Portuguese legislation enforces adequate alternatives to municipal waste landfilling of organic wastes as well as others susceptible of valorisation. In the present work, the energetic valorisation of final municipal solid wastes rejected fractions is studied through the production of Refuse Derived Fuel (RDF). To accomplish this purpose several sampling campaigns were performed. Physical, chemical and energetic characterization of the rejected streams was done. Preliminary data allows us to conclude that studied materials have interesting potential to be used as RDF, particularly if blended with higher heating value materials in order to obtain RDF pellets with good combustion behavior, consistency and storage characteristics.info:eu-repo/semantics/publishedVersio

Nowadays trace organic pollutants represent a major concern in water treatment systems. Activated carbon has been used for most applications aiming at the reduction of these kind of compounds in aqueous effluents, but regeneration needs and high operation costs led to a renewed interest in the search for alternative sorbents. Pine bark is an excedentary raw material from sawmills in Portugal, and therefore a profitable natural resource that has already been successfully tested in the adsorption of organochlorines from contaminated water. This study aims at characterizing the pine bark surface structurally and chemically, to understand the nature of sorption occurring when a trace organic contaminant is present in aqueous effluents. Pentachlorophenol (PCP) was the trace contaminant used in the experiments. Scanning electron microscopy (SEM), mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) and X‐ray photoelectron spectroscopy (XPS) were the techniques used, in addition to classical chemical analysis and solid phase micro extraction (SPME) prior to gas chromatography with mass spectrometry (GC‐MS) for PCP quantification. The pine bark proved to be a material of very low porosity, low specific surface area, strong carbon aromatic content probably relative to polyphenols and lignin composition. Sorption experiments showed a good correlation for the linear adsorption isotherm, as well as the desorption experiments. In the conditions tested, the average PCP removal after 24 h was above 98 per cent. This material proved to be an encouraging sorbent for cheap water remediation solutions.

The treatment of agricultural and forest residues (AFRs) has become an important issue nowadays, both to avoid improper management and for their enhancement. In the study area of Viseu (Portugal), the AFRs are taken to a Residual Biomass Collection Centre. These are valorised in a Biomass Power Plant to produce electricity. Two further processes could be implemented to valorise this biomass: mulching and composting. This study aims to understand the best strategy to enhance this type of biomass residual considering their environmental performance. The Life Cycle Assessment (LCA) was applied considering a cradle-to-grave approach. Different processes of all the technologies were analysed, and the data collected enabled a comparison of 11 environmental impact categories. The results show that composting is the best alternative, except for global warming and ozone layer depletion, and energy valorisation has the greatest impact on five of the considered categories. In the three processes, impacts are mainly associated with the production and shredding phases of the residual biomass, rather than the transportation stages, due to the short distances covered. In all cases, the value of the final product generates market consequences in terms of electricity and fertiliser production. In line with the aim of the study, its outcomes may provide scientific support to local decision makers in defining best practices in the management of the AFRs.