Achieving higher optical power in UV laser systems is a challenging task due to the limited performance of their built-in optical elements. As a rule of thumb, interference coatings of such elements are found to be the weakest links by the means of laser-induced damage threshold (LIDT). The optical resistance is directly attributed to the fundamental absorption properties of deposited layers. Unfortunately, there are only a limited set of available materials with discrete refractive indices that are also compatible with UV applications. In this study, an attempt is made to employ sculptured layers in order to produce durable anti-reflective (AR) coatings by using the so-called glancing angle deposition (GLAD) method. Spectral, structural, mechanical and stress properties of GLAD coatings were investigated in detail. AR coatings produced by GLAD were found to be three times more laser damage resistant at 355 nm wavelength as compared to those prepared by ion beam sputtering (IBS).

A principal possibility to overcome fundamental (intrinsic) limit of pure optical materials laser light resistance is investigated by designing artificial materials with desired optical properties. We explore the suitability of high band-gap ultra-low refractive index material (n less than 1.38 at 550 nm) in the context of highly reflective coatings with enhanced optical resistance. The new generation all-silica (porous/nonporous) SiO₂ thin film mirror with 99% reflectivity was prepared by glancing angle deposition (GLAD). Its damage performance was directly compared with state of the art hafnia/silica coating produced by Ion-Beam-Sputtering. Laser-Induced Damage Thresholds (LIDT) of both coatings were measured in nanosecond regime at 355 nm wavelength. Novel approach indicates the potential for coating to withstand laser fluence of at least 65 J/cm² without reaching intrinsic threshold value. Reported concept can be expanded to virtually any design thus opening a new way of next generation thin film production well suited for high power laser applications.

A one-dimensional photonic crystal with an additional TiO₂ layer, supporting Bloch surface waves (BSW), was used for enhanced signal sensitivity for the detection of protein interaction. To compare the optical response of BSW and photonic crystals (PC), bovine serum albumin and specific antibodies against bovine serum were used as a model system. The results obtained show the enhanced sensitivity of p- and s-BSW components for the 1D PC sample with an additional TiO₂ layer. Furthermore, a higher sensitivity was obtained for the BSW component of p-polarization in the PC sample with an additional TiO₂ layer, where the sensitivity of the ellipsometric parameter Ψ was five times higher and that of the Δ parameter was eight times higher than those of the PC sample. The capabilities of BSW excitations are discussed from the sensitivity point of view and from the design of advanced biosensing.

Polarisation analysis in the mid-infrared fingerprint region was carried out on thin (∼1 $\mathsf{\mu }$m) Si and SiO₂ films evaporated via glancing angle deposition (GLAD) method at ${70}^{\circ }$ to the normal. Synchrotron-based infrared microspectroscopic measurements were carried out on the Infrared Microspectroscopy (IRM) beamline at Australian Synchrotron. Specific absorption bands, particularly Si-O-Si stretching vibration, was found to follow the angular dependence of ∼${cos}^2\theta$, consistent with the absorption anisotropy. This unexpected anisotropy stems from the enhanced absorption in nano-crevices, which have orientation following the ${cos}^2\theta$ angular dependence as revealed by Fourier transforming the image of the surface of 3D columnar films and numerical modeling of light field enhancement by sub-wavelength nano-crevices.

Zero angle polarizers and achromatic waveplates were coated using anisotropic thin films. Multilayer approach with different orientations of optical axes for individual layers allowed for independent control of perpendicular polarization intensity and phase retardance properties.