Synthesizing graphene nanopores: Nanosize pores in graphene can make its electronic properties more favorable for transistor applications and may also be useful for molecular separations. Moreno et al . used Ullmann coupling to polymerize a dibromo-substituted diphenylbianthracene on a gold surface (see the Perspective by Sinitskii). Cyclodehydrogenation of the resulting polymer produced graphene nanoribbons, and cross-coupling of these structures created a nanoporous graphene sheet with pore sizes of about 1 nanometer. Scanning tunneling spectroscopy revealed an electronic structure in which semiconductor bands with an energy gap of 1 electron volt coexist with localized states created by the pores. Science , this issue p. 199 ; see also p. 154
Visualizing Bond Order: Bond lengths in conjugated molecules closely reflect individual bond order and are usually determined by diffraction methods. It is valuable to know bond order for rationalizing aromaticity, and reactivity and for chemical structure determination.
Gross
et al. (p. 1326 ; see the Perspective by Perez and the cover) differentiated the bond orders in individual molecules in the fullerene C 60 and in polyaromatic hydrocarbons by imaging with noncontact atomic force microscopy (AFM). The molecules were adsorbed onto a copper surface, and the AFM tip was decorated with a CO molecule, which was used to measure tip frequency shifts above the bonds and their apparent lengths. Multiple bonds appeared brighter in the images because of stronger Pauli repulsion, and their shorter length was amplified by bending of the CO at the tip apex.
4 July 2013 in European Journal of Organic Chemistry