For shallow groundwater, hydrogeochemical processes and quality assessment must be addressed because shallow groundwater is freely available in many parts of the globe. Due to recent anthropogenic activities and environmental changes in Sakrand, Sindh, Pakistan, the groundwater is extremely vulnerable. To provide safe drinking and agricultural water, hydrogeochemical analysis is required. Ninety-five groundwater samples were analyzed using agricultural and drinking indices to determine the hydrogeochemical parameters using multivariate analysis such as Pearson correlations, principal component cluster analysis, as well as Piper diagrams and Gibbs plot for drinking and agricultural indices. An abundance of ions was observed through the statistical summary; however, cations and anions were recorded in the orders Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ and HCO₃⁻ > Cl⁻ > SO₄²⁻ > NO₃⁻ > F⁻. The hydrogeochemical process used to quantify the major reactions occurring in the groundwater system showed rock dominance; the Piper diagrams evaluated the water type. A mixed pattern of calcium, magnesium, and chloride ions (Ca²⁺−Mg²⁺−Cl⁻ type) was observed. Additionally, the ion exchange method showed an excess of bicarbonate ions due to carbonic acid weathering. The water quality index (WQI) resulted 32.6% of groundwater being unsuitable for human consumption; however, the United States Salinity Laboratory (USSL) diagram showed 60% of samples were unsuitable for irrigation due to high salinity and the Wilcox diagram depicted 5% of samples lying in the unsuitable region. Most of the water samples were suitable for drinking; only a few samples were unsafe for drinking purposes for children due to the high hazard index.

Arsenic (As) contamination in groundwater is a worldwide concern for drinking water safety. Environmental changes and anthropogenic activities are making groundwater vulnerable in Pakistan, especially in Southern Punjab. This study explores the distribution, hydrogeochemical behavior, and pathways of As enrichment in groundwater and discusses the corresponding evolution mechanism, mobilization capability, and health risks. In total, 510 groundwater samples were collected from three tehsils in the Punjab province of Pakistan to analyze As and other physiochemical parameters. Arsenic concentration averaged 14.0 μg/L in Vehari, 11.0 μg/L in Burewala, and 13.0 μg/L in Mailsi. Piper-plots indicated the dominance of Na⁺, SO₄²⁻, Ca²⁺, and Mg²⁺ ions in the groundwater and the geochemical modeling showed negative saturation indices with calcium carbonate and salt minerals, including aragonite (CaCO₃), calcite (CaCO₃), dolomite (CaMg(CO₃)₂), and halite (NaCl). The dissolution process hinted at their potential roles in As mobilization in groundwater. These results were further validated with an inverse model of the dissolution of calcium-bearing mineral, and the exchange of cations between Ca²⁺ and Na⁺ in the studied area. Risk assessment suggested potential carcinogenic risks (CR > 10⁻⁴) for both children and adults, whereas children had a significant non-carcinogenic risk hazard quotient (HQ > 1). Accordingly, children had higher overall health risks than adults. Groundwater in Vehari and Mailsi was at higher risk than in Burewala. Our findings provide important and baseline information for groundwater As assessment at a provincial level, which is essential for initiating As health risk reduction. The current study also recommends efficient management strategies for As-contaminated groundwater.

Land is a vital component of nature around the world and is essential for humans, terrestrial plants, and animals. However, urbanization is growing worldwide and the groundwater quality in urban areas is declining due to rapid development, industrialization, and pollution. Hence, it is important to determine the hydrogeochemistry and changes concerning land use and land cover (LULC). This study was conducted to investigate the hydrogeochemical mechanism of Sargodha, one of Pakistan’s fastest-growing cities, during 2015 and 2021 under two different LULC indices named normalized difference vegetation index (NDVI) and normalized difference built-up index (NDBI). Forty-eight groundwater samples were collected in 2015 and 2021 to assess groundwater quality for domestic use and irrigation. The Piper diagram revealed that (Ca²⁺+Mg²⁺–HCO₃⁻+CO₃²⁻) and (Na⁺+K⁺–SO₄²⁻+Cl⁻) were the main components of hydrogeochemistry in both years. The Gibbs plot and silicate weathering of groundwater samples indicated that rock dominance and silicate weathering played a major role in aquifers. Additionally, the results showed that 4% of the groundwater in 2015 and 21% of the groundwater samples in 2021 were unfit for human consumption. However, 37% and 40% of samples were considered not fit for irrigation in 2015 and 2021, respectively. The LULC, NDVI, and NDBI clearly revealed higher urban areas in 2021 compared to 2015. The relationship between groundwater parameters and land use land cover indices (NDVI and NDBI) explained that none had a major relationship. The non-carcinogenic risk showed health quotient HQ < 1, indicating no severe health risk due to nitrate (NO₃⁻) exposure in the city. The current study suggests conducting future investigations considering a larger scale to recommend efficient management strategies, urbanization planning, and ensuring safe irrigation and drinking water to prevent groundwater pollution.

The global outbreak of coronavirus infectious disease-2019 (COVID-19) draws attentions in the transport and spread of Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) in aerosols, wastewater, surface water and solid wastes. As pathogens eventually enter the subsurface system, e.g., soils in the vadose zone and groundwater in the aquifers, they might survive for a prolonged period of time owing to the uniqueness of subsurface environment. In addition, pathogens can transport in groundwater and contaminate surrounding drinking water sources, possessing long-term and concealed risks to human society. This work critically reviews the influential factors of pathogen migration, unravelling the impacts of pathogenic characteristics, vadose zone physiochemical properties and hydrological variables on the migration of typical pathogens in subsurface system. An assessment algorithm and two rating/weighting schemes are proposed to evaluate the migration abilities and risks of pathogens in subsurface environment. As there is still no evidence about the presence and distribution of SARS-CoV-2 in the vadose zones and aquifers, this study also discusses the migration potential and behavior of SARS-CoV-2 viruses in subsurface environment, offering prospective clues and suggestions for its potential risks in drinking water and effective prevention and control from hydrogeological points of view.

The presence of residual Cr(VI) in soils causes groundwater contamination in aquifers, affecting the health of exposed populations. Initially, permeable reactive barriers(PRB) effectively removed Cr(VI) from groundwater. However, as PRB clogging increased and Cr(VI) was released from upstream soils, the contamination plume continued to spread downstream. By 2020, the level of contamination in the downstream was nearly identical to that in the upstream. The study results show that during normal operation, the PRB can successfully remove Cr(VI) from contaminated groundwater and reduce the carcinogenic and non-carcinogenic risks to humans from the downstream side of groundwater. However, the remediated groundwater still poses an unacceptable risk to human health. The sensitivity analysis revealed that the concentration of the pollutant was the most sensitive parameter and interacted significantly with other factors. Ultimately, it was determined that the residual Cr(VI) in the soil of the study region continues to contaminate the groundwater and constitutes a serious health danger to residents in the vicinity. As remediated groundwater still poses a severe threat to human health, PRB may not be as effective as people believe.