The use of nonrenewable fossil fuels for energy has increased in recent decades, posing a serious threat to human life. As a result, it is critical to build environmentally friendly and low-cost reliable and renewable energy storage solutions. The supercapacitor is a future energy device because of its higher power density and outstanding cyclic stability with a quick charge and discharge process. Supercapacitors, on the other hand, have a lower energy density than regular batteries. It is well known that the electrochemical characteristic of supercapacitors is strongly dependent on electrode materials. The current review highlights advance in the TMOs for supercapacitor electrodes. In addition, the newly discovered hybrid/pseudo-supercapacitors have been discussed. Metal oxides that are employed as electrode materials are the focus of this study. The discovery of nanostructured electrode materials continues to be a major focus of supercapacitor research. To create high-performance electrode materials from a morphological standpoint, various efforts have been attempted. Lastly, we analyze the supercapacitor’s evolving trend and our perspective for the future generations of supercapacitors.
15 December 2015 in International Journal of Industrial Chemistry
The corrosion inhibition study of 2-chloro 3-formyl quinoline was conducted for mild steel corrosion in 1 M hydrochloric acid solution at a temperature range of 303–333 K by chemical and electrochemical measurements. Inhibition efficiency increases with the increase of inhibitor concentration but decreases with increasing temperature. The polarization measurement reveals that the inhibitor acts as the mixed type and this inhibition effect is attributed to the adsorption of the inhibitor on the surface of mild steel from the bulk of the solution. The adsorption of 2-chloro 3-formyl quinoline on mild steel surface is exothermic and obeys the Freundlich adsorption isotherm. Thermodynamic parameters and activation parameters were calculated and discussed in depth. Scanning electron microscopy (SEM) micrographs were used to investigate the surface morphology of the steel sample in presence and absence of inhibitor.
Ni–Si3N4 nanocomposite thin films were fabricated by direct current (DC), Pulse current (PC) and Pulse reverse current (PRC) electrodeposition methods. The structure and surface morphology of thin films were analysed by XRD, Scanning Electron Microscopy and Atomic Force Microscope. Corrosion protection performance of the Ni–Si3N4 nanocomposite on mild steel in 3.5% NaCl corrosive medium was assessed by electrochemical method. Texture coefficient and microhardness of the thin films were determined and discussed. Comparisons and performance of corrosion resistance of these coatings obtained by DC electrodeposition, PC electrodeposition and with PRC electrodeposition were investigated.