The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field. In this study, a Janus window is proposed and prepared based on polymer-stabilized liquid–crystal films/thermochromic materials. It can achieve switchable front long-wave infrared emissivity (ε _Front) and solar modulation ability (ΔT _sol) through dynamic flipping, making it suitable for different seasonal energy-saving requirements. Outdoor experiments show that under daytime illumination, the indoor temperature decreases by 8 °C, and the nighttime temperature drops by 5 °C. MATLAB simulation calculations indicate that the daytime cooling power is 93 W m⁻², while the nighttime cooling power reaches 142 W m⁻². Interestingly, by modifying the conductive layer, it can effectively shield electromagnetic radiation (within the X-band frequency range (8.2–12.4) GHz). Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal, poly(N-isopropyl acrylamide), and normal glass when applied in different climate zones. This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.

Intelligent soft robots that integrate both structural color and controllable actuation ability have attracted substantial attention for constructing biomimetic systems, biomedical devices, and soft robotics. However, simultaneously endowing single-layer cholesteric liquid crystal elastomer (CLCE) soft actuators with reversible 3D deformability and vivid structural color changes is still challenging. Herein, a multi-responsive (force, heat and light) single-layer 3D deformable soft actuator with vivid structural color-changing ability is realized through the reduced graphene oxide (RGO) deposition-induced Janus structure of the CLCE using a precisely-controlled evaporation method. This single-layer structural color soft actuator can directly transform from a flat shape to a 3D shape through the photothermal effect. The introduction of RGO not only improves the mechanical properties and color saturation of the CLCE, but also endows it with near-infrared (NIR) light responsiveness via the photothermal effect. Moreover, due to the structural gradient resulting from the spontaneous deposition of RGO during the deswelling process, CLCEs show a stacked structure of the helical CLC layer and RGO-dispersed amorphous layer, which are capable of undergoing multiple reversible 3D deformations. The reversible deformations of biomimetic devices such as petal-like films imitating blooming flowers, thin strips imitating plant tendrils, and a cobweb-inspired catching net are achieved to demonstrate applications of this single-layer RGO/CLCE composite film. This work provides a simple strategy for the construction of single-layer 3D deformable soft actuators.

In this paper, dye-doped polymer-dispersed liquid crystalline (DDPDLC) films were prepared with high mechanical properties and low driving voltage by doping different dichroic anthraquinone dyes. The effects of various dye and doping concentrations on microscopic morphology, electro-optical characteristics, and mechanical characteristics were investigated. The optimal doping concentrations of different dyes were also explored. The results show that the addition of all dyes decreased the contrast ratio (CR) and the transmittance and mechanical properties of the polymer-dispersed liquid crystalline (PDLC) films. Similar mechanisms underlie the effects of solvent red 111 and solvent blue 104, which lower the driving voltages of the PDLC films. With the increasing concentration of the dye, the haze of the films first decreased and then increased after the content of the dye reached a certain level. For PDLC films doped with solvent green 28, the driving voltage and haze increased with the increasing content of the dye. According to different influencing factors, the dye content corresponding to the best performance of solvent red 111, solvent green 28 and solvent blue 104 is 0.8 wt%, 2.0 wt% and 0.3 wt%. Electrochromic PDLC films have been prepared based on the research results of dye content. The mechanical properties, electro-optical properties and microstructures of the films have been studied. The results show that the DDPDLC films could change color by tuning the applied voltages. The research provides a theoretical basis for obtaining PDLC films with a wider color gamut and supports the practical application of visible light camouflage technology in the military.

In this work, hydroxylated compounds are applied to prepare polymer-dispersed liquid crystal (PDLC) films and the role of the hydroxy group is studied in detail by comparing the effects of the hydroxylated acrylate monomer, the hydroxylated mesogenic component and their corresponding non-hydroxylated components. It is revealed that the hydroxylated acrylate monomer plays a more important role in modifying the morphology of the polymer matrix and thereby the electro-optical performance of the PDLC films. Parameters of the polymer matrix, such as size and density of voids, can be affected by various components, but only the hydroxylated acrylate monomer can alter its type from the typical Swiss-cheese type to the polymer-microsphere type. Essentially, the hydroxylated mesogenic component takes effect through changing the ratio of the liquid crystal phase, while the hydroxylated acrylate monomer can participate in the polymerization and impact the development of the polymer matrix. It is anticipated that this research can help in understanding the role of the hydroxy group in PDLC films.