Heterogeneous photocatalysis has emerged as a versatile and sustainable technology for the degradation of emerging contaminants in water. This review highlights recent advancements in photocatalysts design, including band gap engineering, heterojunction formation, and plasmonic enhancement to enable visible-light activation. Various reactor configurations, such as slurry, immobilized, annular, flat plate, and membrane-based systems, are examined in terms of their efficiency, scalability, and operational challenges. Hybrid systems combining photocatalysis with membrane filtration, adsorption, Fenton processes, and biological treatments demonstrate improved removal efficiency and broader applicability. Energy performance metrics such as quantum yield and electrical energy per order are discussed as essential tools for evaluating system feasibility. Special attention is given to solar-driven reactors and smart responsive materials, which enhance adaptability and sustainability. Additionally, artificial intelligence and machine learning approaches are explored as accelerators for catalyst discovery and process optimization. Altogether, these advances position photocatalysis as a key component in future water treatment strategies, particularly in decentralized and low-resource contexts. The integration of material innovation, system design, and data-driven optimization underlines the potential of photocatalysis to contribute to global efforts in environmental protection and sustainable development.

This work highlights new insights into the performance of TiO₂ doped with noble metal catalysts for the photocatalytic degradation of organic water pollutants. Different samples of titanium dioxide doped with noble metals (Au and Pd) were successfully synthesized via incipient wet impregnation (IWI) and ultrasound-assisted impregnation (US) methods. X-ray diffraction, scanning electron microscopy and UV-Vis reflectance spectroscopy were used for the characterization of the obtained materials. Their photocatalytic efficiency was investigated in aqueous suspension thorough a series of laboratory tests performed under ultraviolet (UV-A) irradiation conditions using 2,4 dinitrophenol (2,4 DNP) as a target molecule. The results clearly show that the method used for the catalyst synthesis affects its photocatalytic activity. It was found that the samples prepared by the IWI method exhibited high photocatalytic activity, and the removal rate obtained with TiO₂-Pd/IWI was higher than that found for TiO₂-Au/IWI. Furthermore, for the best catalyst, some extra photocatalytic experiments were conducted with rhodamine 6G (R6G), a highly stable molecule with a very different chemical structure to 2,4 DNP, in order to check the reactivity of this material. Moreover, the recycling experiments carried out with TiO₂-Pd/IWI clearly demonstrated the high photocatalytic stability of this material for the degradation of 2,4 DNP. All of the collected data confirmed the interesting photocatalytic potential of the selected catalyst in the elimination of organic pollutants with no obvious change in its reactivity after four reaction cycles, which is very promising for promoting future applications in water depollution.

Emerging pollutants such as pharmaceuticals and synthetic dyes increasingly enter agricultural soils through irrigation with treated or untreated wastewater and via biosolid amendments, raising concerns for plant health, soil functionality, and food chain safety. Their environmental behavior is governed by complex interactions between compound physicochemistry, soil properties, and plant physiology, leading to variable persistence, mobility, and ecotoxicological outcomes. This review synthesizes current evidence on the fate, uptake, and phytotoxic effects of drug and dye contaminants in plant–soil systems, and provides a comparative assessment of ecological risks before and after photocatalytic wastewater treatment. The analysis integrates findings from soil- and hydroponic-based studies addressing pollutant sorption–desorption dynamics, leaching, microbial transformations, and plant responses ranging from germination impairment and biomass reduction to oxidative stress and genotoxicity. Special emphasis is given to the formation and behavior of transformation products generated during photocatalytic degradation, which may display altered mobility or toxicity relative to parent compounds. Comparative evaluation reveals that photocatalysis substantially reduces contaminant loads and toxicity in many cases, although incomplete mineralization or the formation of reactive intermediates can sustain or enhance adverse effects under certain conditions. By linking pollutant fate mechanisms with plant and soil responses, this review highlights both the potential and the limitations of photocatalysis as a sustainable strategy for safeguarding agroecosystems in the context of expanding wastewater reuse.

This work demonstrates new evidence of the efficient destruction and mineralization of an emergent organic pollutant using UV-A and titanium nanosized catalysts. The target compound considered in this work is the primary metabolite of a lipid regulator drug, clofibrate, identified in many studies as refractory during conventional wastewater treatment. The photocatalytic performance study was carried out in batch mode at laboratory scale, in aqueous suspension. Kinetic data showed that titanium dioxide P25 Aeroxide^® exhibits the highest photocatalytic efficiency compared to the other investigated catalysts. Pollutant degradation and mineralization efficiencies strongly increased when decreasing the initial substrate concentration. Target molecules oxidized faster when the catalyst load increased, and the mineralization was enhanced under acidic conditions: 92% of mineralization was achieved at pH 4 after 190 min of reaction. Radical quenching assays confirmed that HO^• and ( ${\mathrm{h}}_{\mathrm{vb}}^{+})$ were the reactive oxygen species involved in the photocatalytic oxidation of the considered pollutant. In addition, further results revealed that the removal efficiency decreased in real water matrices. Finally, data collected through a series of phytotoxicity tests demonstrated that the photocatalytic process considerably reduces the toxicity of the treated solutions, confirming the process’s effectiveness in the removal of persistent and biorefractory emergent organic water pollutants.