To investigate the effects of rapid urbanization on water pollution, the water quality, daily unit area pollutant load, water quality score, and real-time water quality index for the Jinwi River watershed were assessed. The contribution of known pollution sources was identified using multivariate statistical analysis and absolute principal component score-multiple linear regression. The water quality data were collected during the dry and wet seasons to compare the pollution characteristics with varying precipitation levels and flow rates. The highest level of urbanization is present in the upstream areas of the Hwangguji and Osan Streams. Most of the water quality parameter values were the highest in the downstream areas after the polluted rivers merged. The results showed a dilution effect with a lower pollution level in the wet season. Conversely, the daily unit area pollutant load was higher in the rainy season, indicating that the pollutants increased as the flow rate increased. A cluster analysis identified that the downstream water quality parameters are quite different from the upstream values. Upstream is an urban area with relatively high organic matter and nutrient loads. The upstream sewage treatment facilities were the main pollution sources. This study provides basic data for policymakers in urban water quality management.

To safeguard aquatic environments in and around the Han River watershed in South Korea, a multivariate statistical evaluation of trace elements, a trace element concentration analysis and source determination, and a human health risk assessment were conducted on 10 trace elements at 25 sites. The results demonstrated that the Han River watershed was mainly affected by anthropogenic activities (traffic/industrial activity). The range of concentrations was arranged in descending order: Fe (217.13 ± 301.03 µg/L) > Mn (102.36 ± 153.04 µg/L) > Zn (23.33 ± 79.63 µg/L) > Ba (29.05 ± 12.37 µg/L) > Ni (5.14 ± 11.57 µg/L) > Cu (3.80 ± 3.56 µg/L) > Pb (0.46 ± 0.52 µg/L) > Se (0.06 ± 0.04 µg/L) > Cd (0.01 ± 0.01 µg/L) > Ag (0.004 ± 0.013 µg/L). The hazard index values of trace elements in surface water for combined pathways (ingestion and dermal contact) were < 1.0 for both adults and children, indicating no possible human health hazards. The estimated total cancer risk did not exceed the acceptable limit (1 × 10⁻⁴) for adults and children. The findings of this study provide data-driven guidelines for water environment policy decisions in the study area.

This study aimed to investigate the irrigation water quality, major pollution sources, and human health hazards by focusing on heavy metal concentrations in the surface water of the Han River watershed, South Korea that supplies water for consumption and irrigation. Here, Mn was found to have the highest mean concentration, with the maximum concentration recorded at IH-2. The heavy metal concentrations were higher during summer and fall than that during spring. The mean concentration of heavy metals was relatively high in the downtown area (1.8 times) and downstream of the wastewater treatment facilities (1.3 times), indicating that the wastewater treatment facilities (WTFs) may be the primary source of pollution. Water at most of the sites were found to be suitable for irrigation. However, the sodium absorption ratio and soluble sodium percentage indicated that IH-2 was unsuitable. The results of the principal component analysis indicated that anthropogenic (vehicle and industrial) activities were the primary sources of metal pollution. Ingestion was identified as the primary exposure pathway in terms of health risks. However, the hazard quotients and hazard index for all pathways were below the safety limit (<1) for children and adults.

Human and veterinary pharmaceuticals are being increasingly used for disease treatment; hence, their distribution and factors influencing them in the aquatic environment need to be investigated. This study observed the effect of human and animal populations, usage, purchasing criteria (prescription vs. non-prescription), and land use to identify the spatio-temporal distribution of eight pharmaceuticals at twenty-four sites of the tributaries of the Han River watershed. In rural areas, the mean concentration (detection frequency) of non-prescription pharmaceuticals (NPPs) was higher (lower) compared to that of prescription pharmaceuticals (PPs); in urban areas, a reverse trend was observed. Pharmaceutical concentrations in urban and rural areas were mainly affected by wastewater treatment plants (WWTPs) and non-point sources, respectively; concentrations were higher downstream (4.9 times) than upstream of the WWTPs. The concentration distribution (according to the target) was as follows: human–veterinary > human > veterinary. Correlation between total concentration and total usage of the pharmaceuticals was high, except for NPPs. Most livestock and land use (except cropland) were significantly positively correlated with pharmaceutical concentrations. Concentrations were mainly higher (1.5 times) during cold seasons than during warm seasons. The results of this study can assist policymakers in managing pharmaceutical pollutants while prioritizing emerging pollutants.

Volatile organic compounds (VOCs) are ubiquitous pollutants in surface water, which is the main source of drinking water in South Korea. We investigated the behavior (concentration, distribution, and environmental risk) of eleven selected VOCs in the surface water of the Han River tributaries using purge-and-trap gas chromatography/mass spectrometry. The average concentration of VOCs was 0.29 ± 0.47 μg/L. Chloroform and trichloroethylene (TCE) were the major pollutants, accounting for approximately 64.2% and 25.6% of the total concentration, respectively, and showing that halocarbons accounted for 94%. Chloroform was positively correlated with TCE and xylenes, and TCE was positively correlated with tetrachloroethylene (PCE). No differences were observed in the temporal average concentrations of total VOCs, but the concentrations differed significantly among sub-watershed areas. The Imjin-Hantan River, Han River mainstream, and Anseong Stream watersheds had a high positive association with TCE, whereas the Bukhan and Namhan River watersheds had a strong positive link with chloroform. The contamination and detection frequency of VOCs were highest in industrial complexes, followed by urban and rural areas. Thus, point source pollution significantly contributed to VOC contamination of these tributaries. Risk quotients for most VOCs were <1, suggesting negligible risk. Considering the relatively high occurrence of VOCs and their potential ecological risks, continuous environmental monitoring and study of environmental impacts based on ecotoxicity studies of domestic aquatic species are warranted.