In this work, we present a novel microfluidic-based approach for investigating the thermodynamics of multicomponent systems at high pressures and temperatures, such as determining miscibility diagrams and critical coordinates of complex mixtures. The developed method is primarily based on (i) bubble and dew point detection through optical characterization and (ii) the use of a so-called dynamic stop-flow measurement mode for fast screening of the diagram parameters, mainly P, T and composition. Our strategy was validated through the studies of model binary CO₂–alkane mixtures. The obtained results were then compared to PREOS-calculated and literature data. We later applied this strategy for determining ternary and quaternary mixtures critical coordinates. This approach has equal accuracy compared to conventional high-pressure optical cell methods but allows for a much faster phase diagram determination, taking advantage of improved heat and mass transfers on the microscale and of the dynamic stop-flow approach.

A modelling method is proposed to highlight the effect of cambial age on the effective modulus of elasticity of laminated veneer lumber (LVL) according to bending direction and veneer thickness. This approach is relevant for industrial purposes in order to optimize the performance of LVL products. LVL is used increasingly in structural applications. It is obtained from a peeling process, where product’s properties depend on cambial age, hence depend on radial position in the log. This study aims to highlight how radial variations of properties and cambial age impact the mechanical behaviour of LVL panels. An analytical mechanical model has been designed to predict the modulus of elasticity of samples made from poplar LVL panels. The originality of the model resides in the integration of different data from the literature dealing with the variation in wood properties along the radius of the log. The simulation of the peeling process leads to veneers with different mechanical properties, which are randomly assembled in LVL panels. The model shows a correct mechanical behaviour prediction in comparison with experimental results of the literature, in particular with the decrease in MOE in LVL made of juvenile wood. It highlights that the bending direction and veneer thickness have no influence on the average MOE, but affect MOE dispersion. This paper proposed an adequate model to predict mechanical behaviour in the elastic domain of LVL panels based on the properties of raw wood material.