prepared on fluorine-doped tin oxide (FTO) glass substrates by spin coating nanofluids. Morphological and structural investigations were performed using scanning transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectroscopy, and Raman spectroscopy. The electrical conductivity and UV light absorption of the DSSCs were analyzed to evaluate their photovoltaic performance. The results of these analyses showed that chemical functionalization and addition of CNC were effective for increasing the electrical conductivity and UV light absorption. Finally, all result trends were the same. Increasing the dispersibility of the counter electrode was found to improve the reduction of I₃⁻ at the interface between the MWCNTs and the electrolyte, thereby, improving the energy conversion efficiency.

Over the years, solar collecting systems have gained interest in renewable energy. This study investigated improving the efficiency of the working fluid in thermal solar systems by using nanofluids with three concentrations of alumina, 0.1, 0.3, and 0.5 wt%. The UV-vis absorbance, electronic conductivity, and thermal transfer properties of the nanofluids were analyzed, and the thermal changes with exposure to solar radiation in an experimental collector system were measured by pyranometer. The electronic conductivity, thermal conductivity, and UV-vis absorbance increased with the alumina concentration. Moreover, the temperatures of the nanofluids increased more under solar irradiation than that of distilled water. This implies that the alumina nanofluids absorb solar energy more efficiently than water. The findings of this study suggest that the use of both alumina nanofluids and nanoparticles will improve the efficiency of thermal solar power systems.

Given the importance of nanofluid dispersion and stability, a number of approaches were proposed and applied to the nanofluid preparation process. Among these approaches, the noncovalent chemical process was intensively utilized because of its effective dispersion ability. For the noncovalent dispersion method, polymers and surfactants are typically used. In order to find an effective noncovalent dispersion method, several types of solutions were prepared in this study. The widely used naturally cellulose nanocrystal (CNC) aqueous solution was compared with several surfactant aqueous solutions. The dispersion characteristics of the prepared fluids were examined by UV/VIS spectroscopy at operating wavelengths ranging from 190 to 500 nm. Furthermore, the heat capacity and the electrical and thermal conductivity of the fluids were analyzed to evaluate their heat transfer performance and conductivity. The Lambda system was utilized for thermal conductivity measurement with operation at proper temperature ranges. The electrical conductivity of the fluids was measured by a conductivity meter. This experimental study revealed that the cellulose nanocrystal was an effective source of the noncovalent dispersion agent for thermal characteristics and was more eco-friendly than other surfactants. Moreover, cellulose aqueous solution can be used as a highly thermal efficient base fluid for nanofluid preparation.