The commercial application of copper bioleaching, an environmentally-friendly approach for low-grade and secondary mineral resources recycling, has increased worldwide since the 2000s. As the world’s second-largest economic entity and the largest developing country, China has the largest demand for metal resources, significantly advancing the theory and industrial technology of copper bioleaching. This paper reviews the exploration and application of copper bioleaching in China. Two typical bioleaching applications and technological processes, bioheap leaching at the Zijinshan Copper Mine and bioheap leaching at the Dexing Copper Mine, are introduced. The considerable research completed by researchers is summarized, especially focusing on the isolation and identification of leaching bacteria, the bioleaching mechanism and interface reactions, multistage percolation behavior, bioleaching system reconstruction, the multiphysics coupled model, and enhanced copper bioleaching from waste printed circuit boards (WPCBs). Based on this investigation in China, key trends and prospects in copper bioleaching—such as efficiency improvement, environmental protection, and improved technology applications—are proposed.

The increasing concern for decarbonization and sustainability in construction materials is calling for green binders to partially replace cement since its production is responsible for approximately 8% of global anthropogenic greenhouse gas emissions. Supplementary cementitious materials (SCMs), including fly ash, slag, silica fume, etc., can be used as a partial replacement for ordinary Portland cement (OPC) owing to reduced carbon dioxide emissions associated with OPC production. This study aims to investigate the sustainable use of waste oyster shell powder (OSP)-lithium slag (LS)-ground granulated blast furnace slag (GGBFS) ternary SCM system in green concrete. The effect of ternary SCMs to OPC ratio (0%, 10%, 20%, and 30%) on compressive strength and permeability of the green concrete were studied. The reaction products of the concrete containing OSP-LS-GGBFS SCM system were characterized by SEM and thermogravimetric analyses. The results obtained from this study revealed that the compressive strength of concrete mixed with ternary SCMs are improved compared with the reference specimens. The OSP-LS-GGBFS ternary SCMs-based mortars exhibited a lower porosity and permeability compared to the control specimens. However, when the substitution rate was 30%, the two parameters showed a decline. In addition, the samples incorporating ternary SCMs had a more refined pore structure and lower permeability than that of specimens adding OSP alone. This work expands the possibility of valorization of OSP for sustainable construction materials.

As cement manufacturing accounts for 8% of global CO₂ emissions, there is an urgent need to tackle the environmental impacts of cement production and address the decarbonization of construction materials. Adopting supplementary cementitious materials (SCMs), including fly ash, slag, silica fume, etc., can be used as a partial replacement for ordinary Portland cement (OPC) to reduce CO₂ emissions related to the OPC industry, while providing benefits for waste valorization. This study aims to explore the sustainable utilization of a waste oyster shell powder (OSP)–lithium slag (LS)–ground granulated blast furnace slag (GGBFS) ternary SCM system in green concrete. The effect of OSP fineness on compressive strength, hydration products, pore structure, and transport properties in ternary SCM-based mortars was studied using a wide array of experimental techniques, including thermogravimetric analysis (TGA), scanning electron microscopy (SEM) analysis, Mercury intrusion porosimetry (MIP), the water absorption test and the rapid chloride penetration test (RCPT). The results revealed that the concrete with the ternary SCMs showed equivalent compressive strength compared to reference specimens. The water absorption and chloride ion charge of the RCPT in the concrete containing the ternary SCMs decreased by up to 30% and 81.4%, respectively. It was observed that the specimens incorporating the OSP with a mesh size of 3000 exhibited the highest compressive strength and the most refined microstructure.

During their service life, concrete structures are subjected to combined fluctuations of temperature and relative humidity, which can influence their durability and service life performance. Self-healing has in recent years attracted great interest to mitigate the effects of such environmental exposure on concrete structures. Several studies have explored the autogenous crack self-healing in concrete incorporating superabsorbent polymers (SAPs) and exposed to different environments. However, none of the published studies to date has investigated the self-healing in concrete incorporating SAPs under a combined change in temperature and relative humidity. In the present study, the crack width changes due to self-healing of cement mortars incorporating SAPs under a combined change of temperature and relative humidity were investigated and quantified using micro-computed tomography and three-dimensional image analysis. A varying dosage of SAPs expressed as a percentage (0.5%, 1% and 2%) of the cement mass was incorporated in the mortar mixtures. In addition, the influence of other environments such as continuous water submersion and cyclic wetting and drying was studied and quantified. The results of segmentation and quantification analysis of X-ray µCT scans showed that mortar specimens incorporating 1% SAPs and exposed to environments with a combined change in temperature and relative humidity exhibited less self-healing (around 6.58% of healing efficiency). Conversely, when specimens were subjected to cyclic wetting and drying or water submersion, the healing efficiency increased to 19.11% and 26.32%, respectively. It appears that to achieve sustained self-healing of cracks, novel engineered systems that can assure an internal supply of moisture are needed.

Cross-laminated timber (CLT) is an innovative wood panel composite that has been attracting growing interest worldwide. Apart from its economic benefits, CLT takes full advantage of both the tensile strength parallel to the wood grain and its compressive strength perpendicular to the grain, which enhances the load bearing capacity of the composite. However, traditional CLT panels are made with glue, which can expire and lose effectiveness over time, compromising the CLT panel mechanical strength. To mitigate such shortcomings of conventional CLT panels, we pioneer herein nail-cross-laminated timber (NCLT) panels with more reliable connection system. This study investigates the flexural performance of NCLT panels made with different types of nails and explores the effects of key design parameters including the nail incidence angle, nail type, total number of nails, and number of layers. Results show that NCLT panels have better flexural performance than traditional CLT panels. The failure mode of NCLT panels depends on the nail angle, nail type, and quantity of nails. A modified formula for predicting the flexural bearing capacity of NCLT panels was proposed and proven accurate. The findings could blaze the trail for potential applications of NCLT panels as a sustainable and resilient construction composite for lightweight structures.