Magnesium hydride (MgH₂) has been considered as a potential material for storing hydrogen, but its practical application is still hindered by the kinetic and thermodynamic obstacles. Herein, Mn-based catalysts (MnCl₂ and Mn) are adopted and doped into MgH₂ to improve its hydrogen storage performance. The onset dehydrogenation temperatures of MnCl₂ and submicron-Mn-doped MgH₂ are reduced to 225 °C and 183 °C, while the un-doped MgH₂ starts to release hydrogen at 315 °C. Further study reveals that 10 wt% of Mn is the better doping amount and the MgH₂ + 10 wt% submicron-Mn composite can quickly release 6.6 wt% hydrogen in 8 min at 300 °C. For hydrogenation, the completely dehydrogenated composite starts to absorb hydrogen even at room temperature and almost 3.0 wt% H₂ can be rehydrogenated in 30 min under 3 MPa hydrogen at 100 °C. Additionally, the activation energy of hydrogenation reaction for the modified MgH₂ composite significantly decreases to 17.3 ± 0.4 kJ/mol, which is much lower than that of the primitive MgH₂. Furthermore, the submicron-Mn-doped sample presents favorable cycling stability in 20 cycles, providing a good reference for designing and constructing efficient solid-state hydrogen storage systems for future application.

The existence and development of modern society require significant amounts of available energy. Combustion engines are the main sources of heat. Their operation is accompanied by the formation of large volumes of emissions, which have different temperatures and contain harmful substances ejected into the environment. Therefore, the urgent problem today is the reduction in heat emissions. This might be achieved through a reduction in the amount of these pollutants by improving primary heat engines, converting to new, alternative types of fuel, and at the same time, to carbon-free fuel. However, such measures only reduce the temperature level of waste heat but not its volume. Conventional technologies for the utilization of heat emissions are ineffective for using heat with temperatures below 500 K. Thermoacoustic technologies can be used to convert such low-temperature heat emissions into mechanical work or electricity. This article is focused on analyzing the possibilities of improving the thermoacoustic engines of energy-saving systems through the rational organization of thermoacoustic energy conversion processes. An original mathematical model of energy exchange between the internal elements of thermoacoustic engines is developed. It is shown that the use of recuperative heat exchangers in thermoacoustic engines leads to a decrease in their efficiency by 10–30%. From the research results, new methods of increasing the efficiency of low-temperature engines of energy-saving systems are proposed.

One of the most effective methods towards improving the environmental safety of combustion engines is the application of specially prepared water-fuel emulsions (WFE). The application of WFE makes it possible to reduce primary sulfur fuel consumption and reveals the possibility of capturing the pollutants from exhaust gases by applying condensing low-temperature heating surfaces (LTHS). In order to realize such a double effect, it is necessary to investigate the pollution processes on condensing LTHS of exhaust gas boilers (EGB), especially the process of low-temperature condensing a sulfuric acid vapor from exhaust gases to investigate the influence of condensing LTHS on the intensity of pollutants captured from the exhaust gases. The aim of this research is to assess the influence of the intensity of pollutants captured from exhaust gases by condensing LTHS in dependence of water content in WFE combustion. Investigations were carried out at a special experimental setup. The processing of the results of the experimental studies was carried out using the computer universal statistical graphic system Statgraphics. Results have shown that in the presence of a condensing heating surface, the degree of capture (purification) of pollutants from the exhaust gas flow is up to 0.5–0.6.

Gas turbine intake air cooling (TIAC) by exhaust gas heat recovery chillers is a general trend to improve turbine fuel efficiency at increased ambient temperatures. The high efficiency absorption lithium–bromide chillers of a simple cycle are the most widely used, but they are unable to cool inlet air lower than 15 °C. A two-stage hybrid absorption–ejector chillers were developed with absorption chiller as a high temperature stage and ejector chiller as a low temperature stage to subcool air from 15 °C to 10 °C and lower. A novel trend in TIAC by two-stage air cooling in hybrid chillers has been substantiated to provide about 50% higher annual fuel saving in temperate climate as compared with absorption cooling. A new approach to reduce practically twice design cooling capacity of absorption chiller due to its rational distribution with accumulating excessive refrigeration energy at decreased thermal loads to cover the picked demands and advanced design methodology based on it was proposed. The method behind this is issued from comparing a behavior of the characteristic curves of refrigeration energy required for TIAC with its available values according to various design cooling capacities to cover daily fluctuation of thermal loads at reduced by 15 to 20% design cooling capacity and practically maximum annual fuel reduction.

The application of water-fuel emulsion (WFE) in internal combustion engines enables to reduce the consumption of sulfurous fuel oils, thereby protecting the environment from emissions of sulfur and nitrogen oxides, as well revealing a great potential for the heat utilization of exhaust gases. The efficiency of utilization of exhaust gas heat in exhaust boilers (EGB) depends on their temperature at the outlet of EGB, id est. the depth of heat utilization. Exhaust gas temperature is limited by the rate of low-temperature corrosion (LTC), which reaches a level of 1.2 mm/year at the wall temperature of about 110 °C for the condensing heat exchange surfaces (HES) and reduces the reliability of the HES operation. Therefore, decreasing the corrosion rate of condensing HES at wall temperature below 110 °C to an acceptable level (about 0.2 mm/year) when undergoing WFE combustion will make it possible to reduce the exhaust gas temperature and, consequently, increase the efficiency of EGB and fuel saving during the operation of the ship power plant. The aim of the research is to assess improvements to the reliability, durability and efficient operation of condensing HES in marine EGB undergoing WFE combustion in a diesel engine based on experimental studies of the LTC process. A special experimental setup was developed for investigation. The use of WFE with a decreased wall temperature of HES below 80 to 70 °C would improve the reliability of the EGB along the accepted service life, increase the lifetime of the HES metal by almost six times as well as the overhaul period, and reduce the cost of repairing condensing HES. Furthermore, due to the reducing corrosion rate under WFE combustion, the application of low-temperature condensing HES makes it possible to enhance the efficiency of deeper exhaust gas heat utilization and provide sustainable efficient operation of a diesel engine plant on the whole at a safe thermal and environmentally friendly level.