Lithium-sulfur (Li-S) batteries have nice prospects because of their excellent energy density and theoretical specific capacity. However, the dissolution of lithium polysulfides and shuttle effects lead to a low coulombic efficiency and cycle performance of Li-S batteries. Therefore, designing electrode materials that can suppress the shuttle effect and adsorb polysulfides is of great significance. In this work, a Co and N-codoped carbon composite via heating a type of Co-etched zeolitic imidazolate framework-67 (ZIF-67), nanocube precursor, in inert gas is reported as a cathode sulfur carrier material for Li-S batteries. The experimental results show that high-temperature carbonization results in mesoporous structures inside the material which not only provide ion channels for the reaction but also improve the adsorption capacity of polysulfides. Furthermore, the exposed metal Co sites and N atoms can also inhibit the shuttle effect. When the annealing temperature is 600 °C, the sulfur composite exhibits a good cycling stability and rate performance. The cathode showed an improved initial specific capability of 1042 and still maintained 477 mAh g⁻¹ at the rate of 1 C (1 C = 1672 mA g⁻¹). Furthermore, at 5 C, a stable specific discharge capacity of 608 mAh g⁻¹ was obtained.

The advantages of high energy density and low cost make lithium–sulfur batteries one of the most promising candidates for next-generation energy storage systems. However, the electrical insulativity of sulfur and the serious shuttle effect of lithium polysulfides (LiPSs) still impedes its further development. In this regard, a uniform hollow mesoporous Ni(OH)₂@CNT microsphere was developed to address these issues. The SEM images show the Ni(OH)₂ delivers an average size of about 5 μm, which is composed of nanosheets. The designed Ni(OH)₂@CNT contains transition metal cations and interlayer anions, featuring the unique 3D spheroidal flower structure, decent porosity, and large surface area, which is highly conducive to conversion systems and electrochemical energy storage. As a result, the as-fabricated Li-S battery delivers the reversible capacity of 652 mAh g⁻¹ after 400 cycles, demonstrating excellent capacity retention with a low average capacity loss of only 0.081% per cycle at 1 C. This work has shown that the Ni(OH)₂@CNT sulfur host prepared by hydrothermal embraces delivers strong physical absorption as well as chemical affinity.