The influence of recycled concrete powder (RCP) and recycled brick powder (RBP) on the dry density, optimal water content, and compressive strength of raw soil materials was investigated in this study. Moreover, the following resistance of freeze–thaw cycles was also considered. Additionally, X-ray diffraction (XRD) and scanning electron microscope (SEM) were selected to detect its mineral composition and observe the microstructure, further revealing the mechanism of performance change. The mass ratios of recycled concrete powder and recycled brick powder were 2~14%. Results showed that the dry density decreased and the optimal water content increased with the increasing dosage of recycled concrete powder and recycled brick powder. When the dosage of RCP or RBP was lower than 14%, raw soil with RCP showed higher optimal water content and lower dry density. However, when the dosage was higher than 14%, the result was the opposite. The addition of recycled concrete powder and recycled brick powder was able to decrease the compressive strength of raw soil, except for 10% of recycled brick powder. Raw soil with recycled brick powder presented higher compressive strength than that of raw soil with recycled concrete powder. RBP could improve the freeze–thaw cycles’ resistance of specimens; however, RCP led to decreasing the resistance of freeze–thaw cycles. These research findings can provide reference to the recycling of construction waste.
AuPt nanoparticles clusters (NPCs) were electrodeposited on multiwalled carbon nanotubes (MWCNTs). The as-prepared AuPt NPCs@MWCNTs nanocomposites exhibited considerably enhanced electrocatalytic activity than Pt NPs@MWCNTs for methanol oxidation in acid medium. In comparison with Pt NPs@MWCNTs, a remarkable resistance to CO poisoning and a higher If/Ib value (the ratio of the forward scan oxidation peak current (If) and reverse scan oxidation peak current (Ib)) was achieved by AuPt NPCs@MWCNTs electrocatalyst, which is attributable to the unique NPCs nanostructure with enlarged electrochemical active surface areas. These results demonstrated the potential of AuPt NPCs@MWCNTs, which can be considered as an efficient electrocatalyst for methanol oxidation in direct methanol fuel cells.
Current research and technical standards primarily rely on observational methods to evaluate the printability of 3D printing materials. There is a lack of quantitative assessment metrics for extrudability and supportability, and experimental data cannot be used to characterize extrudability and buildability. Further research is needed. Based on traditional workability parameters (such as flowability), this study explored the influence of printability characteristics and adopted two quantitative indicators—extrusion uniformity and cumulative deformation rate—to comprehensively evaluate material performance from two aspects, while observing the trend of changes in traditional workability indicators and print quality under experimental conditions. The experimental results showed that the extrusion uniformity of 3D-printed mortar initially improved and then gradually deteriorated as flowability increased, and was inversely proportional to dynamic yield stress. The cumulative deformation rate decreases with the improvement of height retention capability and the increase in static yield stress. Through parameter analysis, the optimal printing performance conditions were determined: when the extrusion uniformity is below 3.3% and the cumulative deformation rate is ≤6%, the corresponding dynamic yield stress range is 200 Pa to 800 Pa, and the static yield stress range is 1800 Pa to 3300 Pa. Under these parameters, the mortar exhibits excellent printing performance, including high-layer stacking capability (≥30 layers) and enhanced structural stability. This experiment demonstrates that using these two quantitative indicators can simply and efficiently evaluate the performance metrics of 3D-printed materials, while also revealing the relationship between the workability and printing quality of 3D-printed recycled micro-powder geopolymer materials.