High energy density materials (HEDM) are the subject of an extensive research effort in relation to the use of these compounds as components of rocket propellants, powders, and formulations of high-performance explosives. Hexanitrohexaazaisowurtzitane (HNIW, i.e., CL-20) has received much attention in these research fields for its specific impulse, burning rate, ballistics, and detonation velocity. In this paper, the development and performances of the explosives from the first to the fourth generation are briefly summarized, and the synthesis status of the fourth-generation explosive, HNIW, is reviewed. The key issues that restrict the development of industrial amplification synthesis of HNIW are analyzed, and the potential directions of development are proposed. It is pointed out that to synthesize new and efficient catalysts is the key to making the cost-effective manufacturing of CL-20 a reality.

A ratiometric two-photon fluorescent probe for accurate monitoring of nitroreductase in hypoxic neurons was developed.

The PM_2.5 and other small particles produced by cooking oil fumes have contributed up to 25% to the urban atmospheric PM_2.5, which has a bad impact on air quality and seriously threatens human health. Aiming at the pollution problem caused by catering oil fume, this article analyzes the threats of air pollution to human health based on the compositions and characteristics of catering oil fume, illustrates the development trend of China′s food and beverage lampblack control policy, and summarizes and points out the current situation and development trend of catering oil fume treatment. In order to provide ideas for the design of more efficient and energy-saving treatment processes in the future, the advantages and disadvantages were reviewed, and the improvement direction of the treatment technology was discussed.

Salt-tolerant aerobic granular sludge(AGS) was successfully cultivated under the dual stress of tetracycline and 2.5% salinity, resulting in an average particle size of 435.0 ± 0.5 and exhibiting a chemical oxygen demand(COD) removal rate exceeding 80%, as well as excellent sedimentation performance. The analysis of metagenomics technology revealed a significant pattern of succession in the development of AGS. The proportion of Oleiagrimonas, a type of salt-tolerant bacteria, exhibited a gradual increase and reached 38.07% after 42 days, which indicated that an AGS system based on moderate halophilic bacteria was successfully constructed. The expression levels of targeted genes were found to be reduced across the entire AGS process and formation, as evidenced by qPCR analysis. The presence of int1 (7.67 log10 gene copies g⁻¹ in 0 d sludge sample) enabled microbes to horizontally transfer ARGs genes along the AGS formation under the double pressure of TC and 2.5% salinity. These findings will enhance our understanding of ARG profiles and the development in AGS under tetracycline pressure, providing a foundation for guiding the use of AGS to treat hypersaline pharmaceutical wastewater.

During Fischer–Tropsch synthesis, O atoms are dissociated on the surface of Fe-based catalysts. However, most of the dissociated O would be removed as H₂O or CO₂, which results in a low atom economy. Hence, a comprehensive study of the O removal pathway as formic acid has been investigated using the combination of density functional theory (DFT) and kinetic Monte Carlo (kMC) to improve the economics of Fischer–Tropsch synthesis on Fe-based catalysts. The results show that the optimal pathway for the removal of dissociated O as formic acid is the OH pathway, of which the effective barrier energy (0.936 eV) is close to that of the CO activation pathway (0.730 eV), meaning that the removal of dissociated O as formic acid is possible. The main factor in an inability to form formic acid is the competition between the formic acid formation pathway and other oxygenated compound formation pathways (H₂O, CO₂, methanol-formaldehyde); the details are as follows: 1. If the CO is hydrogenated first, then the subsequent reaction would be impossible due to its high effective Gibbs barrier energy. 2. If CO reacts first with O to become CO₂, it is difficult for it to be hydrogenated further to become HCOOH because of the low adsorption energy of CO₂. 3. When the CO + OH pathway is considered, OH would react easily with H atoms to form H₂O due to the hydrogen coverage effect. Finally, the removal of dissociated O to formic acid is proposed via improving the catalyst to increase the CO₂ adsorption energy or CO coverage.