Electricity production is a major problem for deep space exploration. The possibility of using radioisotope elements with a very long life as an energy source was investigated in the framework of an EU project “SpaceTRIPS”. For this, a two-stage system was tested, the first in which thermal energy is converted into mechanical energy by means of a thermoacoustic process, and the second where mechanical energy is converted into electrical energy by means of a magnetohydrodynamic generator (MHD). The aim of the present study is to develop an analytical model of the MHD generator. A one-dimensional model is developed and presented that allows us to evaluate the behavior of the device as regards both electromagnetic and fluid-dynamic aspects, and consequently to determine the characteristic values of efficiency and power.

Alkaline nickel-cadmium batteries are among the most used industrial high-power sources. Despite stricter environmental requirements, nickel-cadmium batteries still remain as the main choice for highly reliable power sources for heavy-loaded equipment. Therefore, recovery of cadmium (Cd) from spent batteries is a challenge for the modern recycling industry, particularly as it displays high bio-toxicity. The present study describes a new green approach for Cd recovery from cadmium oxide (CdO). The paper discusses using a ternary chloride composition consisting of calcium, potassium and sodium chloride, thereby avoiding the release of Cd vapour from the reaction volume during the reduction reaction from CdO. For the protective slag layer during the reduction process (which occurs at 650 °C), a 0.515:0.0796:0.405 molar ratio of CaCl₂:KCl:NaCl was chosen, with the aim of achieving a melting point at 483 °C. To describe phase and elemental composition of obtained products X-ray diffraction analysis and energy dispersive X-ray spectroscopy, respectively, were applied. Electron and optical microscopy were used for morphological observations. The presence of the metallic Cd was noted. During the reduction reaction, it was noted that slag separated into two parts: a protective upper layer and bottom layer. It was also noted that metallic Cd accumulated with increasing reaction time in the bottom part of the slag.

In this paper, an electrical generator is presented for the exploitation of alternating energy. Some renewable sources are directly available in such forms, such as the wave power obtainable from the sea, but most of them can be converted to alternative forms; therefore, the proposed generator can be applied to different kinds of renewable sources. In particular, the proposed system is thought to be coupled with a thermoacoustic engine, which converts heat into mechanical vibration without using solid moving parts. This opens the proposed system to the use of most thermal sources, such as solar radiation, waste recovery, geothermic, car exhaust, and others. The object of of this present work concerns the transformation of alternating mechanical energy into electricity by using a specific type of magnetohydrodynamic (MHD) disk generator. The functioning of this generator is based on the interaction between a DC magnetic field embedded in a disk structure and a conducting fluid held in an inner channel. A simplified model of the generator is presented here, and a sensitivity analysis is performed. It is shown that, under specific operating conditions, the efficiency of the system can reach 70% with a level of power of hundreds of watts.

This study presents a carbon footprint assessment of a novel electroslag method for cadmium (Cd) recovery from spent nickel–cadmium (Ni-Cd) batteries in comparison with the carbon footprints of pyrometallurgical and hydrometallurgical cadmium recovery methods. A comparison of CO₂ emissions in three types of technological processes during the recovery of 1 kg of cadmium is carried out. Energy inputs and CO₂ emissions are calculated for the electroslag process and compared to conventional methods, such as pyrometallurgical and hydrometallurgical reduction methods. The electroslag process eliminates cadmium vaporization by using molten KCl–NaCl flux and carbon under electromagnetic stirring. Cadmium reduction occurs under a layer of flux, which prevents the contact of the reduced cadmium with the atmosphere. The electroslag process temperature is limited to 700 °C, which is lower than the boiling point of cadmium (767 °C). The electroslag remelting process uses molten KCl–NaCl flux and carbon as a reductant under electrovortex flow stirring. The pyrometallurgical method for extracting cadmium from nickel–cadmium batteries is based on the reduction of cadmium with carbon at high temperatures. In the pyrometallurgical process, coal (anthracite) is used as the carbonaceous material, which can extract 99.92% of cadmium at 900 °C. Cadmium is separated using a vacuum at temperatures ranging from 800 °C to 950 °C for several hours. Hydrometallurgy is a metal extraction process involving chemical reactions that occur in organic or aqueous solutions at low temperatures. The hydrometallurgical process involves a series of acid or alkaline leaches, followed by separation and purification methods such as absorption, cementation, ion exchange, and solvent extraction to separate and concentrate metals from leach solutions.

This study presents a carbon footprint assessment of a novel electroslag method for cadmium (Cd) recovery from spent nickel-cadmium (Ni-Cd) batteries. The process utilizes molten KCl–NaCl flux and carbon as a reductant under electrovortex flow stirring. Energy inputs and CO₂ emissions are calculated for active process stages and compared to conventional methods. Updated analysis excludes flux melting, recognizing the flux as a non-consumable transport and protection medium. The results highlight the method’s potential for sustainable, continuous cadmium recovery.