Electrification is considered an optimal long-term solution for the decarbonization of the transport sector. However, in the medium period, propulsion systems will continue to dominate urban mobility, thus requiring the shift from fossil fuels toward low carbon fuels. In this regard, the request from the EU to achieve carbon neutrality by 2050 is encouraging the use of innovative fuels and powertrains. Alcohols such as ethanol and methanol are particularly suitable for spark ignition engines. This paper investigates the effect of ethanol/methanol blends on the performance and emissions of a turbocharged direct injection spark ignition engine running on the worldwide harmonized light vehicles test cycle. Three blends were considered, consisting of 10% v/v ethanol (E10), 25% v/v ethanol (E25) and 5% v/v ethanol with 15% v/v methanol (E5M15). Gaseous and particle emissions were measured at the exhaust. The main novelty of the study regards the investigation of the behavior of alcohol blends, especially those based on methanol, in transient conditions. It was found that CO, THC and NO_x emissions decrease with the increase in alcohol content in the blend, with different contributions in the different phases of the cycle. Particle emissions decrease for E10 and even more so for E25. When methanol is added to the blend, particle emissions increase with respect to E25 and they are characterized by a larger diameter.

This study explores the potentiality of low/zero carbon fuels such as methanol, methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port fuel and a direct injection system. Liquid fuels were injected into the intake manifold to benefit from a homogeneous charge formation. Gaseous fuels were injected in direct mode to enhance the efficiency and prevent abnormal combustion. Tests were realized at a fixed indicated mean effective pressure and at three different engine speeds. The experimental results highlighted the reduction of CO and CO₂ emissions for the alternative fuels to an extent depending on their properties. Methanol exhibited high THC and low NO_x emissions compared to gasoline. Methane and, even more so, hydrogen, allowed for a reduction in THC emissions. With regard to the impact of gaseous fuels on the NO_x emissions, this was strongly related to the operating conditions. A surprising result concerns the particle emissions that were affected not only by the fuel characteristics and the engine test point but also by the lubricating oil. The oil contribution was particularly evident for hydrogen fuel, which showed high particle emissions, although they did not contain carbon atoms.

Within the context of ever wider expansion of direct injection in spark ignition engines, this investigation was aimed at improved understanding of the correlation between fuel injection strategy and emission of nanoparticles. Measurements performed on a wall guided engine allowed identifying the mechanisms involved in the formation of carbonaceous structures during combustion and their evolution in the exhaust line. In-cylinder pressure was recorded in combination with cycle-resolved flame imaging, gaseous emissions and particle size distribution. This complete characterization was performed at three injection phasing settings, with butanol and commercial gasoline. Optical accessibility from below the combustion chamber allowed visualization of diffusive flames induced by fuel deposits; these localized phenomena were correlated to observed changes in engine performance and pollutant species. With gasoline fueling, minor modifications were observed with respect to combustion parameters, when varying the start of injection. The alcohol, on the other hand, featured marked sensitivity to the fuel delivery strategy. Even though the start of injection was varied in a relatively narrow crank angle range during the intake stroke, significant differences were recorded, especially in the values of particle emissions. This was correlated to the fuel jet-wall interactions; the analysis of diffusive flames, their location and size confirmed the importance of liquid film formation in direct injection engines, especially at medium and high load.

This work shows the results of an experimental campaign carried out in two spark ignition engines, a small optical research engine and its commercial counterpart, using a turbulent ignition system (pre-chamber) specifically designed for small engines. Advanced optical techniques and conventional methods were used to study the combustion process under various operating conditions. The pre-chamber operated actively in the research engine and passively in the commercial engine. Results showed that the pre-chamber configuration resulted in an increase in indicated mean effective pressure (IMEP) and a decrease in the coefficient of variation (CoV) of IMEP. These improvements compensated for challenges such as slow methane combustion rate, poor lean burn capability, and air displacement. In addition, the pre-chamber configuration exhibited lower fuel consumption and specific exhaust emissions compared to the standard ignition system. The novelty of this work lies in the successful implementation of the turbulent ignition system as a retrofit solution for SI engines, showing improved combustion efficiency and lower emissions. The study goes beyond previous efforts by demonstrating the benefits of the pre-chamber configuration in small engines without requiring extensive modifications. The results provide valuable insights into the automotive industry’s pursuit of engine optimization and highlight the significance of innovative approaches for spark ignition engines in contributing to sustainable mobility.