Handling of food waste and agro-industrial waste digestates, and fly and bottom wood ashes represents an economic and environmental problem for society and industries where they are produced due to the requirement of large capacity storage facilities with special conditions. Since both materials contain important nutrients for crops, two different blending combinations were examined as potential slow-release fertilizers to enhance the circular economy. High share of biomass ashes were selected aiming the chemical alkaline stabilization of the digestates. The concentrations of nitrogen, carbon, and phosphorus in the water-soluble extract of the blends, which was obtained by adding ten parts of milli-Q® per each part of sample and subsequent solid–liquid separation, were measured during a 10-h incubation at 22 °C and 100 rpm. The volatilization of ammonia was the main route of losing nitrogen, with the greatest rate of volatilization at the time of blending and approximately 50 mg NH₃-N/kg blend/hour by the end of the incubation. The hydrolysis taking place at alkaline pH was found responsible of the conversion of organic nitrogen to ammoniacal nitrogen and of the increase of the amount of water-soluble carbon, which rose progressively during the incubation. The release of CO₂ was prevented by the high pH (> 10) of the blends. The drop in the concentration of water-soluble orthophosphate at the time of preparing the mixtures was driven by adsorption onto the ashes. The desorption of some of the orthophosphate was found to be inversely related to the amount of ashes added to the digestates. Graphic Abstract

The use of the commercial simulator Aspen Plus^® could bring an amelioration in the accuracy of the predictions of the chemical species composition in the output streams of the anaerobic digestion process. Compared to the traditionally employed lumped models, which are elaborated from scratch, the models implemented in Aspen Plus^® have access to a broad library of thermodynamic and phenomena transport properties. In the present investigation, a process simulation model for anaerobic digestion has been prepared by including a stoichiometric-equilibria reactor to calculate the extent of the ionization of the molecules present in the anaerobic digestate. The model characterizes the technical feasibility of anaerobic digestate stabilization, by means of biomass ash-based treatment, for the production of an organic fertilizer and potential biogas upgradation with the synthesis of ammonium carbonate. First of all, the titration of the manure digestate with the hydrochloric acid showed that a dose of 3.18 mEq/g would be required to attain the targeted pH of zero-point charge, upon addition of the sewage sludge ash in a ratio to the manure digestate of 0.6 ± 0.2%. Secondly, the profiles of ammonia, carbon dioxide, and methane found in the biogas agree with the pH of the treated digestate and enable the upgrading of the biogas with the production of NH₄HCO₃. The model needs to be further developed to ensure the standards are attained in all output streams of stabilized anaerobic digestate, biomethane, and isolated added-value chemical fertilizers.

The manufacturing of a granular fertilizer based on organic slurry (OS) and sorptive materials aims to enhance the circular economy. This article describes a technology that was conceived after appraising the chemistry of the anaerobic digestate and wood ash and the synergies of combining both materials. The information available in the literature about similar materials such as cattle slurry and lime was also considered to build a better understanding of the underlying science. The processes and machinery designed were optimized from the points of view of energy and material consumption, cost of storage, transportation and land application. The system was sized to process 1 tonne of OS (97% moisture) in a 10 h batch-shift, consuming 140 kg of wood pellets and 0.55 kW of electricity for the fan blowing preheated air. The results of the market research allowed us to reach the most economically viable routes for the commercialization of granular fertilizers. Based on the financial study, an initial investment of GBP 20,000 is needed to successfully implement the value proposition and business plan. The wide adoption of the composite fertilizer improves the management of the OS and reduces the contamination of air, soil, and water derived from intensive agricultural practices.