The purpose of the study was to applicate new synthesized zwitterionic surfactants as hair shampoo components. Hair shampoos formulated for the study contained newly synthesized sulfobetaines at a concentration of 2%. The above additives were evaluated to determine their effect on shampoo dynamic viscosity, texture, yield stress, foaming properties and surface tension of aqueous shampoo solutions. The viscosity of the sulfobetaine-enriched hair shampoos ranged between 6,000 and 21,000 mPa·s, which ensures the required application properties of the formulated products. The yield stress in three prototypical shampoos was equal to approximately 10 Pa, which represents the minimum value that should characterize cosmetics of this type. The sulfobetaines added to the formulations were not found to significantly affect the parameters of hardness and adhesive force. All the formulations under study, except for the shampoo containing N-dodecyl-N-piperidinium-1-propanesulfonate, exhibited good foaming properties. The incorporation of sulfobetaines into hair shampoos contributes to an effective decrease in the surface tension of their aqueous solutions, which may indicate beneficial washing properties. The use of the proposed sulfobetaines in hair shampoos favorably modifies their physicochemical and functional properties. The findings of the study can provide useful insights for the formulation of hair shampoos containing zwitterionic surfactants.

The study investigated the effect of chamomile extract obtained in supercritical carbon dioxide conditions on the basic properties of pharmaceutical ointments. A total of five formulations were designed and prepared, differing in the weight ratio of sunflower oil to chamomile extract (5:0, 3.5:1.5, 2.5:2.5, 1.5:3.5 and 0:5). An increase in the concentration of chamomile extract was found to be accompanied by a decrease in hardness, adhesive power and flow limit. Based on viscosity measurements it was shown that ointments containing the hydrophobic plant extract under study were prone to larger drops in viscosity under the effect of the set shear rate. It was determined that from the viewpoint of ointment spreadability and application to the skin, the optimum concentration of chamomile extract for the studied formulations should be within the range of 1.5-2.5%. Furthermore, the addition of chamomile extract to ointments was found to give samples a yellow-green color. Green was observed to be the dominant color, and its saturation and shade varied for different formulations.

The aim of the study was to employ BET, GAB, and Peleg models for mathematical description of sorptive properties of market powder shampoos of natural origin. Two commercial powder shampoos of plant origin Sapindus mukorossi (A) and Acacia concinna (B) were used as study materials. The sorption isotherm of A. concinna powder shampoo was much higher in the standard reference system in comparison to S. mukorossi shampoo. The B shampoo had a higher monolayer capacity than product A. The examined process in both cases was physical in nature. The most useful for isothermal description turned out to be the theoretical BET equation and empirical Peleg model. They were characterized by high accuracy. Natural powder shampoos differed significantly in terms of physical parameters of particles and sorptive properties, which may suggest their different functional properties.

Purpose – Modern cutting fluids often are real aqueous solutions of chemical compounds. That form of cutting fluid is simpler in preparation, as compared to emulsions and microemulsions. The water base is a good cooling medium of high-ecological value. The purpose of this paper is to discover water-soluble additives that could improve the lubricity of water. Design/methodology/approach – Three cationic surfactants were chosen to be analyzed. Their tribological properties were verified using two testers: T0-2 (four-ball machine) and T-11 (ball-on-disk). The results of the tests performed using friction couples made of steel (T0-2, T-11) and steel-ceramics (T-11) were satisfactory. Findings – The friction coefficients and wear scar diameters are even a few times smaller, as compared to the ones measured in a water environment. Originality/value – The paper demonstrates that the crucial role in improvement of the tribological properties is played by the surface activity of the additives (confirmed by the measurements of the surface tension and wetting angle). As the cationic surfactants are bactericidal and anti-corrosive, they can be classified as multi-purpose additives modifying water lubricity.

The study addressed the effect of the structure of silicone polyethers on selected functional properties of cotton fabric rinsed in conditioners containing the additives under study. Fabric softener formulations containing two comb-structured compounds (PEG/PPG-14/0 Dimethicone and PEG/PPG-20/20 Dimethicone) and one block-structured compound (Bis-PEG/PPG-20/20 Dimethicone) were developed. Cotton fabric rinsed in conditioners containing silicone glycols was not found to be affected by yellowing. However, differences were noted in the softening ability and re-wettability of rinsed fabrics due to diverse structures of the additives used. The most desirable soft hand effect was observed after cotton rinsing in fabric softeners containing the block-structured compound Bis-PEG/PPG-20/20 Dimethicone. In contrast, the highest fabric re-wettability was shown for the conditioner enriched with a comb-structured compound (PEG/PPG-20/20 Dimethicone). The study results demonstrate that the prototypical fabric softeners containing silicone derivatives have a potential to provide quality characteristic required by consumers of this product group.

Traditional technologies applied for obtaining plant raw materials for cosmetic production are based primarily on high-level processing, which is reflected in the qualitative composition of the resulting materials. By using low-temperature drying, it is possible to retain in the raw materials a range of valuable ingredients. In this study, blue honeysuckle powder was used as an ingredient of cosmetic face masks. The stability of the masks was evaluated. Dynamic viscosity, yield point and texture analysis of the cosmetics was performed. The color of the emulsions and the level of skin hydration after face mask application was determined. Emulsions were found to be stable. A decrease in dynamic viscosity of the emulsions as a function of increasing concentrations of the additive and under the conditions of rising rotational speed were observed. Similarly, an increase in the concentration of blue honeysuckle in the emulsions resulted in a decrease in the value of the yield point. Based on the results, it can be stated that the addition of blue honeysuckle caused a decrease in hardness of the masks, while the opposite trend was observed for adhesive force. It was found that an increase in the concentration of blue honeysuckle gave a reddish-yellow color to the samples. Corneometric assessment confirmed proper skin hydration after the application of the emulsions.