This study aimed to develop a highly functionalized adsorbent material for the removal of persistent anionic reactive dye. The modification process was commenced via a wet oxidation method by using zirconium salt as an impregnating material. The process led to an increase in the overall porosity, thermal stability and its oxidative functionality. The newly synthesised material was named ZrAC. The morphological and textural images revealed the irregular and eroded structures with an increase in porosity of the modified adsorbent. The results of chemical and spectral analysis disclosed that the material had successfully gained the oxidative functionality over the surface that will favour the removal of anionic dye. Equilibrium isotherms and adsorption kinetics studies insinuate that the overall process of adsorption follows the Sips isotherm and pseudo-second order kinetic model, respectively. The monolayer adsorption capacity of ZrAC was found to be superior (506 mg g⁻¹) to AC at 500 mg L⁻¹ concentration of persistent reactive dye. Moreover, the desorption capabilities of ZrAC were found to be more prominent, which finally affirms its potential use in a continuous flow system as a reusable adsorbent. Additionally, the stability of zirconium, corroborated from ICP-MS and XPS data, revealed the stability of zirconium after adsorption cycles thus verified its reusability. Thus, the characterization and experimental results of ZrAC strongly advocated its potential as a future adsorbent for removal of reactive dyes.

Sukinda is one of the most polluted regions of the globe due to chromium pollution. The study sheds light into the heavy metal pollution around the mining area and its effect on the health of the resident populace. The Cr(VI) was in the range of 0.027–2.48 mg/L in surface water and BDL–1.35 mg/L in the groundwater. Multivariate analysis revealed that mining activity was the main source of TCr, Cr(VI), and Zn in the surface water that warrants attention. Heavy metal evaluation index showed high levels of Fe, Mn, and Cr in groundwater that can pose serious threat to the exposed population. Cancer and non-cancer risk of Cr(VI) was higher than other metals in groundwater. The results revealed that the total cancer risk was 1.21E-03 and 1.05E-03 in adults and children, respectively, which exceeded the USEPA acceptable cancer health risk. High health risk was observed through oral intake of water, while both cancer and non-cancer risks were negligible through dermal contact. This study strongly advocates proper periodic assessment of drinking as well as surface water in the area and regulation to restrict the use of contaminated water for daily use.

Human health risk assessment from exposure to disinfection by-products (DBPs) during drinking and bathing water vary from country to country as per life expectancy, body mass index, water consumption pattern and individual concentration of DBPs component, etc.