In this study, highly active Fe₃O₄@PDA@Au@GO surface-enhanced Raman spectroscopy (SERS) active substrate was synthesized for application in the enrichment and detection of trace polycyclic aromatic hydrocarbons (PAHs) in the environment. The morphology and structure were characterized by transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD) and UV–visible absorption spectrum (UV–vis spectra). The effect of each component of Fe₃O₄@PDA@Au@GO nanocomposites on SERS was explored, and it was found that gold nanoparticles (Au NPs) are crucial to enhance the Raman signal based on the electromagnetic enhancement mechanism, and apart from enriching the PAHs through π–π interaction, graphene oxide (GO) also generates strong chemical enhancement of Raman signals, and polydopamine (PDA) can prevent Au from shedding and agglomeration. The existence of Fe3O4 aided the quick separation of substrate from the solutions, which greatly simplified the detection procedure and facilitated the reuse of the substrate. The SERS active substrate was used to detect phenanthrene in aqueous solution with a detection limit of 10⁻⁷ g/L (5.6 × 10⁻¹⁰ mol/L), which is much lower than that of ordinary Raman, it is promising for application in the enrichment and detection of trace PAHs.

A method for surface-enhanced Raman spectroscopy (SERS) sensing of polycyclic aromatic hydrocarbons (PAHs) is reported. Fe₃O₄@PDA@Ag@GO is developed as the SERS substrate prepared by classical electrostatic attraction method based on the enrichment of organic compounds by graphene oxide (GO) and polydopamine (PDA) and the good separation and enrichment function of Fe₃O₄. The morphology and structure of the SERS substrate were represented by transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD) and the UV–visible absorption spectrum (UV–vis spectra). The effect of different temperatures on SERS during synthesis was investigated, and it was found that the best effect was achieved when the synthesis temperature was 90 °C. The effect of each component of Fe₃O₄@PDA@Ag@GO nanocomposites on SERS was explored, and it was found that Ag NPs are of great significance to enhance the Raman signal based on the electromagnetic enhancement mechanism; apart from enriching the polycyclic aromatic hydrocarbons (PAHs) through π–π interaction, GO also generates strong chemical enhancement to the Raman signal, and PDA can prevent Ag from shedding and agglomeration. The existence of Fe₃O₄ is favored for the fast separation of substrate from the solutions, which greatly simplifies the detection procedure and facilitates the cycle use of the substrate. The experimental procedure is simplified, and the substrate is reused easily. Three kinds of PAHs (phenanthrene, pyrene and benzanthene) are employed as probe molecules to verify the performance of the composite SERS substrate. The results show that the limit of detection (LOD) of phenanthrene pyrene and benzanthene detected by Fe₃O₄@PDA@Ag@GO composite substrate are 10⁻⁸ g/L (5.6 × 10⁻¹¹ mol/L), 10⁻⁷ g/L (4.9 × 10⁻¹⁰ mol/L) and 10⁻⁷ g/L (4.4 × 10⁻¹⁰ mol/L), respectively, which is much lower than that of ordinary Raman, and it is promising for its application in the enrichment detection of trace PAHs in the environment.

This study focuses on the preparation of a highly active surface-enhanced Raman spectroscopy (SERS) substrate, where Ag nanoparticles synthesized by the Lee–Meisel method are loaded onto the surface of GO@PVP nanoparticles through classical electrostatic attraction. The substrate was characterized by SEM and XPS analysis. The SERS-active substrate was utilized for the detection of phenanthrene in aqueous solutions, achieving a detection limit of 10⁻⁸ g/L (5.6 × 10⁻¹¹ mol/L). In comparison to conventional Raman spectroscopy, this method exhibits a significant reduction in the detection limit and holds promise for trace polycyclic aromatic hydrocarbons (PAHs) monitoring in environmental samples.

Fracturing is the dominant stimulation technique for low-porosity, low-permeability dolomite gas reservoirs, yet the lack of systematic laboratory research on multistage alternating acid etching mechanisms restricts field construction parameter optimization. Targeting the low-permeability Xixiangchi Formation dolomite reservoir in the eastern Sichuan Basin, this work develops a high-temperature, high-pressure core acid etching system coupled with 3D surface scanning. A reliable lab-to-field parameter conversion is established based on the Reynolds and Froude similarity criteria. Four-factor three-level orthogonal tests are conducted to quantify the impacts of pad fluid-to-acid viscosity ratio, total acid volume, pumping rate, and alternating injection stages on JRC-characterized wall roughness and fracture conductivity. The results show an identical factor dominance ranking for both indicators: viscosity ratio > pumping rate > injection stages > total acid volume. The optimal stimulation scheme is determined as a 50:1 viscosity ratio, 120 mL total acid volume, 12.54 mL/min laboratory pumping rate (equivalent to 8 m³/min in field operations), and 3 alternating injection stages. An elevated viscosity ratio intensifies viscous fingering, induces heterogeneous dolomite dissolution, and forms abundant irregular asperities on fracture surfaces. These self-supporting rough structures sustain stable seepage channels and markedly improve conductivity, verifying the positive roughness-conductivity correlation and revealing the core mechanism of heterogeneous etching-driven conductivity enhancement. The findings provide direct experimental support and parameter guidance for multistage alternating acid fracturing design in the Xixiangchi Formation and analogous tight dolomite reservoirs.

In this paper, a surface-enhanced Raman scattering (SERS)-active substrate of GO@PVA@Pd@Ag was fabricated via a composite loading method. Palladium-silver (Pd@Ag) bimetallic nanoparticles were employed as the core enhancement unit, graphene oxide (GO) served as the carrier, and polyvinyl alcohol (PVA) functioned as the dispersant and stabilizer. The structure and properties of the substrate were analyzed by diverse characterization methods, including BET, Fourier transform infrared spectrometry (FTIR), Scanning Electron Microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). Subsequently, the SERS enhancement mechanism was preliminarily discussed. The prepared SERS-active substrate was employed to detect phenanthrene and pyrene in aqueous solution, with detection limits of 10⁻⁷ g/L and 10⁻⁸ g/L. In comparison with conventional Raman spectroscopy, this approach substantially reduces the detection limit and is anticipated to be utilized for the rapid detection of trace phenanthrene in the environment.