The development of nanotechnology has significantly impacted the improvement of photocatalytic performance of ZnO NPs. In this study synthesis of pure ZnO and Ag–ZnO nanoparticles via a co-precipitation method at varying Ag concentrations (1 %, 2 %, 3 %, 4 % and 6 %) to enhance their photo catalytic efficacy. X-ray diffraction (XRD) analysis estimates crystallite size which decreased by increasing Ag concentration, ranging from 30.6 nm (Pure ZnO) to 22.5 nm 6 % Ag-doped ZnO. Scanning electron microscopy (SEM) revealed decrease in particle size with increasing Ag content. UV–Vis spectroscopy indicating a narrowed band gap of optimal sample. Photocatalytic activity of the synthesized nanoparticles was evaluated using methylene orange (MO) dye degradation under light irradiation. The MO concentration exhibited a decrease with increasing irradiation time in the presence of photocatalysts. Recombination rate of NPs decreases by increasing the concentration of Ag i.e. 4%Ag dope ZnO NPs have lowest recombination rate and maximum degradation efficiency. FTIR analysis confirms the preparation of Ag-doped ZnO NPs. This improvement can be credited to the synergistic effect of Ag doping, leading to a narrowed band gap and potentially maximum degradation of MO by using Ag-doped ZnO NPs.

ITO/PEDOT:PSS/P3HT:PC₆₀BM/Mg-Al organic solar cells (OSCs) were fabricated depending on optimization of Poly(3-hexylthiophene-2,5-diyl) (P3HT) and phenyl-C61-Butyric-Acid-Methyl Ester (PC₆₀BM). The optimization of the active layer, P3HT:PC₆₀BM, was carried out under different spin frequencies coating from 900 to 3000 rpm. The post-production annealing temperature of all prepared OSC was studied from 130 to 190 °C. The holes transport layer, poly(3,4-ethylene dioxythiophene) polystyrene sulfonate (PEDOT:PSS), was prepared under constant conditions of 3000 rpm for 35 s, and annealing temperature 178 °C for 15 min. From our study, the optimum conditions for P3HT:PC₆₀BM were spin coating of 3000 rpm, and annealing temperature of 160 °C for 5 min. The optimum J-V parameters values for the prepared OSC were J_SC = 12.01 mA/cm², V_OC = 660 mV, FF = 59%, PCE = 4.65%, and EQE = 61%. A complete OSC with acceptable efficiency was designed using simple and low-cost techniques that may be utilized in the industry. Furthermore, the cost of the synthesized solar cell is projected to be around 1 $/cm², with the goal of lowering the cost and increasing efficiency in the future by incorporating more commercial nanostructured electron/hole transport components.

Currently, hydrogen generation via photocatalytic water splitting using semiconductors is regarded as a simple environmental solution to energy challenges. This paper discusses the effects of the doping of noble metals, Ir (3.0 at.%) and Ni (1.5–4.5 at.%), on the structure, morphology, optical properties, and photoelectrochemical performance of sol-gel-produced SnO₂ thin films. The incorporation of Ir and Ni influences the position of the peaks and the lattice characteristics of the tetragonal polycrystalline SnO₂ films. The films have a homogeneous, compact, and crack-free nanoparticulate morphology. As the doping level is increased, the grain size shrinks, and the films have a high proclivity for forming Sn–OH bonds. The optical bandgap of the un-doped film is 3.5 eV, which fluctuates depending on the doping elements and their ratios to 2.7 eV for the 3.0% Ni-doped SnO₂:Ir Photoelectrochemical (PEC) electrode. This electrode produces the highest photocurrent density (J_ph = 46.38 mA/cm²) and PEC hydrogen production rate (52.22 mmol h⁻¹cm⁻² at −1V), with an Incident-Photon-to-Current Efficiency (IPCE% )of 17.43% at 307 nm. The applied bias photon-to-current efficiency (ABPE) of this electrode is 1.038% at −0.839 V, with an offset of 0.391% at 0 V and 307 nm. These are the highest reported values for SnO₂-based PEC catalysts. The electrolyte type influences the J_ph values of photoelectrodes in the order J_ph(HCl) > J_ph(NaOH) > J_ph(Na₂SO₄). After 12 runs of reusability at −1 V, the optimized photoelectrode shows high stability and retains about 94.95% of its initial PEC performance, with a corrosion rate of 5.46 nm/year. This research provides a novel doping technique for the development of a highly active SnO₂-based photoelectrocatalyst for solar light-driven hydrogen fuel generation.

An aluminum oxide, Al₂O₃, template is prepared using a novel Ni imprinting method with high hexagonal pore accuracy and order. The pore diameter after the widening process is about 320 nm. TiO₂ layer is deposited inside the template using atomic layer deposition (ALD) followed by the deposition of 6 nm TiN thin film over the TiO₂ using a direct current (DC) sputtering unit. The prepared nanotubular TiN/TiO₂/Al₂O₃ was fully characterized using different analytical tools such as X-ray diffraction (XRD), Energy-dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM), and optical UV-Vis spectroscopy. Exploring the current-voltage relationships under different light intensities, wavelengths, and temperatures was used to investigate the electrode’s application before and after Au coating for H₂ production from sewage water splitting without the use of any sacrificing agents. All thermodynamic parameters were determined, as well as quantum efficiency (QE) and incident photon to current conversion efficiency (IPCE). The QE was 0.25% and 0.34% at 400 mW·cm⁻² for the photoelectrode before and after Au coating, respectively. Also, the activation energy was 27.22 and 18.84 kJ·mol⁻¹, the enthalpy was 24.26 and 15.77 J·mol⁻¹, and the entropy was 238.1 and 211.5 kJ⁻¹·mol⁻¹ before and after Au coating, respectively. Because of its high stability and low cost, the prepared photoelectrode may be suitable for industrial applications.