The selection of effective surfactants potentially can mobilize oil up to 50% of residuals in mature carbonate oilfields. Surfactants’ screening for such oilfields usually is complicated by the high salinity of water, high lipophilicity of the rock surface, and the heterogeneous structure. A consideration of features of the oilfield properties, as well as separate production zones, can increase the deep insight of surfactants’ influence and increase the effectiveness of surfactant flooding. This article is devoted to the screening of surfactants for two production zones (Bashkirian and Vereian) of the Ivinskoe carbonate oilfield with high water salinity and heterogeneity. The standard core study of both production zones revealed no significant differences in permeability and porosity. On the other hand, an X-ray study of core samples showed differences in their structure and the presence of microporosity in the Bashkirian stage. The effectiveness of four different types of surfactants and surfactant blends were evaluated for both production zones by two different oil displacement mechanisms: spontaneous imbibition and filtration experiments. Results showed the higher effect of surfactants on wettability alteration and imbibition mechanisms for the Bashkirian cores with microporosity and a higher oil displacement factor in the flooding experiments for the Vereian homogeneous cores with lower oil viscosity.

Surfactant flooding can mobilize trapped oil and change the wettability of the rock to be more hydrophilic, which increases the oil recovery factor. However, the selection of surfactants is difficult in the case of high salinity conditions. In this work, we synthesized three novel anionic-nonionic surfactants based on widely used nonionic surfactant nonylphenol polyethoxylated (NPEO) and evaluated their efficiencies for enhanced oil recovery (EOR) in high salinity water (20% NaCl). The modified surfactants showed a decrease in interfacial tension (IFT) up to 10 times compared with the nonionic precursor. All surfactants had changed the wettability of rock to be more hydrophilic according to contact angle measurements. The effectiveness of surfactants was proved by spontaneous imbibition experiments, in which the synthesized surfactants showed a better displacement efficiency and increased oil production by 1.5–2 times. Filtration experiments showed an increase in oil recovery factor by 2–2.5 times in comparison with the nonionic NPEO. These promising results prove that the synthesis of new surfactants by modifying NPEO is successful and indicate that these novel surfactants have a great potential for EOR in high salinity reservoirs.

Earlier, an experimental and theoretical study of pulsating combustion in a pipe with a tangential supply of a mixture of propane-butane fuel with air was carried out. It was found that the results of calculating the frequencies of gas oscillations differ significantly from the experimental data. One of the reasons is the hypothetical nature of the axial distribution of the speed of sound in the combustion chamber. In this work, this distribution is found on the basis of calculated and experimental data on the gas temperature at the ends of the pipe.