In recent years, biochar has emerged as a remarkable biosourced material for addressing global environmental, agricultural, biomedical, and energy challenges. However, the performances of biochar rest in part on finely tuning its surface chemical properties, intended to obtain specific functionalities. In this review, we tackle the surface treatment of biochar with silane and other coupling agents such as diazonium salts, titanates, ionic/non-ionic surfactants, as well as nitrogen-containing (macro)molecules. We summarize the recent progress achieved mostly in the last five years and correlate the nature and extent of functionalization to eye-catchy end applications of the surface-engineered biochar.

Mesoporous silica SBA-15 was prepared and functionalized by (3-glycidyloxypropyl)trimethoxysilane in order to bind 2-aminothiazole and aminopropyl-triazole ligands. These groups were immobilized through two distinct chemistry routes: reaction of epoxy with amine resulting in AMT-SBA-15 for the former, and epoxy ring opening followed by 1,3-dipolar cycloaddition click reaction providing Tr-SBA-15, for the latter. These ligand-functionalized SBA-15 materials served as reactive platforms for the in situ deposition of silver nanoparticles from the reduction of silver nitrate. The silver-decorated hybrid Ag/AMT-SBA-15 and Ag/Tr-SBA-15 samples, as well as their precursors, were characterized by X-ray diffraction (XRD), N₂ adsorption–desorption isotherms, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The silver-decorated hybrid materials were evaluated as catalysts for the reduction of methylene blue; the results showed excellent catalytic efficiencies with reduction rate constants of 14.3 × 10⁻³ and 9.4 × 10⁻³ s⁻¹ for Ag/Tr-SBA-15 and Ag/AMT-SBA-15, respectively. These values are comparable or higher than those claimed in the literature for similar application.

Immobilization of nanocatalysts on biochar is receiving unprecedented interest among material and catalysis scientists due to its simplicity, versatility, and high efficiency. Herein, we propose a new direct approach to obtain bimetallic copper/nickel nanoparticles loaded on olive stone biochar. The bimetallic-coated biochar and the reference materials, namely bare biochar, copper rich-loaded biochar, and nickel-loaded biochar, were prepared by pyrolysis from olive pit powder particles impregnated first with citric acid (CA) and then with copper and nickel nitrates at 400 °C under nitrogen flow. We employed citric acid in the process in order to examine its effect on the structural and textural properties of biochar supporting the metallic nanoparticles. Surprisingly, citric acid induced the formation of agglomerated or even raspberry-shaped bimetallic copper/nickel nanoparticles. Large 450–500 nm agglomerates of ~80 nm bimetallic CuNi NPs were noted for B-CA@CuNi. Interestingly, for biochar material prepared with initial Cu/Ni = 10 molar ratio (B-CA@CuNi_10/1), the bimetallic NPs formed unusual nanoraspberries (174 ± 8 nm in size), which were agglomerates of individual 10–20 nm CuNi_10/1 nanoparticles. The B-CA@CuNi and reference materials were characterized by Raman spectroscopy, scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and magnetometry. The B-CA@CuNi and B-CA@Ni materials could be efficiently attracted with a magnet but not B-CA@CuNi_10/1 due to the low nickel loading. B-CA@CuNi was tested as a catalyst for the degradation of methyl orange (MO). Discoloration was noted within 10 min, much faster than a similar material prepared in the absence of CA. B-CA@CuNi could be recycled at least 3 times while still exhibiting the same fast catalytic discoloration performance. This paper stresses the important role of citric acid in shaping bimetallic nanoparticles loaded in situ on biochar during the slow pyrolysis process and in enabling faster catalytic discoloration of organic dye solution.

The aim of the present work is to valorise the brewing industry’s waste, i.e., brewer’s spent grain (BSG), into functional biocarbon for environmental catalysis applications. In this context, cost-effective and environmentally friendly biochar support coated with in-situ-generated Ag-Cu nanocrystals, was developed via the wet impregnation of BSG biomass powder with copper (II) nitrate trihydrate and silver nitrate aqueous solution prior to pyrolysis at moderate temperature (500 °C). Small-size homogenously distributed Ag-Cu nanocrystals (≤80 nm) on the surface of the biochar (Biochar@Ag-Cu) were observed by field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM). Elemental compositions were determined by X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray analysis (EDX). The crystalline nature of the nanoparticles was confirmed by X-ray powder diffraction (XRD). Information about the thermal stability of the materials and quality were obtained by thermogravimetric analysis (TGA) and Raman, respectively. The potentiality of the Biochar@Ag-Cu catalyst in the field of pollutant removal is demonstrated by taking methyl orange and methylene blue as model dyes. A kinetics study was performed and analyzed by UV–vis spectroscopy. Its highly active catalytic nature is proved by the complete mineralization of the methyl orange dye (100%) through oxidative degradation. The reusability of the catalyst has shown 96% removal efficiency after 3 cycles. The linear plot of −Ln (C_A/C₀) vs. time (R² = 0.9892) reveals that the mineralization of the methyl orange dye follows pseudo-first-order kinetics (k = 0.603 × 10⁻² min⁻¹). A methyl orange + methylene blue dye mixture degradation study has revealed the faster kinetics of the present catalyst towards methylene blue degradation. The current study suggests that BSG Biochar@Ag-Cu can be a potential candidate in contribution towards SDG 6.