The high recombination rates of photogenerated electron-holes greatly inhibit the catalytic activity of semiconductor photocatalysts. Herein, the heterojunctions of the flower-like g-C₃N₄/BiOBr composites were synthesized as photocatalysts by a simple hydrothermal process. The X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectrometer were utilized to characterize the sample's structure and light absorption properties. The results demonstrated that BiOBr-g-C₃N₄-4:1 showed excellent photocatalytic properties and 96.6% of bisphenol (BPA) was removed in 120 min with illumination of visible light due to its narrower band gap than that of pure BiOBr. BiOBr offer little electrons during the photocatalytic reaction. Moreover, the heterostructure between BiOBr and g-C₃N₄ facilitates the separation of photogenerated carriers. Excellent stability was exhibited after five cyclic degradation of methyl orange (MO) with the illumination of visible light. The active species trapping experiment indicated that superoxide radical anions (${\text{O}}_2^{•-}$) and hole (h⁺) have a great effect on the reaction. A possible mechanism was proposed to explain the whole process of photocatalytic reaction.