In this paper, a two-dimensional characteristic unit was used to simulate the thermal–mechanical performance of a fully ceramic microencapsulated (FCM) fuel pellet, and the criterion of FCM structure integrity was discussed. FCM structure integrity can be reflected though the integrity of the silicon carbide (SiC) matrix or SiC layers because of the excellent fission retention capability of SiC ceramics. The maximum temperature of the SiC matrix under normal conditions of the pressure water reactor (PWR) environment was about 1390 K, which was lower than the decomposition point of SiC. The maximum hoop stress of the SiC matrix, especially the inner part, was up to about 1200 MPa, and the hoop stress of the non-fuel region part was lower than the inner part, which can be attributed to the deformation of tristructural-isotopic (TRISO) particles. The hoop stress of the SiC layers at the end of life was only about 180 MPa, which is much lower than the strength of the chemical vapor deposition (CVD)-SiC. The failure probability of the SiC layer was lower than 9 × 10⁻⁵; thus, the integrity of SiC layers and the fission retention capability were maintained. The structure integrity of FCM fuel was broken because the SiC matrix cracked.

Short-range order can be developed in multi-principal element alloys and influences the point defect behavior due to the large variation of the local chemical environment. The effect of short-range order on vacancy and interstitial formation energy and migration behavior was studied in body-centered cubic multi-principal element alloy NbZrTi by first-principles calculations. Two short-range order structures created by density functional theory and Monte Carlo method at 500 and 800 K were compared with the structure of random solid solution. Both vacancy and interstitial formation energies increase with the degree of short-range order. Point defect formation energies tend to be higher in regions enriched in Nb and lower in regions enriched in Zr and Ti. Both vacancies and interstitials prefer to migrate toward Zr,Ti-rich regions and away from Nb-rich regions, suggesting that Zr,Ti-rich regions can potentially act as recombination centers for point defect annihilation. Compared to an ideal random solid solution, the short-range order increases the spatial inhomogeneity of point defect energy landscape. Tuning the degree of short-range order by different processing techniques can be a viable strategy to optimize the point defect behavior to achieve enhanced radiation resistance in multi-principal element alloys.

MAX phases are promising candidate structural materials for lead-cooled fast reactors (LFRs) and accelerator-driven sub-critical systems (ADSs) due to their excellent corrosion resistance in liquid LBE. In this work, one of the typical MAX phases, Ti₃SiC₂, was exposed to the flowing LBE with a saturated oxygen concentration at 500 °C for up to 3000 h. The corrosion behaviors, including the evolution of the corrosion layer, mechanical properties and wettability, were evaluated via X-ray diffraction, a scanning electron microscope equipped with an energy-dispersive X-ray, a microhardness test and contact angle measurement. The results reveal that a corrosion structure with a duplex layer was formed on the sample surfaces. The outer layer was a diffusion layer, which always remained thin (<3 μm) during the whole test due to the erosion effect caused by the flowing LBE. The inner layer was the stable protective oxide layer, and its thickness increased with exposure time. The growth of the corrosion structure improved the microhardness and reduced the wettability with regard to LBE, which was beneficial to inhibiting further surface corrosion of Ti₃SiC₂.

FeCrAlY coatings deposited on the outer surface of the cladding tube by the magnetron sputtering with varying bias voltages (0 V to −500 V) were corroded at 550°C to 600°C in oxygen-saturated and oxygen-poor lead-bismuth eutectic for 500 h to 1,000 h. The increased bias voltage led to the Al content decreased and the Y content increased. The coating changed from columnar crystals to equiaxed crystals with increased bias voltage. The decreased bias voltage makes an improved corrosion resistance. The fundamental process governing the evolution of microstructure and corrosion resistance in the FeCrAlY coatings was discussed.

Seven FeCrAlY-Al₂O₃ nanoceramic composite coatings are deposited on F/M steel via plasma spraying and laser remelting. A systematic investigation is conducted to examine the dependence of microstructure, mechanical properties, and lead–bismuth eutectic (LBE) corrosion resistance on the nano-Al₂O₃ addition and different Cr and Al contents. With the increase in Al content in FeCrAlY, gradual refinement of the coating grains occurs. The addition of nano-Al₂O₃ promotes the elemental segregation and precipitation of the second phase. The nano-Al₂O₃ notably enhances the mechanical properties of the coatings that are primarily attributed to second-phase and fine-grain strengthening. After LBE corrosion tests, intergranular corrosion morphology could be observed, where the contents of Cr and Al significantly influence the corrosion behavior of the coatings at varying temperatures.