The potential for mineral carbonation of CO₂ in plutonic mafic rocks is addressed through a set of laboratory experiments on cumulate gabbro and gabbro-diorite specimens from the Sines Massif (Portugal). The experiments were conducted in an autoclave, for a maximum of 64 days, using a CO₂ supersaturated brine under pressure and temperature conditions similar to those expected around an injection well during early-phase CO₂ injection. Multiple techniques for mineralogical and geochemical characterization were applied ante- and post-carbonation experiments. New mineralogical phases (smectite, halite and gypsum), roughness increase and material loss were observed after exposure to the CO₂ supersaturated brine. The chemical analysis shows consistent changes in the brine and rock specimens: (i) increases in iron (Fe) and magnesium (Mg) in the aqueous phase and decreases in Fe₂O₃ and MgO in the specimens; (ii) a decrease in aqueous calcium (Ca) and an increase in CaO in the cumulate gabbro, whereas in the gabbro-diorite aqueous Ca increased and afterwards remained constant, whereas CaO decreased. The geochemical model using the CrunchFlow code was able to reproduce the experimental observations and simulate the chemical behavior for longer times. Overall, the study indicates that the early-stage CO₂ injection conditions adopted induce mainly a dissolution phase with mineralogical/textural readjustments on the external area of the samples studied.

This paper reports the preliminary results of a comparative analysis of the effects of three consolidants on the color appearance of fresco paint layers affected by lack of cohesion. In vitro assays were performed with a laboratory-synthesized nanolime, a commercial nanolime (CaLoSiL^® IP25), and a commercial acrylic resin (Primal^TM SF-016 ER^®) applied by nebulization over two sets of replicas of buon and lime fresco painted with red and yellow ochres and smalt pigments. The paint layers were surveyed before, one week, and one month after treatment with technical photography in the visible range (Vis) and ultraviolet-induced fluorescence in the visible range (UVF), as well as optical microscopy (OM-Vis), colorimetry, spectrophotometry, and scanning electron microscopy coupled with energy dispersive x-ray spectroscopy (SEM-EDS). Experimental work also comprised the synthesis of nanolime and its characterization by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetry analysis (TGA-DTG). The results show no alteration on pigments’ spectral curves and elemental composition. The increase in the CIEL* coordinate and ∆E color variation noticed after the treatment with the nanolimes is associated with a white haze formation on the paint surfaces. The impact on color appearance is higher on the darker tones.

The historical monuments of the ‘City of Temples’ (Kathmandu) represent an intrinsic component of Nepal’s cultural heritage. The 2015 devastating Gorkha earthquake, besides human casualties, has led to a widespread demolition or partial damage of monuments at UNESCO World Heritage Sites, including the ones in Durbar squares. This study, through an integrated material characterization of masonry binders, used in four case monuments from Hanuman Dhoka and Patan Durbar squares, intends to contribute to the knowledge of the technological know-how of the past in order to maintain as much as possible the original traditions and to provide appropriate conservation strategies. The analytical characterization of the ancient mortars was carried out by means of X-ray Diffraction (XRD), Attenuated Total Reflectance–Fourier Transform-Infrared Spectroscopy (ATR-FTIR), Thermogravimetric Analysis (TGA), petrographic analysis, X-ray Fluorescence spectroscopy (XRF) and Pyrolysis–Gas Chromatography–Mass Spectrometry (Py-GC-MS). The composition of the mortars has been determined and is in accordance with previous research in traditional materials used in the Nepalese architecture. Chromatographic techniques proved to be particularly important in the analysis of mortars with organic binders as they revealed the possible composition of the binding media, providing additional information valuable for the future conservation/restoration of the stone monuments of the ‘City of Temples’.

Cultural heritage faces significant threats from environmental challenges and unchecked development. Sustainability has made its way into the field, and there is a growing interest in seeing it thrive. The particular field of the conservation and restoration of tangible movable cultural heritage is also being improved by new concepts and treatment options more aligned with environmental standards. This article investigates the integration of sustainability into the conservation and restoration of this specific cultural heritage by leveraging the SCOPUS and BCIN databases to examine the evolution of scientific content on the topic over the past 24 years. Key trends in research include assessing greener practices in conservation and education and guidance for the promotion of sustainable practices. These themes are also championed by organizations and initiatives that disseminate this message to conservation professionals through effective and less formal communication strategies. The findings emphasize the critical value of bridging the gap between scientific research and practical application, advocating for accessible resources and collaborative efforts to advance sustainable conservation practices.

This study investigates the perceptions and practices of Portuguese higher education students regarding the circular economy (CE), emphasising their knowledge, attitudes, and behaviours toward sustainable resource management. Carried out by the Working Group on Circular Economy and Waste Management of the Portuguese Sustainable Campus Network (RCS), the research used an online survey targeting students from 20 higher education institutions (HEIs), resulting in 400 responses. The findings indicate that while students generally hold positive views of the CE, their understanding of its practical applications, such as waste reduction and resource efficiency, remains limited. Only a small proportion of students reported exposure to CE-related topics in their curriculum, revealing a gap in academic integration. This study also identifies significant demographic variations in CE awareness and practices, influenced by factors such as age, field of study, and employment status. These insights underscore the need for HEIs to strengthen CE education and actively involve students in hands-on sustainability initiatives, fostering a generation equipped to drive the transition toward a circular economy.