The modern rhythm of human life leads to well-known problems, which are air, water and soil pollution and climate warming. An increase in the power of industries and vehicles leads not only to atmospheric pollution by-products of incomplete fuel combustion but also to various microscopic particles that form aerosols, which carry an obvious danger to human health and also pollute the buildings’ facades. An environmentally friendly building material with a hybrid method “Nano-titania gradient” was developed. This method consists of forming a gradient of n-TiO2 particles concentration in the composite since the physical properties of the composite are always inextricably linked to the geometry. To increase the efficiency of the photocatalytic process, a method of surface sensitization of titanium dioxide with the use of graphene oxide was proposed, which contributed to an increase in the overall photosensitivity. Thus, the decomposition of nitrogen oxide by volume with the modified surface increased by 27% in comparison with the classic titanium dioxide, and the decomposition of volatile organic substances increased by 32%. It was found that for the facade plate made with surface-sensitized TiO2, the process of self-cleaning is completed after 3 h after the irradiation start. The modern rhythm of human life leads to well-known problems, which are air, water and soil pollution and climate warming. Using the theory of percolation, the concentration range of the photocatalyst content was calculated. To facilitate the material, waste cellulose was introduced. To increase the efficiency of the photocatalytic process, a method of surface sensitization of titanium dioxide (SS TiO2) with the use of graphene oxide was proposed. The analysis of the experimental-statistical models of the compressive strength shows that the optimum content of TiO2 was in the range from 0.8 to 1.1%, and cellulose from 0.4 to 0.8%, the optimum content of SS TiO2 was in the range from 0.7 to 1.1%, and cellulose from 0.4 to 0.8%. Analysis of the experimental and statistical model of the bending strength shows that the optimal content of TiO2 and SS TiO2 was in the range of 0.6 to 1.0%, and cellulose from 0.4 to 0.8%. When studying the structure of composites, it was found that titanium dioxide was sorbed on the surface of swollen cellulose fibers and remained there after the process of cement hydration. The effectiveness of the method of surface sensitization of titanium dioxide by combining it with graphene oxide was shown. Thus, the decomposition of nitrogen oxide by volume with the modified surface increased by 27% in comparison with the classic titanium dioxide, and the decomposition of volatile organic substances increased by 32%. It was found that for the facade plate made with surface-sensitized TiO2, the process of self-cleaning was completed after 3 h after the irradiation start.
The research is devoted to developing the production of crumb rubber-modified bitumen with improved stability. It has been established that the most suitable semi-empirical coefficient for determining the compatible plasticizer to crumb rubber is based on the ratio of paraffin-naphthenic compounds to resinous-asphaltene compounds. With the help of differential scanning calorimetry, temperature regimes of crumb rubber destruction and preparation of rubber-containing components (210 °C) were studied and determined. It was established that determining the dynamic viscosity of hydrocarbon concentrates with crumb rubber on a rotary viscometer is not applicable due to elastic components, making it difficult to measure and obtain reliable data. The most suitable method is the shear viscosity method. Using fluorescent microscopy, it was established that the formation of a branched structure of crumb rubber is achieved in the waste industrial oil, indicating devulcanization processes. It was found that hydrocarbon plasticizer with high naphthenic oil content is the most compatible with crumb rubber. Synthetic wax was found to be of greater interest as a devulcanizing/stabilizing agent, and its application in an amount of 3% allows the formation of a stable CRMB structure and stabilizes the devulcanization process.
1 December 2007 in Theoretical Foundations of Chemical Engineering
A thermodynamic method intended for choosing the most efficient flowsheet in developing new technologies of processing the natural gas is proposed. The method was tested for the process of synthesizing methanol and used in designing a new process, dimethyl ether synthesis.
1 May 2021 in Inorganic Materials: Applied Research
It is found that the time of establishing a critical contact angle of wetting the surface of a pressed sample made of polycrystalline quartz powder with different liquids is determined primarily by the viscosity of the liquid. It is shown that, in order to determine the critical contact angle of powder materials, it is necessary to record the moment at which the diameter of the base of a liquid droplet on the surface of a powder sample has a maximum value.