Iron Oxide Nanoparticles (IONPs) have received unprecedented interest in various applications. The main challenges in IONPs are fluid stability due to agglomeration in a saline condition. This paper aims to investigate the colloidal stability of citric acid (CA), sodium dodecyl sulphate (SDS) and polyvinyl alcohol (PVA) under various molar ratios and levels of salinity. Firstly, the IONPs were synthesized using a facile co-precipitation approach. Secondly, the IONPs were coated using a simple dip-coating method by varying the molar ratio of CA, SDS and PVA. Next, the coated IONPs were characterized by using an X-ray Diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), and a Field Emission Scanning Electron Microscope (FESEM) for the morphological and crystallographic study of coated IONPs. Finally, the coated IONPs were characterized for their zeta potential value and hydrodynamic size using a Zetasizer and their turbidity was measured using a turbidity meter. It was found that at a low salinity level, 0.07 M of CA-IONPs, a high zeta potential value, a smaller hydrodynamic size, and a high turbidity value of −40.9 mV, 192 nm and 159 NTU were observed, respectively. At a high salinity level, 1.0 M SDS-IONPs recorded a high zeta potential value of 23.63 mV, which corresponds to a smaller hydrodynamic size (3955 nm) and high turbidity result (639 NTU). These findings are beneficial for delivering cutting-edge knowledge, especially in enhanced oil recovery (EOR) applications.

After polymer flooding, substantial oil and residual polymers remain in reservoirs, leading to plugging and reduced recovery. MEOR (Microbial Enhanced Oil Recovery) aims to release trapped oil by utilizing microorganisms and their byproducts. The microorganisms can use residual HPAM (hydrolyzed polyacrylamide) as an energy source for polymer degradation, addressing reservoir plugging issues and improving oil recovery. However, microorganisms are sensitive to environmental conditions. This paper presents a detailed update of MEOR, including microbial products, mechanisms, and merits and demerits. The effect of the displacement fluid and conditions on microorganisms is thoroughly demonstrated to elucidate their influencing mechanism. Among these factors, HPAM and crosslinkers, which have significant biological toxicity, affect microorganisms and the efficiency of MEOR. Limited research exists on the effect of chemicals on microorganisms’ properties, metabolism, and oil displacement mechanisms. The development of microbial consortium, their metabolic interaction, and oil displacement microprocesses are also discussed. In addition, prior studies lack insights into microorganisms’ interaction and mechanisms using chemicals. Finally, field trials exist to examine the microbial consortium’s efficiency and introduce new technologies. This review mainly explores the influencing factors on microorganisms, and confirms the credibility of MEOR after polymer flooding, providing a scientific basis for improving the theory of MEOR.

Polymer gel treatment is one of the most popular conformance control methods used in the petroleum industry. The advantage of the polymer gel system used in harsh reservoir conditions is an integrated process that must take into account all elements of gelation kinetics. In high-temperature applications, NH₄Cl has been selected as a retarder to extend the gelation time of a PAM/PEI gel system. However, the gel network loses gel strength when salt and retarder increase, resulting in a weak gel structure, and becomes susceptible. The combination of these two variables leads to the development of a weak gel network, making it fragile and susceptible. To strengthen the weakened PAM/PEI polymer gel, the addition of silica nanoparticles (silica NP) is considered an effective remedy. This article presents the performance of PAM/PEI polymer gel strengthened with silica NP, especially the performance in terms of viscosity, gelation time, and gel strength, as well as performance in porous media. For example, the results exhibited a high storage modulus, G′, which is almost 800 Pa, compared to the loss modulus, G″, throughout the frequency and strain range, indicating solid-like behavior, at significantly high amounts of silica NP. This finding provides a better understanding and knowledge on the influence of solid particles in enhancing the performance of PAM/PEI polymer gel that has been weakened by salinity and retarder.

This paper presents optimization formulation of organically crosslinked polymer gel for high temperature reservoir conformance control using response surface methodology (RSM). It is always desirable to approach an optimal polymer gel formulation study with adequate performance information related to viscosity and gelation time to minimize excessive water production. In this paper, the effects of polymer and crosslinker concentrations and their influences on gelation time and viscosity were investigated. Central composite design (CCD) was used to determine the optimized organically crosslinked polymer gel formulation. Concentrations of two main raw materials, namely, polyacrylamide (PAM) and polyethylenimine (PEI), were varied in a suitable range. This was to obtain the formulation with the desirable two vital responses, which are viscosity and gelation time. It was found that the results fitted the quadratic equation. Statistically, the quadratic model is reliable and adequate perfectly the variability of the responses obtained from the experimental data. In addition, gelation time and gel viscosity may be controlled by adjusting both polymer and crosslinker concentrations. The optimum formulated organically crosslinked polymer gel with significant desirability factor conditions was achieved at 1.5% w/v of PAM and 0.3% v/v of PEI.