In this study, highly active Fe₃O₄@PDA@Au@GO surface-enhanced Raman spectroscopy (SERS) active substrate was synthesized for application in the enrichment and detection of trace polycyclic aromatic hydrocarbons (PAHs) in the environment. The morphology and structure were characterized by transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD) and UV–visible absorption spectrum (UV–vis spectra). The effect of each component of Fe₃O₄@PDA@Au@GO nanocomposites on SERS was explored, and it was found that gold nanoparticles (Au NPs) are crucial to enhance the Raman signal based on the electromagnetic enhancement mechanism, and apart from enriching the PAHs through π–π interaction, graphene oxide (GO) also generates strong chemical enhancement of Raman signals, and polydopamine (PDA) can prevent Au from shedding and agglomeration. The existence of Fe3O4 aided the quick separation of substrate from the solutions, which greatly simplified the detection procedure and facilitated the reuse of the substrate. The SERS active substrate was used to detect phenanthrene in aqueous solution with a detection limit of 10⁻⁷ g/L (5.6 × 10⁻¹⁰ mol/L), which is much lower than that of ordinary Raman, it is promising for application in the enrichment and detection of trace PAHs.

A method for surface-enhanced Raman spectroscopy (SERS) sensing of polycyclic aromatic hydrocarbons (PAHs) is reported. Fe₃O₄@PDA@Ag@GO is developed as the SERS substrate prepared by classical electrostatic attraction method based on the enrichment of organic compounds by graphene oxide (GO) and polydopamine (PDA) and the good separation and enrichment function of Fe₃O₄. The morphology and structure of the SERS substrate were represented by transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD) and the UV–visible absorption spectrum (UV–vis spectra). The effect of different temperatures on SERS during synthesis was investigated, and it was found that the best effect was achieved when the synthesis temperature was 90 °C. The effect of each component of Fe₃O₄@PDA@Ag@GO nanocomposites on SERS was explored, and it was found that Ag NPs are of great significance to enhance the Raman signal based on the electromagnetic enhancement mechanism; apart from enriching the polycyclic aromatic hydrocarbons (PAHs) through π–π interaction, GO also generates strong chemical enhancement to the Raman signal, and PDA can prevent Ag from shedding and agglomeration. The existence of Fe₃O₄ is favored for the fast separation of substrate from the solutions, which greatly simplifies the detection procedure and facilitates the cycle use of the substrate. The experimental procedure is simplified, and the substrate is reused easily. Three kinds of PAHs (phenanthrene, pyrene and benzanthene) are employed as probe molecules to verify the performance of the composite SERS substrate. The results show that the limit of detection (LOD) of phenanthrene pyrene and benzanthene detected by Fe₃O₄@PDA@Ag@GO composite substrate are 10⁻⁸ g/L (5.6 × 10⁻¹¹ mol/L), 10⁻⁷ g/L (4.9 × 10⁻¹⁰ mol/L) and 10⁻⁷ g/L (4.4 × 10⁻¹⁰ mol/L), respectively, which is much lower than that of ordinary Raman, and it is promising for its application in the enrichment detection of trace PAHs in the environment.

To investigate the flow-field characteristics of a submerged pre-mixed abrasive water jet impinging on a wall, a physical model of the conical–cylindrical nozzle and computation domain of a submerged pre-mixed abrasive-water-jet flow field were established. Based on the software of FLUENT 2022R2, numerical simulation of the solid–liquid two-phase flow characteristics of the submerged pre-mixed abrasive water jet impinging on a wall was conducted using the DPM particle trajectory model and the realizable $k–\epsilon$ turbulence model. The simulation results indicate that a “water cushion layer” forms when the submerged pre-mixed abrasive water jet impinges on a wall. Tilting the nozzle appropriately facilitates the rapid dispersion of water and abrasive particles, which is beneficial for cutting. The axial-jet velocity increases rapidly in the convergent section of the nozzle, continues to accelerate over a certain distance after entering the cylindrical section, reaches its maximum value inside the nozzle, and then decelerates to a steady value before exiting the nozzle. In addition, the standoff distance has minimal impact on the flow-field characteristic inside the nozzle. When impinging on a wall surface, rapid decay of axial-jet velocity generates significant stagnation pressure. The stagnation pressure decreases with increasing standoff distance for different standoff-distance models. Considering the effects of standoff distance on jet velocity and abrasive particle dynamics, a standoff distance of 5 mm is determined to be optimal for submerged pre-mixed abrasive-water-jet pipe-cutting operations. When the submergence depth is less than 100 m, its effect on the flow-field characteristics of a submerged pre-mixed abrasive water jet impinging on a wall surface remains minimal. For underwater oil pipelines operating at depths not exceeding 100 m, the influence of submergence depth can be disregarded during cutting operations.

Mobile pipeline refers to a type of pipeline that can be laid and recovered at any time as required, mainly used for product oil transportation. After the completion of the transportation mission, the oil remaining inside the pipeline needs to be evacuated before recovering. Water-driven oil evacuation is commonly used for this purpose. In this paper, the water-driven oil evacuation in an inclined inverted U-shaped pipe was investigated. A numerical model coupling the VOF interface-capturing method, the CSF surface-tension model, and the SST k–ω turbulence model was established and validated against visualization experiments. The oil–water two-phase displacement characteristics in this special pipe configuration were systematically analyzed. The results show that a critical inlet superficial water velocity exists during the evacuation process. Complete oil evacuation can be achieved only when the inlet superficial water velocity exceeds this critical value. The critical velocity increases with increasing pipe inclination angle and pipe diameter. When the inlet superficial water velocity is lower than the critical value, vortical structures and backflow are readily generated at the oil front and within the oil phase, leading to oil accumulation near the end of the upper horizontal section and the formation of a stable retained oil layer in the downward-inclined section. Moreover, larger inclination angles and pipe diameters intensify oil retention and reduce the evacuation efficiency under subcritical conditions. All conclusions are drawn based on the No. 0 diesel–water system at 25 °C, and the applicable scope is limited to working conditions with similar fluid physical properties.