This article outlines the preparation of manganese-doped copper nanoparticles (Mn + Cu NPs) using Vinca rosea (L.) leaf extract as a convenient and environmentally friendly substance. UV–vis, FT–IR, XRD, SEM–EDAX, and DLS instrumental techniques were employed to describe the physical and chemical properties of synthesized V. rosea extract-mediated Vr-Mn + Cu NPs. The synthesized Vr-Mn + Cu NPs were observed to be monodispersed and spherical, with an average size of 412 nm. The plant extract includes a variety of phytochemical components. The Vr-Mn + Cu NPs also have potential antioxidant and antibacterial properties against selected pathogens. The green synthesized Vr-Mn + Cu NPs showed a maximum inhibition zone of 16.33 ± 0.57 mm against E. coli. For dye degradation, MR, EBT, and MO showed the highest degradation percentage capabilities with Vr-Mn + Cu NP-based adsorbents, which were determined to be 78.54 ± 0.16, 87.67 ± 0.06, and 69.79 ± 0.36. The results clearly show that biosynthesized Vr-Mn + Cu NPs may be employed as an antioxidant, antibacterial, photocatalytic dye degradation, and catalytic agent, as well as being ecologically benign.

The Al- and Cu-doped ZnO nanostructured films in this study were deposited using a sputtering technique. Investigations based on X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, Hall effect measurements, and optical transmission spectroscopy was performed to analyze the structural, electrical, and optical characteristics of the prepared Al–ZnO and Cu–ZnO nanostructured films. The analyses show that doping results in enhanced conductivity as well as improved mobility in Al–ZnO and Cu–ZnO films in comparison to pure ZnO films. The Al- and Cu-doped ZnO films exhibited low resistivity (2.9 × 10⁻⁴ Ω cm for Al–ZnO and 1.7 × 10⁻⁴ Ω cm for Cu–ZnO) along with an average transmittance of around 80% in the visible spectrum. Moreover, the optical bandgaps of undoped ZnO, Al–ZnO, and Cu–ZnO nanostructures were observed as 3.3, 3.28, and 3.24 eV, respectively. Finally, solar cells were assembled by employing ZnO nanostructured thin films as photoelectrodes, resulting in efficiencies of 0.492% and 0.559% for Al–ZnO- and Cu–ZnO-based solar cells, respectively.

The nanocrystalline bismuth oxide (Bi₂O₃) was produced utilizing a green combustion process with Mexican Mint gel as the fuel. The powder X-ray diffraction (PXRD) method proved the nanocrystalline nature and Bi₂O₃ nanoparticles (BONPs) in α phase and the average crystalline size of BONPs nanoparticles has been found to be 60 nm. The spherical-shaped structure with bright dot-like spots in the center of the selected area diffraction (SAED) is confirmed by the scanning electron microscopy (SEM) and Energy dispersive X-ray spectroscopy (EDAX) in conjunction with the transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) demonstrating the crystalline behavior of green NPs. The Kubelka-Monk function was used to analyze diffuse reflectance spectra, and the results revealed that BONPs have a band gap of 3.07 eV. When utilized to evaluate the photocatalytic capabilities of NPs, the direct green (DG) and fast orange red (F-OR) dyes were found to be activated at 618 and 503 nm, respectively. After 120 min of exposure to UV radiation, the DG and F-OR dyes’ photodegradation rate reduced its hue by up to 88.2% and 94%, respectively. Cyclic voltammetry (CV) and electrochemical impedance techniques in 0.1 N HCl were used to efficiently analyze the electrochemical behavior of the produced BONPs. A carbon paste electrode that had been enhanced with BONPs was used to detect the glucose and uric acid in a 0.1 N HCl solution. The results of the cyclic voltammetry point to the excellent electrochemical qualities of BONPs. Bi₂O₃ electrode material was found to have a proton diffusion coefficient of 1.039 × 10⁻⁵ cm²s⁻¹. BONP exhibits significant potential as an electrode material for sensing chemicals like glucose and uric acid, according to the electrochemical behavior.

Photodetectors based on one-dimensional structures have recently attracted great interest due to their high surface-to-volume ratio and light-trapping efficiency. In this study, a self-powered photodetector based on vertically aligned WO₃ nanorod with SiO₂ as an interfacial layer has been fabricated using glancing angle deposition. Scanning electron microscope (SEM) analysis confirms the successful growth of WO₃ nanorod and SiO₂ thin film with a thickness of 125nm and 70nm, respectively. The devices optical properties were also analysed using UV-visible spectroscopy, which revealed a wide bandgap and an intense absorption peak in the ultraviolet region. The electrical analysis showed a nonlinear rectifying current-voltage behaviour with high photosensitivity. Additionally, the photodetector exhibits a fast response of 0.31s rise time and 0.32s fall time at 0V. Moreover, the devices possess a high detectivity and a responsivity of 0.68mA/W. Thus, the obtained finding reveals a potential candidate for self-powered photodetector application.