Composite materials with carbon and glass fibers in an epoxy matrix are widely used systems due to their excellent mechanical parameters, and machining is a standard finishing operation in their manufacture. Previous studies focused exclusively on the characteristics of the fibers released into the air. This work aimed to analyze the nature of the material waste that remains on the work surface after machining. The dust on the work surface is made up of fibers and a polymer matrix, and due to its dimensions and chemical stability, it is a potentially dangerous inhalable material currently treated as regular waste. The smallest sizes of destroyed carbon fibers were generated during drilling and grinding (0.1 μm), and the smallest glass fiber particles were generated during milling (0.05 μm). Due to their nature, carbon fibers break by a tough fracture, and glass fibers by a brittle fracture. In both cases, the rupture of the fibers was perpendicular to or at an angle to the longitudinal axis of the fibers. The average lengths of destroyed carbon fibers from the tested processes ranged from 15 to 20 µm and 30 to 60 µm for glass fibers.
Conventional dry machining (without process media) of carbon fibre composite materials (CFRP) produces tiny chips/dust particles that float in the air and cause health hazards to the machining operator. The present study investigates the effect of cutting conditions (cutting speed, feed per tooth and depth of cut) during CFRP milling on the size, shape and amount of harmful dust particles. For the present study, one type of cutting tool (CVD diamond-coated carbide) was used directly for machining CFRP. The analysis of harmful dust particles was carried out on a Tescan Mira 3 (Tescan, Brno, Czech Republic) scanning electron microscope and a Keyence VK-X 1000 (Keyence, Itasca, IL, USA) confocal microscope. The results show that with the combination of higher feed per tooth (mm) and lower cutting speed, for specific CFRP materials, the size and shape of harmful dust particles is reduced. Particles ranging in size from 2.2 to 99 μm were deposited on the filters. Smaller particles were retained on the tool body (1.7 to 40 μm). Similar particle sizes were deposited on the machine and in the work area.
Carbon fiber (CF) and carbon fiber-reinforced polymers (CFRPs) are widely used in the aerospace, automotive, and energy sectors due to their high strength, stiffness, and low density. However, significant waste is generated during manufacturing and after the use of CFRPs. Traditional disposal methods like landfilling and incineration are unsustainable. CFRP machining processes, such as drilling and milling, produce fine chips and dust that are difficult to recycle due to their heterogeneity and contamination. This study investigates the oxidation behavior of CFRP drilling waste from two types of materials (tube and plate) under oxidative (non-inert) conditions. Thermogravimetric analysis (TGA) was performed from 200 °C to 800 °C to assess weight loss related to polymer degradation and carbon fiber integrity. Scanning electron microscopy (SEM) was used to analyze morphological changes and fiber damage. The optimal range for removing the polymer matrix without significant fiber degradation has been identified as 500–600 °C. At temperatures above 700 °C, notable surface and internal fiber damage occurred, along with nanostructure formation, which may pose health and environmental risks. The results show that partial fiber recovery is possible under ambient conditions, and this must be considered regarding the harmful risks to the human body if submicron particles are inhaled. This research supports sustainable CFRP recycling and fire hazard mitigation.
The present study focuses on the elimination of delamination during the drilling of a linen-based biocomposite material in epoxy resin used for the manufacture of sports kayaks, depending on the tool material, cutting conditions, and the use of additional wooden support plates. In the present study, HSS (high-speed steel) and Carbide cutting tools without coatings, with the same geometry and two types of cutting conditions (n = 1500 rpm, fn = 0.05 and 0.1 mm/rev) were used. A Sololite-type wooden backing plate was used to aid in reducing delamination. The results show that the additional support plates significantly reduced delamination by up to 80% both at the material inlet and especially at the drill hole outlet. In this study, the use of a lower feed rate (fn = 0.05 mm/rev) per tooth was shown to have a significant effect on reducing the delamination of biocomposite materials with flax fibers, which are generally known to be difficult to machine. The Carbide cutting tool shows significantly better results both in terms of its wear and in terms of delamination of the biocomposite material. The highest delamination was obtained without the use of a backing board at the tool exit after 50 drilled holes of 3509 µm. With the use of a backing board, this delamination decreased to 693 µm after 50 drilled holes.
The objective of the present work was to prepare hybrid epoxy composites with improved mechanical and thermal properties. The simultaneous use of two different modifiers in an epoxy resin was motivated by the expected occurrence of synergistic effects on the performance properties of the matrix. Such a hybrid composite can be used in more severe conditions and/or in broader application areas. Hybrid epoxy composites were prepared with polyurethane (PUR), Nanomer nanoclay and carbon nanotubes (CNT), followed by the evaluation of their mechanical and thermal properties. Synergistic improvements in mechanical properties of hybrid composites were observed for 0.5 wt% Nanomer and 1 wt% carbon nanotubes (CNT), 7.5 wt% PUR and 1 wt% CNT, and 5 wt% PUR and 1 wt% CNT, confirming the occurrence of synergistic effects as to the impact strength (IS) of the matrices, compared to binary systems. The toughening induced by CNT/Nanomer modifiers can be attributed to the specific interfacial interactions between the two nanoparticles, while in the case of CNT/PUR, it can be explained by the combined effects of flexible polymer chains and the specific arrangement of nanoparticles in epoxy systems. Spectroscopy analysis confirmed the occurrence of interaction between OH groups in the epoxy matrix with CNT and reactive groups of PUR. The fracture surface showed plastic deformations, with good dispersion of CNT, explaining the improved mechanical properties of the matrix composites.
The influence of machining parameters on the generation of dust particles during the machining of carbon fiber-reinforced polymer (CFRP) composites remains insufficiently understood. These particles, which stay suspended in the air, pose a serious health risk to operators. This study examined the effects of cutting conditions—specifically cutting speed, feed per tooth, and depth of cut—and the impact of delaminations formed during CFRP drilling on the size, shape, and quantity of hazardous dust particles. Experiments were conducted using a commercially available uncoated cemented carbide cutting tool. The analysis of dust particle size and morphology, as well as the evaluation of delamination, was performed using microscopic and tomographic methods. The results demonstrate that reducing the cutting speed led to a decrease in particle size for the investigated CFRP material. Furthermore, it was observed that tool wear results in the generation of smaller particles. Simultaneous delamination during drilling was found to significantly affect the structural integrity of the composite material.