Ni1−xZnxFe2O4 (x = 0.5, 0.6, 0.7) nanoparticles were synthesized by a thermal decomposition method. The synthesized particles were identified as pure spinel ferrite structures by X-ray diffraction analysis, and they were calculated to be 46–51 nm in diameter by the Scherrer equation, depending on the composition. In the FE-SEM image, the ferrite nanoparticles have spherical shapes with slight agglomeration, and the particle size is about 50 nm, which was consistent with the value obtained by the Scherrer equation. The lattice parameter of the ferrite nanoparticles monotonically increased from 8.34 to 8.358 Å as the Zn concentration increased from 0.5 to 0.7. Initially, the saturation magnetization value slowly decreases from 81.44 to 83.97 emu/g, then quickly decreases to 71.84 emu/g as the zinc content increases from x = 0.5, through 0.6, to 0.7. Ni1−xZnxFe2O4 toroidal samples were prepared by sintering ferrite nanoparticles at 1250 °C and exhibited faceted grain morphologies in the FE-SEM images with their grain sizes being around 5 µm regardless of the Zinc content. The real magnetic permeability (μ′) of the toroidal samples measured at 5 MHz was monotonically increased from 106, through 150, to 217 with increasing the Zinc content from x = 0.5, through 0.6, to 0.7. The cutoff frequency of the ferrite toroidal samples was estimated to be about 20 MHz from the broad maximum point in the plot of imaginary magnetic permeability (μ″) vs. frequencies, which seemed to be associated with domain wall resonance.
Three types of In2O3 nanoparticles decorated with Au, Pd and Pt nanoparticles, respectively, were synthesized by thermal decomposition method, and the effects of metal nanoparticles on their phase, microstructure, chemical state, carrier types were investigated with XRD, SEM/TEM, and XPS. Additionally, sensing properties to CO gas, such as sensitivity, etc., were examined with sensing apparatus. Au-decorated In2O3 nanoparticles exhibited the highest sensitivity to CO gas, with S = 5.59 at a 10 ppm CO gas concentration at 50 °C compared to Pd or Pt-decorated In2O3 nanoparticles. This can be interpreted as a much higher adsorption of oxygen molecules on the In2O3 surface due to the high oxygen vacancies in the In2O3 lattice, which generates an electron depletion region in the outer layer of In2O3 to sharply increase the resistance or the spill-over effect due to Au nanoparticles on In2O3. Au nanoparticles were observed in the TEM images and confirmed by XPS analysis.
(Pb, La)(Zr, Ti)O3 (PLZT) with antiferroelectric properties can be applied as a capacitor whose capacitance increases in a high electric field. From this, we obtained a high sintering density at 950 °C by adding low-temperature sintering additives, 8.0 wt% of PbO and 2.5 wt% of ZnO, simultaneously to a (Pb0.88, La0.12)(Zr0.86, Ti0.14)O3 composition. The change in electrical characteristics was confirmed in terms of Sn4+ substitution, resulting in no change in the sintering density by Sn4+ substitution. However, as the amount of Sn4+ substitution increases, the dielectric constant gradually decreases from 1300 to 700, and the grain size decreases from about 4 to 1 µm in terms of microstructure. In the crystal structure analysis, the general formation of a single perovskite structure was confirmed. The results of the hysteresis curve measurement revealed that the breakdown electric field increases from 4 to 9 kV·mm−1 as the amount of Sn4+ substitution gradually increases. However, polarization decreases in the same way as the permittivity trend. The composition exhibits excellent electrical properties when the ratio of Sn4+ is 0.4: a high energy storage density of 3.5 J·cm−3, energy efficiency of 80%, and breakdown electric field of about 8.5 kV·mm−1.