The steady-state electrical conduction current for single and multilayer polyimide (PI) nanocomposite films was observed at the low and high electric field for different temperatures. Experimental data were fitted to conduction models to investigate the dominant conduction mechanism in these films. In most films, space charge limited current (SCLC) and Poole–Frenkel current displayed dominant conduction. At a high electric field, the ohmic conduction was replaced by current–voltage dependency. Higher conduction current was observed for nanocomposite films at a lower temperature, but it declined at a higher temperature. PI nanocomposite multilayer films showed a huge reduction in the conduction current at higher electric fields and temperatures. The conclusions derived in this study would provide the empirical basis and early breakdown phenomenon explanation when performing dielectric strength and partial discharge measurements of PI-based nanocomposite insulation systems of electric motors.
15 August 2020 in Journal of Applied Polymer Science
The implementation of space charge measurements based on thermal perturbation on thin films requires an improvement of the temperature distribution estimation at the surface and in the depth of dielectric materials for getting reliable space charge profile measurements. Absolute temperature variations are needed, both in time and space. The present contribution addresses surface temperature measurements based on either thermoelectric or bolometric effects. Both responses have been measured on copper-coated silicon nitride layers and gold-coated polypropylene films heated with a Nd:YAG laser pulse. It is shown that high temporal resolution thermal response can be obtained through the bolometric response and that the information appears nearly independent on the nature of the coating electrode. The setup developed provides good signal to noise ratio for heated electrodes of a few ohm resistance. Strategies are still to develop to get the temperature profile in the insulating sample layer.
The present work deals with the study of the electrical behavior of cross-linked polyethylene (XLPE) used for HVDC cable insulation. The aim is to better understand the influences of electrical and thermal stresses on the insulating material in order to provide useful information for designing HVDC cables. This study was carried out on Rogowski samples made of XLPE insulation with semiconductive electrodes, aged for more than 3 years (1220 days) at three different temperatures (70, 80 and 90 °C) under two DC electric fields (30 and 60 kV/mm). Dielectric loss factor, volume resistivity and space charge accumulation were measured. Results are analyzed and cross-correlated, in order to propose possible ageing kinetics.
This paper concerns several epoxy resin nanocomposites. A DER 332 epoxy resin was chosen as matrix and nanosilica and/or Boron Nitride were chosen as fillers. Conduction currents results obtained using Polarization and Depolarization Current (PDC) tests at room temperature are presented and discussed. Different conduction phenomena were observed following the analysis of the variation of the current density versus the applied electric field. Using the depolarization currents obtained at room temperature under several applied electric fields, time to frequency domain transformation was performed. For this purpose, the currents were fitted using a general time response function based on Curie-von Schweidler law and on the transform proposed by Hamon. The empiric law proposed by Helegeson was also investigated. The time to frequency domain transformed spectra were compared with those obtained by Dielectric Spectroscopy.
Surface charge accumulation in the spacer modifies local electric fields, which restricts the industrialization of high voltage direct current (HVDC) gas-insulated transmission lines (GILs). In this paper, the state of art in gas/solid interface charging physics and models, covering areas of charge measurement techniques, charge transport mechanisms, charge related DC surface flashover models, and charge control methods, is reviewed and discussed. Key issues that should be considered in future studies are summarized and proposed. The purpose of this work is to provide a brief update on the most important and latest progress in this research area, and to educate readers as to the current state of the gas-solid interface charging phenomenon, which has seen great progress in the past few years.