The Paldang Reservoir (PDR) in South Korea is vital for supplying drinking water and maintaining ecosystems; thus, a comprehensive understanding of its water quality is necessary. Spatiotemporal changes in reservoir water quality were evaluated by applying Korean water quality indices and multivariate statistical techniques (MSTs). A dataset of 15 water quality parameters at five sites in the PDR were evaluated from 2017 to 2021. The organic matter, suspended matter, total phosphorus (TP), chlorophyll a (Chl-a), and total coliforms in the PDR exhibited a fair grade or higher. Chemical oxygen demand was found to correlate with biochemical oxygen demand, Chl-a, and TP. The average real-time water quality index (RTWQI) and average trophic state index (TSI_KO) of the PDR were excellent and mesotrophic, respectively, and 46% of eutrophic conditions occurred during the monsoon season. For a hierarchical cluster analysis (HCA), the five sites were grouped into three polluted areas and 12 months were grouped into dry and wet seasons. Principal component analysis and factor analysis identified four potential pollution sources (domestic sewage, industrial wastewater, intensive agricultural activities, and livestock wastewater) in the PDR and explained 79.7% of the total changes. Thus, the RTWQI, TSI_KO, and MSTs are useful tools for assessing freshwater quality in Korea, predicting potentially harmful conditions, and potentially assisting policymakers in PDR management.

This study aimed to estimate pollutant unit loads for different landuses and pollutants that reflected long-term runoff characteristics of nonpoint source (NPS) pollutants and recent environmental changes. During 2008–2014, 2026 rainfall events were monitored. The average values of antecedent dry days, total rainfall, rainfall intensity, rainfall duration, runoff duration, and runoff coefficient for each landuse were 3.8–5.9 d, 35.2–65.0 mm, 2.9–4.1 mm/h, 12.5–20.4 h, 12.4–27.9 h, and 0.24–0.45, respectively. Uplands (UL) exhibited high suspended solids (SS, 606.2 mg/L), total nitrogen (TN, 7.38 mg/L), and total phosphorous (TP, 2.27 mg/L) levels, whereas the runoff coefficient was high in the building sites (BS), with a high impervious surface ratio. The event mean concentration (EMC) for biological oxygen demand (BOD) was the highest in BS (8.0 mg/L), while the EMC was the highest in BS (in the rainfall range 50 mm). The unit loads for BOD (1.49–17.76 kg/km²·d), TN (1.462–10.147 kg/km²·d), TP (0.094–1.435 kg/km²·d), and SS (15.20–327.70 kg/km²·d) were calculated. The findings can be used to manage NPS pollutants and watershed environments and implement relevant associated management systems.

To safeguard aquatic environments in and around the Han River watershed in South Korea, a multivariate statistical evaluation of trace elements, a trace element concentration analysis and source determination, and a human health risk assessment were conducted on 10 trace elements at 25 sites. The results demonstrated that the Han River watershed was mainly affected by anthropogenic activities (traffic/industrial activity). The range of concentrations was arranged in descending order: Fe (217.13 ± 301.03 µg/L) > Mn (102.36 ± 153.04 µg/L) > Zn (23.33 ± 79.63 µg/L) > Ba (29.05 ± 12.37 µg/L) > Ni (5.14 ± 11.57 µg/L) > Cu (3.80 ± 3.56 µg/L) > Pb (0.46 ± 0.52 µg/L) > Se (0.06 ± 0.04 µg/L) > Cd (0.01 ± 0.01 µg/L) > Ag (0.004 ± 0.013 µg/L). The hazard index values of trace elements in surface water for combined pathways (ingestion and dermal contact) were < 1.0 for both adults and children, indicating no possible human health hazards. The estimated total cancer risk did not exceed the acceptable limit (1 × 10⁻⁴) for adults and children. The findings of this study provide data-driven guidelines for water environment policy decisions in the study area.

Because identifying the factors affecting water quality is challenging, water quality assessment of an individual component based on the arithmetic mean method cannot adequately support management policies. Therefore, in this study, we assessed the water quality target attainment at 24 sites in the Nakdong River Basin by applying multivariate log-linear models to identify factors influencing water quality, including flow and season. The temporal and seasonal water quality trend and flow were also analyzed using the calculated model coefficients. Specifically, weekly data on biological oxygen demand (BOD), total phosphorous (TP), and flow during 2013–2018 were used to investigate the 2018 water quality target attainment level for this river. The significance and suitability of the models were analyzed using the F-test, root mean squared error (RMSE), mean absolute percent error (MAPE), and adjusted R² values. All 24 models applied in this study showed statistical significance and suitability for the prediction of BOD and TP concentrations. Moreover, flow was identified as the main factor affecting water quality and had a predominant effect on BOD and TP concentrations in tributaries and the main stream, respectively. Furthermore, among the 24 sites, BOD and TP targets were evidently attained at 18 and 17 sites, respectively.