In this work, the potential of a novel hydroxyapatite decorated with carbon nanotube composite (CNT-HAP) for fluoride removal was investigated. The synthesized CNT-HAP composite was systematically characterized by X-ray diffraction(XRD), Fourier Transform infrared spectroscopy(FTIR), scanning electron microscope (SEM) and Brunauer–Emmett–Teller(BET). Batch adsorption experiments were conducted to investigate the defluorination capacity of CNT-HAP. The CNT-HAP composite has a maximum adsorption capacity of 11.05 mg·g⁻¹ for fluoride, and the isothermal adsorption data were fitted by the Freundlich model to calculate the thermodynamic parameters. Thermodynamic analysis implies that the adsorption of fluoride on CNT-HAP is a spontaneous process. Furthermore, the adsorption of fluoride follows pseudo-second-order model. The effects of solution pH, co-existing anions and reaction temperature on defluorination efficiency were examined to optimize the operation conditions for fluoride adsorption. It is found that the optimized pH-value for fluoride removal by CNT-HAP composite is 6. In addition, among five common anions studied in this work, the presence of ${\text{HCO}}_3^{-}$ and ${\text{PO}}_4^{3-}$ could considerably affect the fluoride removal by CNT-HPA in aqueous media. Finally, the underlying mechanism for the fluoride removal by CNT-HAP is analyzed, and an anion exchange process is proposed.

The tremendous input of ammonium and rare earth element (REE) ions released by the enormous consumption of (NH₄)₂SO₄ in in situ leaching for ion-adsorption RE mining caused serious ground and surface water contamination. Anaerobic ammonium oxidation (anammox) was a sustainable in situ technology that can reduce this nitrogen pollution. In this research, in situ, semi in situ, and ex situ method of inoculation that included low-concentration (0.02 mg·L⁻¹) and high-concentration (0.10 mg·L⁻¹) lanthanum (La)(III) were adopted to explore effective start-up strategies for starting up anammox reactors seeded with activated sludge and anammox sludge. The reactors were refrigerated for 30 days at 4 °C to investigate the effects of La(III) during a period of low-temperature. The results showed that the in situ and semi in situ enrichment strategies with the addition of La(III) at a low-concentration La(III) addition (0.02 mg·L⁻¹) reduced the length of time required to reactivate the sludge until it reached a state of stable anammox activity and high nitrogen removal efficiency by 60–71 days. The addition of La(III) promoted the formation of sludge floc with a compact structure that enabled it to resist the adverse effects of low temperature and so to maintain a high abundance of AnAOB and microbacterial community diversity of sludge during refrigeration period. The addition of La(III) at a high concentration caused the cellular percentage of AnAOB to decrease from 54.60 ± 6.19% to 17.35 ± 6.69% during the enrichment and reduced nitrogen removal efficiency to an unrecoverable level to post-refrigeration.

The pollution of water bodies by nutrients and heavy metals can lead to a loss of biodiversity, environmental degradation, and harm to human health. During the two-month monitoring period (e.g., December 2019 to January 2020), variables such as trace metals (e.g., Cu, Zn, As, and Cr), nutrients (e.g., NH₄⁺-N, TN, and TP), water temperature, pH value, dissolved oxygen (DO), chemical oxygen demand (COD) and five-day biochemical oxygen demand (BOD₅) were measured at 102 monitoring points in the main stream and tributaries of the Ganjiang River in the Poyang Lake Basin. A variety of multivariate statistical techniques, including cluster analysis (CA), principal component analysis (PCA), and correlation analysis, were used to conduct risk assessments and source analyses of the nutrient elements and heavy metals in the Ganjiang River system. The results show that although the Ganjiang River Basin is polluted by human activities, its water chemistry characteristics and trace metal and nutrient elements concentrations were better than the national standards. Through principal component analysis, the water pollution sources could be divided into urban sewage, agricultural activities, industrial activities, and the sources of industrial activities and transportation activities. The comprehensive risks of noncarcinogens (H^c) and comprehensive risks of carcinogens (R^c) for adults and children due to drinking water indicated that the risk from drinking water for the children in the basin was greater than that for adults, and that the H^c for adults and children was acceptable. However, the R^c for adults and children was slightly higher than the acceptable values. This study provides a reference for the fine control of the environmental water pollution sources in the Ganjiang river basin and health risk assessments in the basin, which are of great significance for improving the environmental water quality standards in the river basin and for reducing the risk of carcinogenesis.