Understanding the origins and processes of riverine dissolved inorganic carbon (DIC) is crucial for predicting the global carbon cycle with projected, more frequent climate extremes yet our knowledge has remained fragmented. Here we ask: How and how much do DIC production and export vary across space ( shallow vs . deep , uphill vs . depression ) and time ( daily , seasonal , and annual )? How do the relative contributions of biogenic ( soil respiration ) and geogenic ( carbonate weathering ) sources differ under different temperature and hydrological conditions ? We answer these questions using a catchment‐scale reactive transport model constrained by stream flow, stable water isotopes, stream DIC, and carbon isotope data from a headwater karstic catchment in southwest China in a subtropical monsoon climate. Results show climate seasonality regulates the timing of DIC production and export. In hot‐wet seasons, high temperature accelerates soil respiration and carbonate weathering (up to a factor of three) via elevating soil CO ₂ and carbonate solubility, whereas high discharge enhances export by two orders of magnitude compared to cold‐dry seasons. Carbonate weathering is driven more by soil CO ₂ than water flow. At the annual scale, 92.9% and 7.1% of DIC was produced in shallow and deep zone, respectively, whereas 64.5% and 35.5% of DIC was exported from shallow and deep zone, respectively. These results highlight the uniqueness of subtropical karst areas as synchronous reactors and transporters of DIC during the hot‐wet monsoon, contrasting the asynchronous production and export in other climate regions. A future hotter and wetter climate with more intensive storms in the region may further intensify DIC production and export, accentuating the potential of subtropical karst regions as global hot spots for carbon cycling.

Incubation experiments using a typical cornfield soil in the Wujiang River watershed, SW China, were conducted to examine the impacts of soil moisture and fertilizer on N₂O emissions and production mechanisms. According to the local fertilizer type, we added NH₄NO₃ (N) and glucose (C) during incubation to simulate fertilizer application in the cornfield soil. The results showed that an increase in soil moisture and fertilizer significantly stimulated N₂O emissions in cornfield soil in the karst area, and it varied with soil moisture. The highest N₂O emission fluxes were observed in the treatment with nitrogen and carbon addition at 70% water-filled pore space (WFPS), reaching 6.6 mg kg⁻¹ h⁻¹, which was 22,310, 124.9, and 1.4 times higher than those at 5%, 40%, and 110% WFPS, respectively. The variations of nitrogen species indicated that the production of extremely high N₂O at 70% WFPS was dominated by nitrifier denitrification and denitrification, and N₂O was the primary form of soil nitrogen loss when soil moisture was >70% WFPS. This study provides a database for estimating N₂O emissions in cropland soil in the karst area, and further helped to promote proper soil nitrogen assessment and management of agricultural land of the karst watersheds.

Agricultural activities are major contributors to global greenhouse gas (GHG) emissions, with methane (CH₄) and nitrous oxide (N₂O) emissions accounting for 40% and 60% of total agricultural emissions, respectively. Therefore, developing effective emission reduction pathways in agriculture is crucial for achieving carbon budget balance. This article synthesizes the impact of farmland management practices on GHG emissions, evaluates prevalent accounting methods and their applicable scenarios, and proposes mitigation strategies based on systematic analysis. The present review (2000–2025) indicates that fertilizer management dominates research focus (accounting for over 50%), followed by water management (approximately 18%) and tillage practices (approximately 14%). Critically, the effects of these practices extend beyond GHG emissions, necessitating concurrent consideration of crop yields, soil health, and ecosystem resilience. Therefore, it is necessary to conduct joint research by integrating multiple approaches such as water-saving irrigation, conservation tillage and intercropping of leguminous crops, so as to enhance productivity and soil quality while reducing emissions. The GHG accounting framework and three primary accounting methods (In situ measurement, Satellite remote sensing, and Model simulation) each exhibit distinct advantages and limitations, requiring scenario-specific selection. Further refinement of these methodologies is imperative to optimize agricultural practices and achieve meaningful GHG reductions.

Nitrous oxide (N₂O) is a major agricultural greenhouse gas. Its direct emission factor (EF) is a key parameter for greenhouse gas inventories and developing mitigation strategies. However, the Intergovernmental Panel on Climate Change (IPCC) default EF may not reflect actual emissions from Chinese croplands. This study compiled extensive field observations from key agricultural regions in China. A systematic meta-analysis was conducted to evaluate annual N₂O emissions and nitrogen fertilizer-induced direct emission factors. Subgroup analyses revealed that fertilizer type, land use, soil texture, and climate zone all significantly influence EF. Univariate meta-regression indicated that EF is positively correlated with nitrogen (N) application rate and mean annual temperature but negatively correlated with soil pH, highlighting these factors as key drivers of N₂O emissions. The mean EF in Chinese croplands was about 0.68%, much lower than the 1% global default recommended by the IPCC. The combined effects of optimized agricultural management, cropping systems, and local environmental conditions help explain these lower emission factors. These findings provide a scientific basis for developing region-specific emission factors, improving cropland mitigation strategies, and enhancing the accuracy of greenhouse gas inventories.