Lead halide perovskite quantum dots (PQDs) display remarkable photoelectric performance. However, defects such as weak stability in air and water environments limit the development of lead halide PQDs in solid-state light applications. Herein, centrifugal spinning is used for the fabrication of stable luminous PQD nanofibers. After immersion in water for 11 months, the PQD fibers still maintained considerable photoluminescence quantum yield, showing high stability in hostile environments. The water-stability mechanism of the fibers can be explained by the changing defect density, crystal growth of PQDs, and the molecular transformation at the fiber surface. The white LED based on the fibers exhibits satisfying color gamut performance (128% of National Television System Committee). Due to the short photoluminescence lifetime of PQDs, the communication potential is also considered. The fibers obtained by centrifugal spinning present a bandwidth of 11.2 MHz, showing promising performance for solid-state light and visible light communication applications.
In this report, a blue anti-transmission film (BATF) has been introduced to improve the color-conversion efficiency (CCE) and the stability of quantum dot (QD) films. The results indicate that the CCE can be increased by as much as 93% using 15 layers of BATFs under the same QD concentration. Therefore, the same CCE can be achieved using BATF-QD hybrid films with a lower QD concentration when compared with standard QD films. The hybrid and QD films with the same CCE of 60% were aged at an environmental temperature of 25°C and with a 10 mA injection current light-emitting diode source. The CCE and luminous efficacy that are gained by the hybrid film increased by 42.8% and 24.5%, respectively, when compared with that gained by the QD film after aging for the same time period of approximately 65 h. In addition, the hybrid film can effectively suppress the red-shift phenomenon of the QD light spectra, as well as an expansion of the full-width at half maximum. Consequently, these BATF-QD hybrid films with excellent optical performance and stability show great potential for illumination and display applications.
19 September 2019 in Journal of Electronic Packaging
Quantum dot (QD) attracts great attention in light-emitting diode (LED) packaging for high-quality light sources, while it leads to low light efficiency due to the significantly high reabsorption loss between QDs. Accordingly, we experimentally study the reabsorption properties of QD color convertors (QCCs) for LED packaging considering various thicknesses and concentrations under different injection current. The results indicate the QCC configuration with a small thickness and large concentration can have the same absorption ability for chip light as that with the opposite configuration, resulting in the same QD light proportion. However, the QCC configuration having smaller thickness is more useful to decrease the reabsorption loss, leading to higher radiant power (an increase of larger than 37.2%). Moreover, it is essential to gain a high radiant power of QD light with small reabsorption loss, which can be realized by combining QCCs with a low QD content and a source with a large injection current. Based on this simple and effective approach, a conversion loss smaller than 20%, close to their quantum yield, can be achieved, which is approximately four times smaller than that gained by QCCs with a high QD content. However, it introduces additional radiant power of chip light, suppressing further improvement in the QD light proportion. Much work is still required to make full use of the redundant chip light. This study provides a better understanding of the reabsorption properties of QCCs and can significantly accelerate their applications in illumination and display applications.
The ability to precisely obtain tunable spectrum of lead halide perovskite quantum dots (QDs) is very important for applications, such as in lighting and display. Herein, we report a microchannel reactor method for synthesis of CsPbBr3 QDs with tunable spectrum. By adjusting the temperature and velocity of the microchannel reactor, the emission peaks of CsPbBr3 QDs ranging from 520 nm to 430 nm were obtained, which is wider than that of QDs obtained in a traditional flask without changing halide component. The mechanism of photoluminescence (PL) spectral shift of CsPbBr3 QDs was investigated, the result shows that the supersaturation control enabled by the superior mass and heat transfer performance in the microchannel is the key to achieve the wide range of PL spectrum, with only a change in the setting of the temperature controller required. The wide spectrum of CsPbBr3 QDs can be applied to light-emitting diodes (LEDs), photoelectric sensors, lasers, etc.
Laser-driven white light illumination is considered as the next generation of high brightness white light source. The most common way to achieve laser-based white light is using a blue laser to excite phosphor/ silicone converter (reference converter). However, the relatively low thermal conductivity of phosphor limits most of the heat to its surface and cannot be dissipated effectively. In this work, a converter with copper sintering powder framework/paraffin (CPSF/P) embedded into the phosphor/silicone is proposed. As an internal heat transfer channel, copper powder sintering framework (CPSF) transfers heat to paraffin coated in porous skeleton, and then paraffin absorbs the generated heat through solid–liquid phase transition, which effectively dissipates the heat concentrated on the phosphor surface and improves its thermal stability. Under high-power laser excitation of 7.74 W, the surface temperature of the reference converter is up to 660 °C, while the maximum temperature of the CPSF/P converter is only 139 °C, which is reduced by 521 °C (78.9%). The results show that the proposed CPSF/P converter can withstand higher excitation power and show better thermal stability than the reference converter, which is helpful to obtain higher color stability. This provides an efficient heat dissipation scheme for high-power laser-driven lighting.