Constructed wetlands (CW) is an environmentally friendly technique for removing pollutants from wastewater and has been applied to municipal wastewater, petroleum refinery wastewater, agriculture drainage, acid mine drainage, etc. The past decade has seen a remarkable number of innovations in the exponentially growing field of microbiology. This manuscript covers a critical review of key aspects of CW, such as various types of CW, the contaminants and their removal mechanisms, degradation pathways, challenges and opportunities, materials, applications, and theory with a focus on recent advances in the last three decades. In addition, an attempt has been taken to project future advances in the field of CW and facilitate these advances by framing key unsolved problems in CW. Guidelines are prepared for the fast-growing CW field through the standardization of key design aspects. This review covers the evaluation of the current state-of-the-art of CW technology and provides definitions and performance metric nomenclature in an effort to unify the fast-growing CW community. It also contains an outlook on the emerging trends in CW and proposes future research and development directions.

The Kingdom of Saudi Arabia has been experiencing consistent growth in industrial processes and product use (IPPU). The IPPU’s emission has been following an increasing trend. This study investigated time-series and cross-sectional analyses of the IPPU sector. Petrochemical, iron and steel, and cement production are the leading source categories in the Kingdom. In recent years, aluminum, zinc, and titanium dioxide production industries were established. During the last ten years, a significant growth was observed in steel, ethylene, direct reduce iron (DRI), and cement production. The growth of this sector depends on many factors, including domestic and international demand, socioeconomic conditions, and the availability of feedstock. The emissions from IPPU without considering energy use was 78 million tons of CO₂ equivalent (CO₂eq) in 2020, and the cement industry was the highest emitter (35.5%), followed by petrochemical (32.3%) and iron and steel industries (16.8%). A scenario-based projection analysis was performed to estimate the range of emissions for the years up to 2050. The results show that the total emissions could reach between 199 and 426 million tons of CO₂eq in 2050. The Kingdom has started initiatives that mainly focus on climate change adaptation and economic divergence with mitigation co-benefits. In general, the focus of such initiatives is the energy sector. However, the timely accomplishment of the Saudi Vision 2030 and Saudi Green Initiative will affect mitigation scenarios significantly, including in the IPPU sector. The mitigation opportunities for this sector include (i) energy efficiency, (ii) emissions efficiency, (iii) material efficiency, (iv) the re-use of materials and recycling of products, (v) intensive and longer use of products, and (vi) demand management. The results of this study will support the Kingdom in developing an appropriate climate change mitigation roadmap.

Slags from the ferrous and nonferrous metallurgical industries have been used to treat toxic contaminants in water and wastewater. Using slag as a recycling or renewable resource rather than a waste product has environmental and economic benefits. Recycled smelter slags can be used in both in situ and ex situ treatment. However, their application has some limitations. One of the challenges is how to handle spent slag adsorbents, as they contain the accumulation of solid waste loaded with high concentrations of toxic contaminants. These challenges can be overcome by regeneration, recycling, reuse, and immobilization treatment of spent slag adsorbents. The present paper explored the scientific and technical information about the composition, reaction mechanisms, adsorption capacity, and opportunities of recycled slags while adsorbing toxic compounds from contaminated water. It comprehensively reviewed the current state of the art for using smelting slags as sustainable adsorbents for water and wastewater. The study revealed that ferrous slags are more effective in removing a wide range of toxic chemicals than nonferrous smelter slags. It investigated the necessary improved approach through the 5Rs (i.e., reduce, reuse, recycle, remove, and recover) using smelter slags as reactive materials in ex situ and in situ treatment.

The specific objectives of the study were to determine the approximate design parameters for filter bed and highlight the possible scope of using mixed iron oxides rich smelter slag for in situ or ex situ treatment. The batch and column study was conducted to assess the As removal capacities from contaminated water. X-ray fluorescence (XRF) analysis of the slag waste product determined the presence of large quantities of iron (Fe). In this study, the maximum removal capacities were found to be approximately 1.78 mg As per g of slag and 100% removal of As(V) was achieved during the first 30 days of three column operations. The changes in redox potential (E_h) values and the changes in effluent pH throughout the column operation period indicated redox reactions occurring in the system. The column experiments were modelled using a semi-analytic solution to the advection–dispersion–adsorption equation incorporated in the commercial software, Pollute V7. From the best-fit of the modelling results to the experimental breakthrough curves, the hydrodynamic dispersion coefficient (D) was found to be 0.0115 and 0.00775 m²/day for column 1 and column 2, respectively, and 0.00862 m²/day for column 3. The values of the distribution coefficient (K_D) were 0.18, 0.173 and 0.171 m³/kg or L/g for the three columns and 0.24 L/g from the batch test. The results from the experiments may be used to aid the design of a filter bed or reactive barrier in a scenario where the mixed iron oxides rich smelter waste product is used as a candidate reactive medium.