(Pb, La)(Zr, Ti)O3 (PLZT) with antiferroelectric properties can be applied as a capacitor whose capacitance increases in a high electric field. From this, we obtained a high sintering density at 950 °C by adding low-temperature sintering additives, 8.0 wt% of PbO and 2.5 wt% of ZnO, simultaneously to a (Pb0.88, La0.12)(Zr0.86, Ti0.14)O3 composition. The change in electrical characteristics was confirmed in terms of Sn4+ substitution, resulting in no change in the sintering density by Sn4+ substitution. However, as the amount of Sn4+ substitution increases, the dielectric constant gradually decreases from 1300 to 700, and the grain size decreases from about 4 to 1 µm in terms of microstructure. In the crystal structure analysis, the general formation of a single perovskite structure was confirmed. The results of the hysteresis curve measurement revealed that the breakdown electric field increases from 4 to 9 kV·mm−1 as the amount of Sn4+ substitution gradually increases. However, polarization decreases in the same way as the permittivity trend. The composition exhibits excellent electrical properties when the ratio of Sn4+ is 0.4: a high energy storage density of 3.5 J·cm−3, energy efficiency of 80%, and breakdown electric field of about 8.5 kV·mm−1.
The field of application of Glass Fiber Reinforced Polymer expands as well as the size of the component where composite material is applied. Due to the size limitation of the prepreg used, it is difficult to apply 1ply to large parts. Many studies have been reported on the bolt joint that assembles parts and parts for the joint area, butt and overlap design for joining dissimilar materials, and mechanical properties. Although the mechanical properties of the joint areas are important, studies on the microstructure are also needed. In this study, the microstructure was observed by controlling the type of subsidiary materials in the bagging process by applying prepregs of the same composition. It was found that the air and resin flow inside the prepreg acted differently depending on the type of subsidiary material. The flow of resin during curing was inferred from the influence of subsidiary materials and explained by connecting it with the microstructure. The behavior of the resin determined thickness, resin, and void contents of the composite. This flow affects voids in the joint area, causing differences in microstructure and mechanical properties. There was no significant difference in the tensile strength of the laminate specimens manufactured according to the process, but the minimum strength was found in the specimens containing many void contents. The joint specimen showed a decrease in strength as the void content increased. It was discussed that this reduced the adhesive force of the specimen due to the effect of the void generated in the joint area.
Two-dimensional (2D) molybdenum disulfide (MoS2) is the most mature material in 2D material fields owing to its relatively high mobility and scalability. Such noticeable properties enable it to realize practical electronic and optoelectronic applications. However, contact engineering for large-area MoS2 films has not yet been established, although contact property is directly associated to the device performance. Herein, we introduce graphene-interlayered Ti contacts (graphene/Ti) into large-area MoS2 device arrays using a wet-transfer method. We achieve MoS2 devices with superior electrical and photoelectrical properties using graphene/Ti contacts, with a field-effect mobility of 18.3 cm2/V∙s, on/off current ratio of 3 × 107, responsivity of 850 A/W, and detectivity of 2 × 1012 Jones. This outstanding performance is attributable to a reduction in the Schottky barrier height of the resultant devices, which arises from the decreased work function of graphene induced by the charge transfer from Ti. Our research offers a direction toward large-scale electronic and optoelectronic applications based on 2D materials.
Carbon nanocoils and/or microcoils were synthesized using C2H2 as the source gas along with the injection of SF6 as an incorporated additive gas under the thermal chemical vapor deposition (TCVD) system. To control the geometries of the carbon coils, we varied the SF6 flow injection time at different reaction temperature ranges. At the lowest reaction temperature (550°C), carbon microcoils were dominantly formed within a relatively short initial SF6 flow injection time (less than 5 min). By increasing the SF6 flow injection time, carbon nanocoils could be well developed on the entire surface of the sample. At 750°C, the formation of carbon microcoils dominated over the entire sample surface, irrespective of the SF6 flow injection time. Based on these results, the growth mechanism for the dominantly formed carbon coils was suggested and discussed. In addition, the causes for the dominant formation of carbon nanocoils and/or microcoils according to the SF6 flow injection times with the different reaction temperatures were analyzed.